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Hui Li Jun Liu Songhai Xie Minghua Qiao Weilin Dai Yunfeng Lu Hexing Li 《Advanced functional materials》2008,18(20):3235-3241
Mesoporous Ce‐doped Pd nanospheres with a hollow chamber are synthesized by chemical reduction of PdCl2 with KBH4 in an aqueous solution containing Ce(NO3)3 and Bu4PBr. The later acts as a template for the hollow chamber via forming organic vesicles. During the liquid‐phase phenol hydrogenation to cyclohexanone, the as‐prepared catalyst exhibits a much‐higher activity than the corresponding solid nanoparticle catalyst prepared in the absence of Bu4PBr. Meanwhile, the Ce dopants greatly enhance the activity and selectivity to cyclohexanone. The hollow chamber is quite stable against heating in solution and the catalyst could be used repetitively many times. Such a catalyst shows a good potential in industrial applications. 相似文献
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Zhaoxu Tu Ievgen S. Donskyi Haishi Qiao Zhonglin Zhu Wolfgang E. S. Unger Christian P. R. Hackenberger Wei Chen Mohsen Adeli Rainer Haag 《Advanced functional materials》2020,30(35)
Multidrug resistance resulting from a variety of defensive pathways in cancer has become a global concern with a considerable impact on the mortality associated with the failure of traditional chemotherapy. Therefore, further research and new therapies are required to overcome this challenge. In this work, a cyclic R10 peptide (cR10) is conjugated to polyglycerol‐covered nanographene oxide to engineer a nanoplatform for the surmounting of multidrug resistance. The nuclear translocation of the nanoplatform, facilitated by cR10 peptide, and subsequently, a laser‐triggered release of the loaded doxorubicin result in efficient anticancer activity confirmed by both in vitro and in vivo experiments. The synthesized nanoplatform with a combination of different features, including active nucleus‐targeting, high‐loading capacity, controlled release of cargo, and photothermal property, provides a new strategy for circumventing multidrug resistant cancers. 相似文献
75.
2000年9月在敦煌辐射校正场用国内外两组仪器同时获取场地数据,经数据处理分析后,对中巴地球资源一号卫星CCD相机进行了绝对辐射定标。本文通过对试验数据的结果比对和误差分析,证明国产仪器完全能满足对中巴地球资源一号卫星进行绝对辐射定标的精度要求。 相似文献
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B. S. Lamsal M. Dubey V. Swaminathan Y. Huh D. Galipeau Q. Qiao Q. H. Fan 《Journal of Electronic Materials》2014,43(11):3965-3972
This work studied the electronic characteristics of the grains and grain boundaries of indium tin oxide (ITO) thin films using electrostatic and Kelvin probe force microscopy. Two types of ITO films were compared, deposited using radiofrequency magnetron sputtering in pure argon or 99% argon + 1% oxygen, respectively. The average grain size and surface roughness increased with substrate temperature for the films deposited in pure argon. With the addition of 1% oxygen, the increase in the grain size was inhibited above 150°C, which was suggested to be due to passivation of the grains by the excess oxygen. Electrostatic force microscopy and Kelvin probe force microscopy (KPFM) images confirmed that the grain growth was defect mediated and occurred at defective interfaces at high temperatures. Films deposited at room temperature with 1% oxygen showed crystalline nature, while films deposited with pure argon at room temperature were amorphous as observed from KPFM images. The potential drop across the grain and grain boundary was determined by taking surface potential line profiles to evaluate the electronic properties. 相似文献
78.
Waveband switching in optical networks 总被引:20,自引:0,他引:20
The rapid advances in dense wavelength-division multiplexing technology with hundreds of wavelengths per fiber and worldwide fiber deployment have brought about a tremendous increase in the size (i.e., number of ports) of photonic cross-connects, as well as in the cost and difficulty associated with controlling such large cross-connects. Waveband switching (WBS) has attracted attention for its practical importance in reducing the port count, associated control complexity, and cost of photonic cross-connects. We show that WBS is different from traditional wavelength routing, and thus techniques developed for wavelength-routed networks (including, for example, those for traffic grooming) cannot be directly applied to effectively address WBS-related problems. We describe two multigranular OXC architectures for WBS. By using the multilayer MG-OXC in conjunction with intelligent WBS algorithms for both static and dynamic traffic, we show that one can achieve considerable savings in the port count. We also present various WBS schemes and lightpath grouping strategies, and discuss issues related to waveband conversion and failure recovery in WBS networks. 相似文献
79.