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991.
Industrial production of Si3 N4 from SiCI4 , is increasing. An element rivaling CI in abundance and cheapness with potentially suitable chemistry for this application is sulfur. Thus, Si–S–N chemistry was investigated to determine its usefulness in producing Si3 N4 . Bifunctionality in S, as opposed to mono-functionality in CI, may allow special routes via polymers to become important. 相似文献
992.
Enthalpies of segregation for isovalent impurities in magnesium and calcium oxide as a function of surface concentration were calculated by using an atomistic computer simulation method. We have considered Be2+ , Mg2+ , Ca2+ , Ba2+ , and Ni2+ , segregating to both (001) and (110) faces. The results obtained can be extrapolated to predict the behavior of other impurities including Mn2+ , Fe2+ , and Co2+ , We find, for example, that Fe2+ , Mn2+ , Ca2+ , Sr2+ , and Ba2+ will concentrate at the (001) surface of MgO, while Ni2+ will be depleted. The enthalpy of segregation is found to vary substantially with coverage particularly for the larger impurities. The enthalpy becomes less negative with increasing impurity concentration due to the increasing lattice strain until the surface is nearly saturated. Then additional stabilization is obtained by restructuring of the surface layer. We predict reconstructed surfaces for both the (001) and (110) faces, which contain a high concentration of a larger impurity ion. The enthalpy of segregation shows a maximum at around 50% surface coverage implying a bimodal surface distribution of segregant. The influence of segregation on surface energy suggests two unusual effects. The (001) surface energy of the impure crystal becomes negative for surface concentrations of impurity greater than 10% Ba2+ or 75% Sr2+ in MgO. This implies a thermodynamic barrier to sintering. At high coverages of Ba2+ in MgO the (110) surface becomes more stable than the (001) face suggesting that facetting may occur. 相似文献
993.
994.
Renaudier J. Brenot R. Dagens B. Lelarge F. Rousseau B. Poingt F. Legouezigou O. Pommereau F. Accard A. Gallion P. Duan G.-H. 《Electronics letters》2005,41(18):1007-1008
Self-pulsation at 45 GHz repetition frequency has been demonstrated in 1.5 /spl mu/m monolithic single-section quantum dot Fabry-Perot semiconductor lasers without saturable absorber. The mode-beating exhibits a narrow linewidth below 100 kHz, demonstrating high phase correlation between these modes. Such modelocked lasers open ways to low timing-jitter components for clock recovery or millimetre-wave generation in wireless transmission applications. 相似文献
995.
The kinetics of electronic processes in vidicon phototargets based on semiconductor-insulator structures with a narrow-gap semiconductor is considered taking into account charge drain in the insulator layer and relaxation of the nonequilibrium depletion region in the semiconductor layer. The integration time, threshold sensitivity, and resolution at various intensities of incident radiation are estimated. 相似文献
996.
The literature provides little information on high-speed, high-normal-load, plain linear bearings, although the case for two rigid surfaces in relative linear motion can readily be solved by assuming squeeze action resistance. A new genus of internal combustion engines based on the Stiller-Smith mechanism incorporates connecting rods constrained by linear bearings, with the central normal load on the rod restricted by an oil film. A general analysis takes into account the bending of the rod, when the distributed oil film pressure resists the distributed load on the elastic rod. Design charts result that yield the dimensionless velocity at which the rod sinks in the oil as a function of the dimensionless load and the bearing clearance, and predict the deflection of the beam. The rod clearance history simulations for the Stiller-Smith engine compare favourably with computations for the rigid beam, confirming the analysis technique. 相似文献
997.
Poly-N,N-dimethylaniline was prepared by electrochemical polymerization of the monomer on gold, platinum and tin oxide electrodes
in an acid medium. The polymer was characterized by cyclic voltammetry and scanning electron microscopy. Poly-N,N-dimethylaniline electrodes, modified by electrodeposition of palladium particles, were prepared. 相似文献
998.
999.
1000.
Heretakis I.I. Papakanellos P.J. Capsalis C.N. 《Antennas and Propagation, IEEE Transactions on》2005,53(3):938-947
A genetically optimized technique that fully automates the potentially laborious allocation of the auxiliary monopoles for the method of auxiliary sources (MAS) is presented for the problem of electromagnetic (EM) scattering by isotropic dielectric cylinders with various cross sections. The proposed technique uses as input information not only the geometry of the scatterer but also the exciting field and the material properties of the cylinders are implicitly taking part in the optimization procedure. The resulting auxiliary surfaces, where the simulating monopoles are situated, are appropriately adapted to the original boundary surface and the MAS modeling is greatly facilitated. In addition, certain considerations are taken into account in order to avoid undesirable numerical dependencies between the fictitious monopoles. Finally, the accuracy of the numerical method combined with overdetermined systems of equations is examined for isotropic cylinders of various geometries and dielectric characteristics. 相似文献