On Barenblatt's problem

The problem of flow in media with double porosity (e.g. fissured rocks) is considered by utilizing the author's concept of “multiporosity” and employing the apparatus of continuum theory of mixtures. Relevant results obtained by Barenblatt et al. within the Russian literature are shown to be contained in the present theory.     

Inverted-annular film boiling heat transfer from vertical surfaces

A theoretical model is developed which allows a consistent treatment of the wall heat flux in an inverted-annular film boiling regime. The model is based on an analytical solution of the energy conservation equations in the vapor and liquid regions downstream of the quench front. A constant vapor film thickness is assumed, which depends on the fluid equilibrium quality at the quench front. Good agreement is obtained in comparing the model with quasi-steady state experimental results.     

Smart polyoxometalate-based nitrogen monoxide sensors

An electrochemical sensor design for selective NO detection is presented based on a polyoxometalate (POM) cluster immobilized on an electrode through a polyelectrolyte matrix. It is suggested that the POM can electrocatalyze the reduction of NO. The reduction current is proportional to the NO concentration in the investigated concentration window ranging from 1 nM to 10 microM. The sensitivity of the device can be adjusted by the number of immobilized layers. The response to possible interfering reagents such as nitrate and nitrite can be controlled through the multilayer design. By a predominant negatively charged outer surface, the response to these ions is markedly reduced.     

Investigations of the deposition of lead-bearing aerosols on the surfaces of vegetation

SEM and X-ray microprobe analysis were combined with clean lab technology atomic absorption spectroscopy to observe the deposition of aerosols on undisturbed pine needle surfaces, to obtain physical and chemical information from the observed particles and to chemically remove these particles for analysis. Comparisons were made among sites with traffic densities of 100, 1000, 10000 cars per day. Correlations were made with periods of heavy rainfall. The results show that the particle size distribution, shape and surface chemistry are possibly characteristic of automotive exhausts, that both the chemical washing procedure and rainfall efficiently remove most particles from the surface, including those bearing lead, and that the rate of deposition is constant between rainfalls and partly a function of traffic density. Deposition rates of 0.3 ng Pb cm^?2 day^?1 were observed at 100 cars per day, 2–3 ng Pb cm^?2 day^?1 for 1000 and 10000 cars per day.