A 60 GHz phased array with measurement and de-embedding techniques

We present a 60 GHz phased array system that combines several key technologies to realize 10 GHz bandwidth coverage. Particularly, a tightly coupled dipole array centered at 60 GHz is designed and tested for its wideband performance. The tightly coupled dipole elements offer excellent wideband behavior of 10 GHz with voltage standing wave ratio?<?3 with scanning to 45°, as well as low cost printed circuit board fabrication. Additionally, we demonstrate a measurement setup with de-embedding procedure to measure gain at the antenna feed point. A feeding structure was designed and fabricated for de-embedding gain pattern measurements. Recovered measurements are shown to be in agreement with simulation.     

Implementation of response surface methodology to optimise extraction of onion (Allium cepa) solid waste phenolics

An experimental setup based on a 2³-full factorial, central composite design was implemented with the aim to optimising recovery of polyphenols from onion solid wastes (OSW). In order to allow for the establishment of a sustainable process, reusable and non-toxic solutions composed of water/ethanol/citric acid were employed as extracting media. The factors considered were (i) the pH of the medium, (ii) the extraction time and (iii) the ethanol concentration. The model obtained produced a satisfactory fitting of the experimental data with regard to total polyphenol extraction (R² = 0.97, p = 0.0025) and the reducing power of the extracts (R² = 0.97, p = 0.0033), but not with the antiradical activity (R² = 0.89, p = 0.0592). The 2nd order polynomial equations obtained after elaboration of the experimental data indicated that all parameters considered were significant in respect with the efficiency of total polyphenol recovery. The highest total polyphenol yield was theoretically predicted to be 9342 ± 1435 mg gallic acid equivalents per 100 g dry weight, under optimal conditions (60% EtOH, pH 2 and 4.2 h). Liquid chromatography-electrospray ionisation mass spectrometry of the optimally obtained extract revealed that the principal phytochemicals recovered were quercetin 3,4′-diglucoside, quercetin 4′-glucoside and quercetin. Simple linear regression analysis between the total polyphenol and the antiradical activity of the OSW extracts showed that there was no correlation in a statistically significant manner, as opposed to reducing power.Industrial relevanceThe recovery of value-added substances from agri-food industrial wastes is an issue with importance pertaining to both the reduction of the waste load released to the environment, and the development of novel, natural food additives with functional properties. Up to date, the examinations pertaining to the clarification of factors that can affect extractability were based on rather unilateral assessment, while it is generally accepted that the retrieval depends on several parameters, which render the phenomenon a particular complexity. In this view, the implementation of factorial design with respect to investigating in parallel several factors pertaining to efficient polyphenol recovery becomes imminent. Thus the establishment of models on such a sound experimental basis is expected to provide a reliable background for more costand resource-effective processes, with a potential direct industrial applicability.     

Surface area production during grinding

During grinding, in cascading mills, the mass distribution of the material moves continuously to finer sizes. Grinding models are usually designed to predict the size distribution of the mill products either as a function of effective breakage events and the time or the energy consumed by the mill. Mill products are always tested for their size analysis and their fineness is usually expressed as the size d through which a certain amount of material passes, i.e. d₈₀. However, particulate materials have some supplementary properties that a grinding model should predict as well. The specific surface area is such an important supplementary property. Initially, the present work examines the relationship between mass distribution and the surface area of ground materials and determines the conditions under which, mass distribution can be used to determine the surface area. Based on these findings the work further examines the operating conditions of a cascading mill under which the surface area of the material increases at the highest rate. The operating parameter examined is the mill load ratio expressed as the mass ratio of mill grinding media and the material present in the mill.     

Mechanical properties and cytotoxicity of 3Y-TZP bioceramics reinforced with Al2O3 particles

The influence of Al₂O₃ addition and sintering parameters on the mechanical properties and cytotoxicity of tetragonal ZrO₂–3 mol% Y₂O₃ ceramics was evaluated. Samples containing 0, 10, 20 and 30 wt.% of Al₂O₃ particles were prepared by cold uniaxial pressing (80 MPa) and sintered in air at 1500, 1550 and 1600 °C for 120 min. The effects of the sintering conditions on the microstructure were analyzed by X-ray diffraction analysis and scanning electron microscopy. Hardness and fracture toughness were determined by the Vickers indentation method and the mechanical resistance by four-point bending tests. As a preliminary biological evaluation, “in vitro” cytotoxicity tests were realized to determine the cytotoxic level of the ZrO₂–Al₂O₃ composites, using the neutral red uptake method with NCTC clones L929 from the American Type Culture Collection (ATCC) bank. Fully dense ceramic materials were obtained with a hardness ranging between 1340 HV and 1585 HV, depending on the amount of Al₂O₃ in the ZrO₂ matrix. On the other hand, no significant influence of the Al₂O₃ addition on fracture toughness was observed, exhibiting values near 8 MPa m^1/2 for all compositions and sintering conditions studied. The non-cytotoxic behavior, the elevated fracture toughness, the good bending strength (σ_f = 690 MPa) and the elevated Weibull's modulus (m = 11) exhibited by the material, show that these ceramic composites are highly suitable biomaterials for dental implant applications.     

Structural, photoluminescent and electrical properties of CdTe films with different compositions fabricated by CMBD

CdTe films with different compositions (Cd-rich, Te-rich and stoichiometric) were fabricated by a novel and low cost chemical molecular beam deposition method (CMBD) in atmospheric pressure hydrogen flow. Cd and Te granules were used as precursors. The films were deposited on ceramic (SiO₂:Al₂O₃) substrates at 580 °C and 600 °C. The growth rate was varied in the range of 9-30 Å/s. The composition (Cd/Te) of the samples was changed by controlling the molecular beam intensity (MBI) ratio. Three samples fabricated at MBI ratios Cd/Te = 0.5, 1.0 and 1.16 were investigated by XRD, AFM, EDX, SEM, photoluminescence (PL) and Hall methods.     

Physico-chemical characterisation of a non-conventional food protein source from earthworms and sensory impact in arepas

This study aimed to characterise a non-conventional protein source: a powder made from earthworms, and to evaluate its potential use as human food. The way it was prepared led to low solubility and wide particle size distribution. Sensory analysis was used to assess the acceptability and the organoleptic properties of maize-based pan-cakes fortified with this novel protein powder. Satisfying products were obtained with a substitution level of 5.5% (w/w) earthworm powder in pan-cakes. GC-MS allowed the identification of more than seventy volatile compounds that may be responsible for the off-odour of the powder. The most abundant chemical groups found in the volatile fraction were ketones with undecan-2-one, alcohols with pentan-1-ol, and aldehydes with hexanal. Partial delipidation was tested as a way to improve the organoleptic quality of the powder. It clearly led to less intensely coloured samples but delipidation must be optimised to have an impact on odour.     

Distributed uplink scheduling and rate control in cdma2000 using adaptive antenna arrays

Distributed uplink scheduling and rate control in CDMA networks are considered in the case of adaptive antenna arrays present at the base station. The system model with omnidirectional antennas is generalized to the case where adaptive antenna arrays are deployed. Rate control in a probabilistic manner is investigated. Long-term control by the base station through token bucket constraints is incorporated in the system. Monte Carlo simulation results show considerable improvement when adaptive antenna arrays are used. Optimization of the rate transition probabilities is treated in the special case of on–off scheduling.     

Field-Assisted Ion Exchange in Type III Silica

Field-assisted ion exchange of protons in type III silica for Cs or Nu ions from a molten salt was investigated. Although electrolysis occurred, infrared measurements showed no change in hydroxyl content after ion exchange for extended periods. Scanning electron microprobe studies of cesium-exchanged specimens revealed a high-cesium-content layer =2,μm thick; this layer is believed to result from surface reaction with the molten salt.     

Redefining the Water Poverty Index

Abstract

The Water Poverty Index (WPI) of arid and semiarid climatic zones is redefined by introducing the contribution of rainfed agriculture into WPI calculations and by making the WPI equation account for diversities in climatic conditions within arid and semiarid zones and for recycled household water used in irrigation.