Stretchable and Tunable Microtectonic ZnO‐Based Sensors and Photonics

The concept of realizing electronic applications on elastically stretchable “skins” that conform to irregularly shaped surfaces is revolutionizing fundamental research into mechanics and materials that can enable high performance stretchable devices. The ability to operate electronic devices under various mechanically stressed states can provide a set of unique functionalities that are beyond the capabilities of conventional rigid electronics. Here, a distinctive microtectonic effect enabled oxygen‐deficient, nanopatterned zinc oxide (ZnO) thin films on an elastomeric substrate are introduced to realize large area, stretchable, transparent, and ultraportable sensors. The unique surface structures are exploited to create stretchable gas and ultraviolet light sensors, where the functional oxide itself is stretchable, both of which outperform their rigid counterparts under room temperature conditions. Nanoscale ZnO features are embedded in an elastomeric matrix function as tunable diffraction gratings, capable of sensing displacements with nanometre accuracy. These devices and the microtectonic oxide thin film approach show promise in enabling functional, transparent, and wearable electronics.     

A formal model of atomicity in asynchronous systems

Summary We propose a generalisation of occurrence graphs as a formal model of computational structure. The model is used to define the atomic occurrence of a program, to characterise interference freeness between programs, and to model error recovery in a decentralised system.     

Interaction of guided light in rib polymer waveguides with dielectrophoretically controlled nanoparticles

This work demonstrates an optofluidic system, where dielectrophoretically controlled suspended nanoparticles are used to manipulate the properties of an optical waveguide. This optofluidic device is composed of a multimode polymeric rib waveguide and a microfluidic channel as its upper cladding. This channel integrates dielectrophoretic (DEP) microelectrodes and is infiltrated with suspended silica and tungsten trioxide nanoparticles. By applying electrical signals with various intensities and frequencies to the DEP microelectrodes, the nanoparticles can be concentrated close to the waveguide surface significantly altering the optical properties in this region. Depending on the particle refractive indices, concentrations, positions and dimensions, the light remains confined or is scattered into the surrounding media in the microfluidic channel.     

Cholesterol gallstone induction in hamsters reflects strain differences in plasma lipoproteins and bile acid profiles

Because different strains of hamsters vary in their susceptibility to gallstones, the relationship between plasma lipoproteins, hepatic cholesterol, bile lipids and bile acid profile was examined during gallstone induction in strains of male Syrian hamsters from Charles River Lakeview (CHR), Biobreeder F₁B (BIO) and Harlan Sprague-Dawley (HAR). Gallstones were induced by feeding a purified diet containing 0.4 or 0.8% cholesterol for 5 wk. Basal plasma total cholesterol was similar, but the hypercholesterolemia induced by dietary challenge was significantly lower in CHR than in HAR and BIO hamsters. Cholesterol-fed CHR hamsters transported cholesterol mainly in HDL (47%), whereas VLDL-C+IDL-C predominated in BIO and HAR hamsters, and their HDL transported only 28 and 38%, respectively. HAR hamsters accumulated the most hepatic cholesterol, revealed the highest cholate/cheno ratio, the lowest glycine/taurine ratio and hydrophobicity index. HAR also developed the fewest cholesterol gallstones (23%), while 64% of CHR and 58% of BIO hamsters had cholesterol gallstones and 34% of BIO hamsters developed pigment stones. Doubling dietary cholesterol from 0.4 to 0.8% doubled the incidence of cholesterol gallstones but exerted minimal impact on other parameters compared to strain differences. Thus, different strains of hamsters vary considerably with respect to biliary cholesterol, bile acid profile and formation of cholesterol gallstones associated with differences in plasma lipoprotein profiles.     

Instantiability of RSA-OAEP Under Chosen-Plaintext Attack

We show that the widely deployed RSA-OAEP encryption scheme of Bellare and Rogaway (Eurocrypt 1994), which combines RSA with two rounds of an underlying Feistel network whose hash ( i.e., round) functions are modeled as random oracles, meets indistinguishability under chosen-plaintext attack (IND-CPA) in the standard model based on simple, non-interactive, and non-interdependent assumptions on RSA and the hash functions. To prove this, we first give a result on a more general notion called “padding-based” encryption, saying that such a scheme is IND-CPA if (1) its underlying padding transform satisfies a “fooling" condition against small-range distinguishers on a class of high-entropy input distributions, and (2) its trapdoor permutation is sufficiently lossy as defined by Peikert and Waters (STOC 2008). We then show that the first round of OAEP satisfies condition (1) if its hash function is t-wise independent for t roughly proportional to the allowed message length. We clarify that this result requires the hash function to be keyed, and for its key to be included in the public key of RSA-OAEP. We also show that RSA satisfies condition (2) under the \(\Phi \)-Hiding Assumption of Cachin et al. (Eurocrypt 1999). This is the first positive result about the instantiability of RSA-OAEP. In particular, it increases confidence that chosen-plaintext attacks are unlikely to be found against the scheme. In contrast, RSA-OAEP’s predecessor in PKCS #1 v1.5 was shown to be vulnerable to such attacks by Coron et al. (Eurocrypt 2000).     

Synthesis of (all‐rac)‐α‐Tocopherol Using Fluorinated NH‐Acidic Catalysts

The synthesis of (all‐rac)‐α‐tocopherol starting from trimethylhydroquinone and isophytol using fluorinated NH‐acidic catalysts is described. Scope and limitations of this type of catalysts are discussed. Advantages of this new procedure are high yield and selectivity, no waste problem and mild reaction conditions. Best results in the synthesis of (all‐rac)‐α‐tocopherol (94% yield) using NH‐acidic compounds are obtained in polar solvents. The used catalyst could be recovered.     

Partially reversible adsorption of annexin A1 on POPC/POPS bilayers investigated by QCM measurements, SFM, and DMC simulations

The kinetics of annexin A1 binding to solid-supported lipid bilayers consisting of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC)/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphoserine (POPS; 4:1) has been investigated as a function of the calcium ion concentration in the bulk phase. Quartz crystal microbalance measurements in conjunction with scanning force microscopy, fluorescence microscopy, and computer simulations indicate that at a given Ca2+ concentration annexin A1 adsorbs irreversibly on membrane domains enriched in POPS. By contrast, annexin A1 adsorbs reversibly on the POPC-enriched phase, which is composed of single POPS molecules embedded within a POPC matrix. The overall area occupied by the POPS-enriched phase is controlled by the CaCl2 concentration. Monte Carlo simulations suggest that the area of the POPS-enriched phase increases by a factor of 7 when the Ca2+ concentration is changed from 0.01 to 1 mM.