Atomic force microscopy on polymers and polymer related compounds

Summary Surface morphology and molecular arrangement have been recorded by atomic force microscopy (AFM) on polytetrafluoroethylene (PTFE) and on polycarbonate (PC) films. In a thin layer of PTFE deposited by rubbing polymer on hot glass substrate unidirectional orientation of polymer has been revealed. Individual polymer chains have been visualized. An interchain distance of .53 nm and several periodicities along the chain contours have been found-.44 nm, .62 nm and .82 nm-in accordance with a 13/6 helix.The monitoring of surface changes during thermal treatment of amorphous-bis-phenol A-PC film has been realized by AFM. Different types of surface morphology were revealed. Spherulites are formed during polymer crystallization. In most cases, however, numerous nanocrystallites appeared after thermal treatment. On their surfaces well-ordered atomic scale AFM images have been received. The arrangement of AFM patterns can be characterized by periodicities of .50 nm and .52 nm in the orthogonal directions. Polycarbonate oligomers-as the product of surface degradation-effectively might form the observed nanocrystallites.Prof. Dr. G. Zachmann zum 60. Geburtstag herzlichst gewidmetThese results were given by us first in a lecture in Baltimore, at the 5th ISPAC Symposium on May 31, 1991, and in a lecture in Santa Barbara, at the Nanoscope Users Meeting on June 25, 1991     

Zur Reaktivität von Tanninen in Abhängigkeit vom Kambialalter

Ohne Zusammenfassung     

Exergoeconomic analysis and evaluation of energy-conversion plants—I. A new general methodology

A new approach to the combination of exergetic and economic analysis (exergoeconomic analysis) for the investigation of energy-conversion processes is presented. This approach allows the monetary evaluation of costs caused by irreversibilities (exergy losses), as well as comparisons between these costs and the investment and operating costs for each component of a plant. The present analysis permits identification and evaluation of inefficiencies in an energy-conversion plant and of opportunities for improvement.     

Guaranteed inclusions for the complex generalized eigenproblem

A method is described which produces guaranteed bounds for a solution of the generalized complex eigenproblem. The method extends a similar approach for general systems of nonlinear equations to the special case of complex pencils, where under weaker assumptions stronger assertions can be proved.     

Solar duct for lighting and ventilation Santa Amalia building Barcelona -Spain

The Santa Amalia building in Barcelona is a block of six flats incorporating a duct by which ligth is sent to the kitchens - previously without natural ligthing- and also allows natural ventilation. Moreover, the passive solar gains obtained from the extensive glazed surfaces and the conservation of internal heat gains, along with a high degree of isulation, give energy saving of 68% for heating.     

The Geography of Opportunity and Unemployment: An Integrated Model of Residential Segregation and Spatial Mismatch

Abstract: This article combines the neighborhood effects and spatial mismatch frameworks into a single model explaining how geographic factors contribute to unemployment. Using National Longitudinal Survey of Youth (1979) data, I estimate a two‐step model that separately models the effects of segregation and spatial mismatch. The first model predicts educational attainment as a function of exposure to residential segregation as a youth. The second model predicts unemployment probability as an adult as a function of educational attainment and spatial mismatch. The empirical results show that segregation does have discernable effects on educational attainment for blacks, but not for whites. I also find that spatial mismatch affects unemployment probability for blacks, but such an effect is hardly present for whites. A partial equilibrium analysis using predictions from the models shows that large changes in either segregation levels or the central city/suburban distribution of the black population would yield only moderate decreases in unemployment probability for the black population overall. Yet despite small predicted effects, these results should be viewed with caution because the general equilibrium effects of a large scale movement of blacks and whites across metropolitan space are largely impossible to predict with current data.     

Reactive energy measurement using frequency controlled analog-to-pulse-rate converter

Contents This paper analyzes a problem of phase shifting and deseribes a novel method for electronic reactive energy measurement. The proposed measurement structure, composed of an integrator as a phase shifting circuit and a frequency controlled analog-to-pulse-rate converter, provides for the measurement completely in accordance with IEC definition of reactive energy, which is performed with simple but high performance metering device.

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Die Blindverbrauchsmessung anhand eines netzsynchronisierten Analog-Frequenz-Wandlers

Übersicht In diesem Artikel wird das Problem der Phasenverschiebung analysiert und eine neue Meßmethode für elektronische Blindverbrauschsmessung aufgezeigt. Die vorgeschlagene Strucktur, bestehend aus einem Integrator als Phasenschieber und netzkontrolliertem Analog-Frequenz-Wandler, ermöglicht die Verwirklichung eines einfachen aber präzisen Elektrizitätszählers zur Messung der Blindenergie, dessen Arbeitsprinzip mit den IEC Empfehlungen vollkommen übereinstimmt.

     

Twisted axially loaded rod with shear and compressibility

Summary Stability of a twisted and axially compressed elastic rod is analysed using the Euler method of adjacent equilibrium configuration. The constitutive equations of the rod are assumed in the form that takes into account both shear of the cross-sections and compressibility of the rod axis. It is shown that bifurcation points of the non-linear system of equations describing equilibrium are determined from the linearized system of equations. The influence of shear and compressibility on the critical values of twisting couple and compressive force is obtained. Moreover, the bifurcation pattern is examined by using the Liapunov-Schmidt method.