High-temperature oxidation of intermetallics formed by group IV transition metals with chromium

We have studied the oxidation resistance of chromium intermetallics: TiCr₂, HfCr₂, and ZrCr₂, in the temperature interval 873–1473 K with isothermal holding of the specimens for up to 20 h. We have shown that the intermetallics TiCr₂ and HfCr₂ are oxidized 2–3 times more slowly than pure titanium and hafnium, but more than 1–2 orders of magnitude faster than chromium at T≤1273 K and 4–6 times faster at 1473 K. In this temperature interval, the intermetallic ZrCr₂ is rapidly oxidized at an increasing rate as the heating temperature rises. The scaling resistance of intermetallics of Group IV d metals with chromium is determined by formation of scales in which the major role is played by the oxides TiO₂, HfO₂, and ZrO₂, with weak protective properties.     

An intrinsic observer for a class of Lagrangian systems

We propose a new design method of asymptotic observers for a class of nonlinear mechanical systems: Lagrangian systems with configuration (position) measurements. Our main contribution is to introduce a state (position and velocity) observer that is invariant under any changes of the configuration coordinates. The observer dynamics equations, as the Euler-Lagrange equations, are intrinsic. The design method uses the Riemannian structure defined by the kinetic energy on the configuration manifold. The local convergence is proved by showing that the Jacobian of the observer dynamics is negative definite (contraction) for a particular metric defined on the state-space, a metric derived from the kinetic energy and the observer gains. From a practical point of view, such intrinsic observers can be approximated, when the estimated configuration is close to the true one, by an explicit set of differential equations involving the Riemannian curvature tensor. These equations can be automatically generated via symbolic differentiations of the metric and potential up to order two. Numerical simulations for the ball and beam system, an example where the scalar curvature is always negative, show the effectiveness of such approximation when the measured positions are noisy or include high frequency neglected dynamics.     

An example of a GAS system which can be destabilized by an integrable perturbation

A construction of a globally asymptotically stable time-invariant system which can be destabilized by some integrable perturbation is given. Besides its intrinsic interest, this serves to provide counterexamples to an open question regarding Lyapunov functions.     

An exploratory study of adolescent's perceptions of the Web

Abstract The purpose of this exploratory study was to investigate the influence of two individual characteristics (Web experience and academic focus) of adolescents on the Web perception, using off-line questionnaires (a Lickert response scale) constituted on the basis of a series of interviews. Questions concerned: perceptions about the nature of information found in the Web; 'strategies' of access to the interesting Internet sites and the reliability of different information resources (libraries, television, Web, etc.). Results lead to the assumption that adolescents with high Web experience became more critical, less confident and less enthusiastic than adolescents with low Web experience and that, in some dimensions, perceptions of literature students are different to those of science students. Even if some interesting results were obtained, further research is needed to explore users' perceptions related to individuals' characteristics and to determine the generalisability of the influences identified in this exploratory study.     

Determination of shear strength values according to EN 408

This paper presents the results of 382 shear tests carried out according to EN 408. The test pieces consisted of spruce (Picea abies) and varied in density and ring width orientation (radial, tangential and at an angle of 45° to the steel plates). In addition pieces containing pith and knots were tested. The paper discusses problems observed when using this test configuration and shows that the test results do not support the characteristic shear strength values as given in EN 338. Moreover, the test results do not support the relationship between characteristic shear strength and characteristic bending strength as given in EN 384.

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Résumé Cet article présente les résultats de 382 essais de cisaillement menés conformément à EN 408. Les éprouvettes d’essai sont en épicéa (Picea abies) et présentent une variabilité en termes de masse volumique et d’orientation des cernes d’accroissement (radiale, tangentielle, à un angle de 45° par rapport aux plaques métalliques). Des éprouvettes supplémentaires contenant du cœur et des nœuds ont également été testées. L’article évoque les problèmes qui ont été mis en évidence lors de l’utilisation de ce dispositif expérimental et montre que les résultats expérimentaux ne sont pas en accord avec les valeurs caractéristiques de résistance au cisaillement données dans EN 338. De plus, ces résultats ne confirment pas la relation entre résistance caractéristique au cisaillement et résistance caractéristique à la flexion telle que stipulée dans EN 384.

     

Characteristic curves of hydrogenated amorphous silicon based solar cells modeled with the defect pool model

Using the improved expression of the defect pool model proposed by Powell and Deane we match the experimental current-voltage and the spectral response characteristic curves of hydrogenated amorphous silicon solar cells. We compare the electrical parameters resulting from using the different defect pool models published in the literature and from assuming a uniform density of dangling bond in every device layer. We discuss the applicability of the algorithm derived by Schumm for the stabilized state exploring its sensitivity to the sample history. Finally we propose an expression for stabilized cells adapting Schumm's ideas to the expression derived by Powell and Deane.     

Micromechanism of corrosion fracture of the plates of heat exchangers

We have studied the micromechanism of corrosion fracture of heat-transfer plates of a heat exchanger. The operation of heat exchangers under conditions of contamination of the plates with a sediment from water leads to their local corrosion under the sediment. The conditions of operation of the heat exchangers being equal, heat-transfer plates made of AiSi316Ti steel worked 2.36 times as long as those of AiSi304L steel. The corrosion fracture of plates under the sediment began from pitting initiation near nonmetallic inclusions of a certain nature. Afterwards, these pittings built up into corrosion spots by the mechanism of stress corrosion and hydrogen embrittlement. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 1, pp. 110–116, January–February, 2007.     

Uranium(III) in aqueous solutions: Preparation,properties, synthesis of solid compounds

Published data on the preparation procedures, stability, and complexation of U(III) in aqueous solutions are summarized and correlated. Reactions with inorganic and organic free radicals studied by the flash radiolysis method, the spectroscopic properties, the extraction and ion-exchange behavior of U(III), and methods for isolation of solid U(III) compounds from aqueous solutions are discussed.     

Femtochemistry of Guest Molecules Hosted in Colloidal Zeolites

The ultrafast deprotonation of 2‐(2′‐hydroxyphenyl)benzothiazole (HBT) hosted in nanometer‐sized FAU and MFI zeolites is reported. Samples are prepared via in‐situ incorporation of HBT in the precursor colloidal solutions resulting in the formation of nanometer‐sized zeolites under hydrothermal treatment. The diameter of the zeolite particles formed in the crystalline suspensions is determined by dynamic light scattering and high‐resolution transmission microscopy to lie in the range 40–100 nm. It is shown that the HBT loading does not influence the degree of the zeolite crystallinity but does change the size and the morphology of the individual zeolite nanoparticles. Colloidal suspensions containing the crystalline nanoparticles are well suited for optical investigations since they are sufficiently transparent and clear. The photochemical properties of the HBT guest in the zeolite‐host systems are studied with femtosecond transient transmission spectroscopy. Depending on the acid–base properties either the enol or the keto tautomer of HBT is found to be hosted in the internal voids of the zeolites; upon UV excitation, the HBT‐keto tautomer is converted to the enol form in both MFI‐ and FAU‐type hosts. The HBT photoconversion takes place via an ultrafast deprotonation within 1.5 ps as detected by femtosecond transient absorption spectroscopy.