Preparation and properties of sulfopropyl chitosan derivatives with various sulfonation degree

In this investigation, chitosan (CS) is modified by propane sultone via a sulfonation reaction to create various degrees of sulfonation. The sulfonated chitosan (SCS) has a pendant alkyl sulfonic group dangling at the side chain, which can improve its hydrophilicity and water solubility. Elemental analysis, Fourier transform infrared spectroscopy (FTIR) and ¹³C nuclear magnetic resonance (¹³C NMR) were applied to identify the structure by determining the distribution of the substituents in the product. The degree of sulfonation in the SCS can be controlled and the hydrogen bonding interaction can be reduced by varying the degree of sulfonation. A solubility test proved that solubility increased with degree of substitution at over a wide range of pH values. X‐ray diffraction patterns of SCS samples demonstrated that the crystallinity declined as the degree of sulfonation increased. Thermogravimetric analysis and modulated differential scanning calorimetry (MDSC) results indicated that thermal stability fell but water absorbance increased with the degree of sulfonation. More water‐soluble SCS is thus obtained. The controllable different sulfonation degree of the CS polymer suggests new possibilities for the application of CS‐based materials. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

受火钢结构非线性性能的向量式有限元分析

采用向量式有限元分析,对受火钢结构的非线性响应进行研究。通过与已公布的钢结构试验数据及分析结果相比较,验证数字模型。对Williamstoggle框架和钢框架在地震荷载和火荷载下的非线性性能响应进行研究。数值结果显示:当温度低于临界值时,随着温度增加,Williamstoggle框架的承载力显著增大;然而,当温度高于临界值时,随着温度增加,Williamstoggle框架的承载力显著减少,但当温度达到1000℃时,承载力仍大于室内温度时的弹性屈服强度。此外,随着温度增加,屈服前浅拱向上偏转,而且其挠度远小于同样跨度的梁结构。屈曲后,结构的挠度向下,当重新平衡时,显示出悬链线作用。在地震诱发的火灾中,结构变形受余震、火、结构单元的破坏影响较大。     

Size effect in reactivity of copper nanoparticles to carbon tetrachloride degradation

Surface area-normalized rate constants (k(SA)) of reaction between metallic nanoparticles and reducible contaminants, such as chlorinated hydrocarbons, heavy metals, and nitrate, have been reported to be dramatically increased as compared to that of commercial metallic powder. However, k(SA) for individual pollutants in previously published data vary by as much as 1-2 orders of magnitude and much of this variability is due to the effect of various sizes. The size dependence of the reactivity of nanoparticles is not yet fully understood; however, yielding nanoparticles with uniform size and without agglomeration during the period of reaction would demonstrate the effect of varying particle size. In this study, resin-supported zerovalent copper with average particle size of 7, 10, 18, 26, and 29, respectively, were successfully synthesized and evidenced no agglomeration during the reaction period of 10h. The k(SA) of copper nanoparticles (k(n,SA)) was 110-120 times higher than that of powdered copper particles (k(p,SA)) when the copper particle size was about 10nm. However, for diameters of 18-29 nm, the ratio of k(n,SA)/k(p,SA) was around 10-20, indicating that the reactivity of small copper nanoparticles (approximately 10nm) varies discontinuously. Thus, most variability in previous k(SA) is attributed to the presence of small nanoparticles.     

Comparison of bioactive components in GABA tea and green tea produced in Taiwan

The aim of this study is to investigate the bioactive components of GABA (γ-aminobutyric acid) tea as compared with green tea produced in Taiwan. Using in total 56 tea samples (28 green tea and 28 GABA tea), moisture content, Hunter L, a and b values, phenolic compounds, amino acids including GABA, fatty acids and ascorbic acid were determined. The results showed that moisture, total free amino acids, crude fat, Hunter L value, total nitrogen, free fatty acids and reducing sugar did not differ significantly between GABA tea and green tea. However, GABA tea had higher Hunter a and b values, while green tea had higher total catechin and ascorbic acid contents (p < 0.05). Of major catechins, epicatechin and epigallocatechin gallate were found to be lower in GABA tea than in green tea. For free amino acids, GABA, alanine, ammonia, lysine, leucine and isoleucine were found to be significantly higher in GABA tea, while the glutamic acid, aspartic acid, and phenylalanine were higher in green tea (p < 0.05). Theanine, tryptophan, valine, threonine and methionine were not found to be different between the two kinds of tea.     

Using author co-citation analysis to examine the intellectual structure of e-learning: A MIS perspective

The increased use of e-learning techniques as an accepted form of teaching has resulted in a growing volume of academic research dedicated to their assessment. Despite the importance of the technique, there is little comprehensive knowledge on e-learning, especially in non-educational fields. Author co-citation analysis (ACA) is an analytical method for identifying the intellectual structure of specific knowledge domains through the relationship between two similar authors. ACA has been applied to many fields, such as information retrieval, knowledge management, and strategic management; however, it has not yet been used to analyze e-learning development. This study examines the intellectual structure of e-learning from the perspective of management information systems (MIS). By applying the ACA method, we analyze and categorize international and Taiwanese research topics into clusters. Our results show that Taiwanese authors put more effort into practical studies of business training, while international authors focus on a users’ psychological reaction to learning context. Altogether, our research provides a clear intellectual analysis of e-learning practices from 1996 to 2009, enabling us to thoroughly study and understand the influence of these techniques on modern education.     

On the throughput of multicasting with incremental forward error correction

In this paper, we consider a multicasting model that uses incremental forward error correction (FEC). In this model, there is one sender and r/sup n/ receivers. The sender uses an ideal (n,n(1-p),np) FEC code to code a group of n(1-p) data packets with additional np redundant packets so that any set of n(1-p) packets received by a receiver can be used to recover the original n(1-p) data packets. Packets to the receivers are lost independently with probability q. For this model, we prove several strong laws of large numbers for the asymptotic throughput as n /spl rarr/ /spl infin/. The asymptotic throughput is characterized by the unique solution of an equation in terms of p, q, and r. These strong laws not only provide theoretical justification for several important observations made in the literature, but also provide insights that might have impact on future design of multicasting protocols.     

An optimal scheduling algorithm for testing interconnect using boundary scan

Systems will soon be built with ICs that conform with the IEEE 1149.1 boundary scan architecture. Due to the hierarchical nature of such systems, they may contain many boundary scan chains. These chains can be used to test the system, subsystem, and board interconnect. To reduce test time, the application of test vectors to these scan chains must be carefully scheduled. This article deals with problems related to finding an optimal schedule for testing interconnect. This problem is modeled using a directed graph. The following results are obtained: (1) upper and lower bounds on interconnect test time; (2) necessary and sufficient conditions for obtaining an optimal schedule when the graph is acyclic; (3) sufficient condition for obtaining an optimal schedule when the graph is cyclic; and (4) an algorithm for constructing an optimal schedule for any graph.This work was supported by Defense Advanced Research Projects Agency and monitored by the Office of Naval Research under contract No. N00014-87-K-0861. The views and conclusions contained in this document are those of the authors and should not be interpreted as necessarily representing the official policies, either expressed or implied, of the Defense Advanced Research Projects Agency or the U.S. Government.     

Evidence for an Activation Locus of the Word-Frequency Effect in Lexical Decision.

The authors report a lexical decision experiment designed to determine whether activation is the locus of the word-frequency effect. K. R. Paap and L. S. Johansen (1994) reported that word frequency did not affect lexical decisions when exposure durations were brief; they accounted for this by proposing that data-limited conditions prevented late-occurring verification processes. Subsequently, P. A. Allen, A. F. Smith, M. Lien, T. A. Weber, and D. J. Madden (1997) and K. R. Paap, L. S. Johansen, E. Chun, and P. Vonnahme (2000) reported additional evidence that word-frequency effects do and do not have an activation locus, respectively. The authors further tested this issue in a lexical decision experiment using data-limited procedures--predicted by verification models to eliminate word-frequency effects. The authors observed word-frequency effects using individually determined exposure durations that were only 1 screen cycle longer than the exposure duration that yielded chance performance. Word-frequency effects persisted even when an adjusted measure of performance was used. (PsycINFO Database Record (c) 2010 APA, all rights reserved)