助卷辊电液伺服系统相关辨识法研究

用相关辨识法分析了卷取机助卷辊电液伺服系统的频率特性 ,采用 Levy法求出系统的传递函数 ,并且给出该系统频率特性相关参数。     

韩国不锈无缝钢管工业考察

详细介绍了韩国三美（ＳＡＭＭＩ）钢公司的不锈无缝钢管生产设备及工艺。     

稳定态二氧化氯杀菌剂的制备及应用

稳定态二氧化氯(C1O2)是一新型杀菌消毒剂，具有高效、广谱、安全的特性，适用范围广，不产生对人体有害物质。介绍了稳定态ClO2的性质、检测、制备条件及其在有关领域的应用。     

风力发电机塔架的涂装

按照设计要求制备用于风力发电机塔架的防腐蚀配套涂料,塔架的筒体内部涂层由环氧树脂聚酰胺富锌底漆和环氧树脂聚酰胺云母氧化铁中涂漆组成,筒体外部涂层由环氧树脂聚酰胺富锌底漆、环氧树脂聚酰胺云母氧化铁中涂漆和丙烯酸脂肪族聚氨酯面漆组成。该涂料体系的防腐涂层可常温固化,厚度达到275μm,防腐蚀寿命可达20年之久,其防腐效果、耐冲击性和耐候性良好。文章同时讨论了涂装工艺过程中易出现的问题及解决办法。     

活性炭对海水中硼的吸附研究

未处理的生活污水和海水中均含有一定量的硼，给人们的生产和生活带来严重影响，因此，微量硼的分离与去除意义重大。利用活性炭吸附法吸附溶液中的微量硼，对其影响因素如接触时间、吸附质质量浓度、pH、吸附剂量及温度等进行了研究，并对比了动静态吸附及酸碱再生效果，确定了适宜的实验条件。应用该法吸附某海水中的微量硼，其一次除硼率可达90％以上，硼质量浓度达到WHO规定饮用水的要求。     

均相催化水合法合成乙二醇动力学研究

在反应温度为45～75℃,NY 健化剂浓度为0.093mol/L,水比为6～10的反应条件下,对均相催化水合法合成乙二醇动力学进行了研究。测定了反应速率常数及反应过程中溶液 pH 值的变化。依据实验结果,提出了反应机理,建立了反应动力学方程,并利用 Levenberg-Marquardt 方法回归了动力学参数。研究结果表明:在 NY 催化剂存在下,均相催化水合法合成乙二醇反应对环氧乙烷浓度是一级反应,其表观活化能为71113.8 J/mol 和指前因子3.05×10~9 min~(-1)。相对直接水合法而言,NY 催化剂降低了反应的活化能,大大提高了反应速度。     

Surface Chemical Modification of Poly(Methylphenylphosphazene)

Summary The surface reactivity of poly(methylphenylphosphazene), PMPP, and its derivatives containing silane, PMPP-SiH, and alcohol, PMPP-OH, substituents was investigated. These polymers were fabricated into films by casting from THF solutions and reactions were carried out at the interface between solid film samples and solutions. The surface of PMPP was successfully modified by deprotonation under dilute conditions followed by reactions with RMe₂SiCl [where R = CH=CH₂, and H]. While surfaces of PMPP-OH were not readily modified, those containing Si-H groups reacted with oxygen when heated and with carbon tetrachloride. The polymer surfaces were examined by contact angle measurements, attenuated total reflectance infrared spectroscopy (ATR-IR), and scanning electron microscopy (SEM). We dedicate the paper to Christopher W. Allen in recognition of his outstanding contributions to inorganic ring and polymer chemistry.     

Cu/SBA-15 as adsorbent for propane/propylene separation

Samples of mesoporous silica SBA-15 were prepared under hydrothermal conditions where Cu cations were incorporated to the structure by impregnation in order to compare the adsorption behavior in the presence and absence of this element. The adsorption/desorption equilibrium isotherms of propylene, propane, and N₂ were measured to evaluate their usefulness in the propane/propylene separation. All the adsorption isotherms of SBA-15 measured in the absence of Cu cations were described by the Freundlich equation, while the adsorption isotherms of propane on Cu/SBA-15 were better represented by the Henry equation and those of propylene were satisfactorily described by the Langmuir model in the range P < 100 Torr. The adsorption uptake of propylene increased and that of propane decreased in Cu/SBA-15 as compared to the amounts observed in the SBA-15 sample. The presence of Cu atoms in the adsorbent lattice increased the selectivity towards propylene. Under some working conditions the adsorbed amount of propylene in Cu/SBA-15 sample was totally reversible and the propane uptake, negligible.     

纳米Fe2O3的制备与气敏性质的研究

报道了纳米氧化铁的制备工艺，采用沉淀法、溶胶凝胶法制备了纳米α-Fe2O3、γ-Fe2O3粉体，用热重－差热分析（TG－DTA）、X射线衍射（XRD）、透射电镜（TEM）和二次粒度分布对粒子进行表征，并制作了气体敏感元件。讨论了纳米氧化铁的制备工艺对气敏性质的影响。     

SERCOS Ⅱ在注塑机全电动设计中的应用

针对传统注塑机在加工精度、加工效率上的不足，提出一种全电子注塑机的控制方案，介绍了基于SERCOSⅡ实时系统的运动控制方法，分析了实现注塑过程的高速高精度的硬件体系。在试验样机3个月的连续工作中，当周期循环时间为4ms，注射量最大达到80cm^3时，产品的成型周期能够控制在15s以内，注出产品的质量、精度均满足要求，表明该设计切实可行。