Separation of trace level hafnium from tungsten: a step toward solving an astronomical puzzle

182Hf (T(1/2) = 9 x 10(6) y) is believed to be formed by pure r-process during a supernova explosion, and therefore, the search for minute traces of 182Hf in the earth's crust is of great interest. Only accelerator mass spectrometry (AMS) is well suited for detecting such low levels of 182Hf. But any attempt to measure 182Hf by AMS must ensure that the sample is free from its naturally occurring stable isobar 182W. A simple method for separation of tungsten and hafnium has been developed using radiometric simulation followed by checking the decontamination of tungsten from Hf in a synthetic sample by AMS. The separation studies were performed by a liquid-liquid extraction technique using tri-n-octylamine (TOA) as the organic reagent. It has been found that a very high separation factor (1.6 x 10(6)) can be achieved when 0.3 M TOA diluted in cyclohexane is used as the organic phase and 6 M HCl (in the presence of small amount of H2O2) is used as the aqueous phase.     

Planning for the Subernarekha river system in eastern India

The study describes the systems studies carried out to plan a river basin in order to determine the nature and size of water storage facilities and releases for irrigation and industrial uses, and the associated cropping pattern. The model has been formulated in the framework of a linear programming model for a specific target year. This model is developed in the context of planning the Subernarekha river basin. The results are discussed and these provide information and insight suggesting the need for more disaggregated analysis of interaction between irrigation and related agroeconomic parameters.     

Effect of interface on the mechanical behaviour of glass bead-filled PVC

The surface of glass beads of average particle size 100m was modified (a) by incorporating extra hydroxyl groups by chemcial treatment, and (b) by applying a thin coating of polymethacrylic acid (PMA) on the glass surface. The corresponding chemical changes were investigated using infrared spectroscopy. The tensile behaviour of a glass bead-filled PVC composite prepared with surface-modified glass beads, showed the following effects: (a) hydroxyl groups incorporated on to the glass surface did not affect the glass-PVC interface and hence did not change the tensile behaviour of the composite; (b) PMA coating on the glass surface caused improvement in the tensile behaviour in the low strain region and deterioration in the high region. An SEM study of the fractured surface suggested debonding at the glass-PVC interface in the first case, and failure of the PVC-PMA interface in the second case.     

Enhanced α-Mn2O3 nanorods synthesized by one-pot hydrothermal route for supercapacitors

Journal of Materials Science: Materials in Electronics - Pseudo-capacitors are the emerging energy storage devices which forms a bridge between batteries and conventional capacitors. In the present...     

Lithographic patterning of superconducting YBCO films

Microbridges of YBa₂Cu₃O₇ thin films have been fabricated by conventional photolithography and wet chemical etching using EDTA, and by the lift-off lithography technique. The variation of etch rate with etch time, etchant temperature, and post-deposition sintering temperature has been studied. It has been shown that both techniques are useful for film patterning. However, an additional sintering step is necessary for the chemically etched sample to regain the original film properties. An order of increase in critical current density is observed for the patterned film.     

Carbon nanotube reinforced hydroxyapatite composite for orthopedic application: A review

Application of hydroxyapatite (HA) in orthopedic implants suffers from its low fracture toughness and poor wear resistance. Carbon nanotube (CNT), with its high stiffness and mechanical strength, is an attractive reinforcement for HA to surmount these issues. The last 7–8 years have seen a number of studies to explore the efficiency of CNT reinforcement in strengthening HA, in the form of composites and coatings. Impressive improvement in the fracture toughness and wear resistance of HA with CNT reinforcement and beneficial effects on biocompatibility has sparked further research interests, for possible clinical applications. This review article aims to cover a wide span of this exciting and expanding research arena – from detailed technical discussions on HA–CNT system, their processing techniques and the influence of CNT dispersion in the HA matrix. Role of CNT in the improvement of mechanical properties and tribological behavior of the composite has been discussed in light of different processing techniques. Other important issues related to HA–CNT system, e.g., phase transformation and crystallinity of HA and HA–CNT interfacial bonding has been stressed upon. Biocompatibility of HA–CNT composites, which is extremely important for its intended orthopedic application, has been summarized with an overview of the present status. An in-depth analysis of the information presented in this review facilitates a better understanding of the current state of HA–CNT research and allows framing guidelines toward future research direction for its successful clinical application.     

Bulk micromachining of silicon in TMAH-based etchants for aluminum passivation and smooth surface

The fabrication of silicon based micromechanical sensors often requires bulk silicon etching after aluminum metallization. All wet silicon etchants including ordinary undoped tetramethyl ammonium hydroxide (TMAH)-water solution attack the overlaying aluminum metal interconnect during the anisotropic etching of (100) silicon. This paper presents a TMAH-water based etching recipe to achieve high silicon etch rate, a smooth etched surface and almost total protection of the exposed aluminum metallization. The etch rate measurements of (100) silicon, silicon dioxide and aluminum along with the morphology studies of etched surfaces are performed on both n-type and p-type silicon wafers at different concentrations (2, 5, 10 and 15%) for undoped TMAH treated at various temperatures as well as for TMAH solution doped separately and simultaneously with silicic acid and ammonium peroxodisulphate (AP). It is established through a detailed study that 5% TMAH-water solution dual doped with 38 gm/l silicic acid and 7 gm/l AP yields a reasonably high (100) silicon etch rate of 70 μm/h at 80 °C, very small etch rates of SiO₂ and pure aluminum (around 80 Å/h and 50 Å/h, respectively), and a smooth surface (±7 nm) at a bath temperature of 80 °C. The etchant has been successfully used for fabricating several MEMS structures like piezoresistive accelerometer, vaporizing liquid micro-thruster and flow sensor. In all cases, the bulk micromachining is carried out after the formation of aluminum interconnects which is found to remain unaffected during the prolonged etching process at 80 °C. The TMAH based etchant may be attractive in industry due to its compatibility with standard CMOS process.