N‐Heterocyclic Carbene‐Catalyzed Umpolung Formal [3+3] Cycloaddition of Enals with Isatogens: Access to Fused Indolin‐3‐ones with a Tetrasubstituted Carbon Stereocenter

A novel synthetic method to access fused indolin‐3‐ones with a tetrasubstituted carbon stereocenter has been developed via NHC‐catalyzed umpolung formal [3+3] cycloaddtion of enals with isatogens. This methodology could be also applied for the quick construction of the 6‐5‐5 tricyclic pyrrolo[1,2‐a]indole skeleton which is frequently found as a core structure of many indole alkaloids.

     

Synthesis of amphoteric nanocomposite hydrogels with ultrahigh tensibility

Amphoteric nanocomposite hydrogels (NC gels) were synthesized by in situ copolymerization of acrylic acid (AA) and N[‐3(dimethylamino)propyl] methacrylamide (DMAPMA) in an aqueous dispersion of laponite XLG. Mechanical analyses demonstrated that this type of hydrogels had a combination of high tensile strength and excellent stretchability. The tensile strength was increased by 5 times up to 316 kPa when the laponite content was increased from 0.1 wt% to 20 wt%, and a maximum fracture strain of 2,317% was achieved for hydrogels containing 3 wt% laponite. Additionally, the marked improvements in strength were achieved with minimal sacrifice of the tensibility. This work provided a continuation to previous efforts of the preparation and properties of ionic NC gels. POLYM. COMPOS. 36:538–544, 2015. © 2014 Society of Plastics Engineers     

High performance modification of hyperbranched polyborate on diglycidyl ether of bisphenol‐a resin

High performance epoxy resin was obtained by introducing hyperbranched polyborate (HBPB) into diglycidyl ether of bisphenol A (DGEBA) resin to overcome the defects such as low char yield and poor toughness of DGEBA resin. By virtue of the massive functional end groups, hyperbranched and rigid boron‐containing structures of HBPB, the thermal resistance of DGEBA resin cured with diamino diphenyl sulfone (DDS) can be greatly improved. Moreover, with the toughening effect of hyperbranched structures of HBPB, the mechanical properties such as flexural strength and interlaminar shear strength of the carbon fiber reinforced DGEBA‐DDS composite could be greatly increased by HBPB without a decrease on modulus and glass transition temperature of DGEBA‐DDS resin. POLYM. COMPOS. 36:424–432, 2015. © 2014 Society of Plastics Engineers     

Performance enhancement of multicrystalline silicon solar cells and modules using double‐layered SiNx:H antireflection coatings

Silicon nitride coating deposited by the plasma‐enhanced chemical vapor deposition method is the most widely used antireflection coating for crystalline silicon solar cells. In this work, we employed double‐layered silicon nitride coating consisting of a top layer with a lower refractive index and a bottom layer (contacting the silicon wafer) with a higher refractive index for multicrystalline silicon solar cells. An optimization procedure was presented for maximizing the photovoltaic performance of the encapsulated solar cells or modules. The dependence of their photovoltaic properties on the thickness of silicon nitride coatings was carefully analyzed. Desirable thicknesses of the individual silicon nitride layers for the double‐layered coatings were calculated. In order to get statistical conclusions, we fabricated a large number of multicrystalline silicon solar cells using the standard production line for both the double‐layered and single‐layered antireflection coating types. On the cell level, the double‐layered silicon nitride antireflection coating resulted in an increase of 0.21%, absolute for the average conversion efficiency, and 1.8 mV and 0.11 mA/cm² for the average open‐circuit voltage and short‐circuit current density, respectively. On the module level, the cell to module power transfer factor was analyzed, and it was demonstrated that the double‐layered silicon nitride antireflection coating provided a consistent enhancement in the photovoltaic performance for multicrystalline silicon solar cell modules than the single‐layered silicon nitride coating. Copyright © 2015 John Wiley & Sons, Ltd.     

优化组合预测的设计与分析

阐述了组合预测方法的基本原理,并从理论上论证了组合预测方法相对于单一预测模型的优越性。针对以往的组合预测模型最优权重不能保证非负性的问题,提出了一种新的基于前向神经网络模型的最优权重确定方法,并引入了神经网络优选组合预测模型。通过分析和比较,此模型具有很强的自适应性和较高的预测精度。     

合成气压缩机扩能改造总结

介绍合成气压缩机组改造全过程,对改造环节中遇到问题的解决和处理方案进行了详细的说明,并对机组改造前后的性能参数进行对比和分析,为以后大机组的改造积累了宝贵的经验.     

变频器在高速公路上的应用

变频器应用于高速公路收费站栏杆机、收费站和服务区供水系统、隧道通风系统.高速公路使用了变频器后,可提升自动化控制水平,并有一定的节能效果.     

浅层超稠油热采杜84-平28井设计与实钻技术

曙一区杜84块是辽河油田超稠油难采储量中规模较大的具有代表性的区块,开发中存在注汽困难、生产周期短、油井作业频繁热损失大、地层普遍出砂、综合成本高、开采难度大等一系列问题。根据油藏生产动态和综合分析油藏地质参数,结合油藏特征及原井网开发状况,通过对杜84-平28井优化设计和精心组织施工,重点对施工中产生的主要问题进行分析,采取科学合理的技术措施,取得显著的开发效果。     

国内首台大容量垂直输煤机在主厂房内的应用

汕头电厂二期拟建设1台600 MW超临界机组。由于一、二期厂房高度不一致,故需安装垂直输煤装置,作为一、二期连接的输煤设备。经过安装、调试及设备修改,垂直输煤提升装置运行稳定,效果良好。     

小型嵌入式系统的分析方法--IFSM

首先从软件工程角度将嵌入式系统划分为小型嵌入式系统和复杂嵌入式系统,并分析两者区别。在分析已有软件工程方法的基础上,提出基于改进有限状态机的分析方法和基于盒图的设计方法是适用于小型嵌入式系统开发的工具,并以实例说明。最后对使用这些工具时应该注意的问题以及对策进行分析,表明这些方法具有较强的通用性。