Stress-dilatancy of Zipingpu gravel in triaxial compression tests

Experimental investigations of the dilatancy and particle breakage of gravelly material from the Zipingpu concrete-faced rockfill dam, which was subjected to high-intensity seismic load during the 2008 Wenchuan earthquake, were conducted through a series of large-scale drained triaxial compression tests. A hyperbolic relation between the input plastic work and the degree of particle breakage was found for Zipingpu gravel, independent of the initial void ratio and confining pressures. The stress-dilatancy for Zipingpu gravel was analyzed and compared with data from two rounded alluvial and three angular quarried gravelly and rockfill materials in the literature. A nearly linear relationship between the dilatancy D~p and the stress ratio η was found at medium-to-large stress ratios before the peak stress ratio. The slope of the stress-dilatancy line before peak had slight dependence on the void ratio and confining pressure of the gravel. After peak, the stress-dilatancy relation shifts down compared with that before peak for the gravel specimen. The phase-transformation stress ratio decreased with increased confining pressure, with the exception of sub-rounded gravel with little particle breakage. A nearly linear relationship was found between the phase-transformation stress ratio M_f and the state parameter y for the Zipingpu gravel, regardless of the void ratio and confining pressure of the specimens.     

页岩气藏改造体积的快速确定

对影响页岩气单井产量的基质渗透率、人工裂缝(长度、条数)、天然裂缝(导流能力、连通性)及吸附气量等诸多参数进行模拟。结果发现,页岩气单井产量与上述参数均呈正比,而与天然裂缝间距成反比。通过大量的数值模拟计算进行了图版绘制,用BP人工神经网络法对各因素与改造体积的关系进行训练,以快速确定任意条件下的改造体积形状和大小。     

竖向荷载下弹性支承直墙拱反弯点理论分析

在工程实践中,直墙拱应用较多。由于拱脚位移的存在,合理假设拱脚约束为转角约束、竖向约束和水平弹性约束,应用力法推导出了在弯矩、剪力和轴力共同作用下直墙拱沿弧长的弯矩公式。研究了竖向均布荷载、竖向三角形荷载和竖向集中力荷载作用下,直墙拱沿弧长的弯矩分布及反弯点形成的规律;发现在3种荷载作用下,使得拱脚弯矩为零时的圆心角依次减小。取弹簧支座刚度为等效的下端固支、上端允许水平位移的直墙的抗推刚度,得出了随着直墙高度增加,圆弧拱拱顶弯矩增大而拱脚弯矩减小的变化规律。在直墙拱的设计中,建议选取合适的直墙高度和使得圆弧拱拱脚弯矩为零的圆心角大小,从而有利于提高结构抗弯承载力及拱脚抗剪承载力。     

土体抗剪强度指标变异水平对边坡稳定安全系数取值的影响

针对传统的边坡稳定极限平衡方法不能考虑土体抗剪强度指标变异性影响的问题,基于极限状态的概率分析原理,采用Monte-Carlo法对均质路堤边坡的稳定性开展了可靠度计算,讨论了稳定安全系数一定的条件下边坡失效概率随土体抗剪强度指标变异水平的变化规律,分析了安全系数与边坡可靠指标的对应关系及其随土体抗剪强度指标变异水平的变化特征。研究表明：边坡可靠度受土体抗剪强度指标变异性影响显著,呈现出随土体抗剪强度指标变异水平提高而急剧减小的趋势;为保证边坡具有相同的可靠性,安全系数的取值应与土体抗剪强度指标的变异性相适应,据此提出了基于可靠指标和土体抗剪强度指标变异水平的安全系数取值原则及其对应的三参数函数关系式。     

Mechanical properties of silica aerogels prepared from a mixture of TEOS and organo-alkoxysilanes of type R1SiX3

Silica aerogels were prepared from a mixture of tetraethylorthosilicate and organo- alkoxysilanes. The effects of organo-alkoxysilanes on the mechanical properties of the silica aerogels were studied. The flexibility of silica aerogels was significantly improved by incorporation of organo-alkoxysilanes. When MTES and TEOS were combined as precursors of silica areogels, with the increased amount of MTES, the apparent elastic modulus and apparent compressive strength monotonously rose. At the same organo- alkoxysilanes to TEOS ratio, the size of alkyl groups of the organo-alkoxysilanes had little effect on the mechanical properties. In series of MTES and TEOS, the lowest elastic modulus of silica skeleton and the highest compressive strength of silica skeleton were observed at MTES to TEOS ratio of around 50：50. At a certain organo-alkoxysilanes to TEOS ratio, the elastic modulus of silica skeleton increased and the compressive strength of silica skeleton decreased with the size increase of the alkvl grouns.     

基于广义微状态的运动想象分类研究

该文根据传统微状态的概念,提出了一种广义微状态定义,并基于该定义实现了一种多分类运动想象任务特征提取算法。该文使用实验室2分类数据和2008年国际脑机接口竞赛4分类数据集对提出的特征提取算法进行了测试。对2分类数据特征用最小夹角算法分类,准确率最高达到95.56%;对多分类数据特征用SVM算法分类,效果稳定,其中竞赛数据4分类kappa分析结果接近2008年竞赛获胜者水平,测试结果验证了算法的有效性。     

Effects of laser heat treatment on the fracture morphologies of X80 pipeline steel welded joints by stress corrosion

The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment （LHT） on H2S stress corrosion in the National Association of Corrosion Engineers （NACE） solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.     

锥度量空间中四个自映射的公共不动点定理

在完备的锥度量空间中讨论了4个自映射的公共不动点定理,其存在性和唯一性得到证明。所得主要结果将锥度量空间中的公共不动点定理进行了推广。     

生态敏感性评价研究进展

生态敏感性评价不仅为分析和预测区域生态系统失衡和环境问题提供依据,而且是生态环境影响分析和城市生态系统建设调控的重要内容和环节。文章总结了生态敏感性评价的内涵,从生态敏感性评价对象、评价方法和步骤、评价体系建立的方法、评价权重确定和评价模型选择的方法等方面,阐述了当前生态敏感性评价的研究进展,分析了生态敏感性研究存在的不足,并对生态敏感性的应用前景做出了展望。     

Separation of propylene and propane with a microporous metal–organic framework via equilibrium-kinetic synergetic effect

Adsorption separation of olefin and paraffin can greatly lower the energy consumption associated with the currently utilized distillation technique but remains a great challenge. Herein, we report the efficient separation of propylene (C₃H₆) and propane (C₃H₈) in a phosphate anion-functionalized metal–organic framework (MOF) ZnAtzPO₄ by synergetic effect of equilibrium and kinetics. The material features periodically expanded and contracted apertures decorated with electronegative groups, offering eligible pore shape and pore chemistry to effectively trap C₃H₆ under moderate isosteric heat of adsorption (27.5 kJ mol⁻¹) while obstruct the diffusion of C₃H₈. It simultaneously combines excellent thermodynamic selectivity (uptake ratio of 1.71) and kinetic selectivity (~31) for C₃H₆/C₃H₈ separation, meanwhile can be easily regenerated. Breakthrough experiment for C₃H₆/C₃H₈ gas mixture was conducted and confirmed the outstanding separation capability of ZnAtzPO₄. The equilibrium and kinetics cooperative C₃H₆/C₃H₈ adsorption separation was for the first time found in anion-functionalized MOFs, and further confirmed by computational studies.