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The alginate thickener is the thickener frequently used for reactive printing of textile. The thickener responds with reactive pigments and thus does not lead to the fabric composition becoming stiffer. In this study, we prepared oxidised natural guar gum with hydrogen peroxide, sodium hypochlorite and sodium hydroxide. All other polysaccharides comprise reactive hydroxyl units with a stronger reactivity that must be replaced if they are to be used in reactive printing. Guar derivatives were synthesised and verified using Fourier-transform infrared (FTIR) spectroscopy. Natural thickeners, synthetic guar gum derivatives, have been employed in textile printing technique. In comparison to other synthetic thickeners, modified environmental guar gum polymer has been shown to be an ecologically friendly and low-cost thickener. Cotton fabric printed with modified guar thickening with hydrogen peroxide has even stronger colour strength than fabric printed with sodium alginate thickener, which is highly favourable. Penetration properties, colour value, colour strength, colour fastness to washing, light and rubbing was compared with alginate thickener (readily available on the market). Guar gum thickeners showed enhanced features versus sodium alginate for reactive printing. Partially replaced guar gum is an appropriate option due to the colour and physical properties.  相似文献   
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This study aims to predict the coercivity of cobalt nanowires fabricated by Alternating Current (AC) pulse. Coercivity is one of the most important properties of magnetic materials and its value shows the needed magnetic field in a way that magnetization of system is decreased to zero. There are many parameters such as pH of solution, oxidative and reductive times, oxidative and reductive voltages, interval between pulses (off-time), and concentration of deposition solution that have direct effect on materials magnetic properties of. Change of initial conditions to obtain the best results is very time consuming, therefore employing a method which can save both the time and cost is necessary. Hence, it this study Artificial Neural Network (ANN), which has numerous applications and has attracted many attentions in various fields, was applied. Through this study, an ANN was designed to present a template that is capable for predicting output data (coercivity) according to input data (pH, oxidative and reductive times, oxidative and reductive voltages, and off-time). Besides, in this research, the results for pH = 4 and 6 were investigated and the effect of off-time as well as the deposition time on coercivity were studied.  相似文献   
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In this study, poly(l ‐lactide) (PLA) is melt‐blended with thermoplastic polyurethane (TPU) to modify the brittleness of PLA. An aliphatic ester‐based TPU was selected in order to have an ester sensitivity for degradation and an inherent biocompatibility. Using this compatible TPU, there was no need to apply problematic compatibilizers, so the main positive properties of PLA such as biocompatibility and degradability were not challenged. The detected microstructure of PLA/TPU blends showed that when the TPU content was lower than 25 wt %, the structure appeared as sea‐islands, but when the TPU content was increased, the morphology was converted to a cocontinuous microstructure. A higher interfacial surface area in the blend with 25 wt % TPU (PLA25) resulted in a higher toughness and abrasion resistance. The various analyses confirmed interactions and successful coupling of two phases and confirmed that melt‐blending of PLA with the aliphatic ester‐based TPU is a convenient, cost‐effective, and efficient method to conquer the brittleness of PLA. The prepared blends are general‐purpose plastics, but PLA25 showed an optimum mechanical strength, toughness, and biocompatibility suitable for a wide range of applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43104.  相似文献   
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A thermodynamic analysis of propane dehydrogenation with carbon dioxide was performed using constrained Gibbs free energy minimization method. Different reaction networks corresponding to different catalytic systems, including non-redox and redox oxide catalysts, were simulated. The influences of CO2/C3H8 molar ratio (1–10), temperature (700–1000 K), and pressure (0.5–5 bar) on equilibrium conversion and product composition were studied. In the presence of CO2 with a molar ratio of CO2/C3H8 = 1, the temperature of dehydrogenation can be 30 K lower than that of dehydrogenation in the presence of steam (H2O/C3H8 = 1) and about 50 K lower than that of simple dehydrogenation without dilution to achieve 60% propane conversion. It was found that the occurrence of dry reforming of propane and coke-forming side reactions could strongly impact the equilibrium product composition of the multireaction system and, therefore, these reactions should be kinetically controlled. Comparison of the simulated reactant conversions with those reported in the literatures revealed that the experimental conversion levels of propane are far below the corresponding equilibrium values due to rapid catalyst deactivation by coke, implying that research efforts should be directed toward formulation of more active and selective catalysts.  相似文献   
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Chitosan (CS) and hydrophobic‐modified chitosan (HM‐CS) chains were wrapped onto multiwalled carbon nanotubes (MWNTs) and introduced to polyvinyl alcohol (PVA) matrices as nanohybrid conductive polymer composites (CPCs) for detection of polar vapors. The effect of grafted alkyl groups on polarity of CS chains were studied by quantum mechanics (QM). The designed composites were applied as sensitive layers to clarify the response mechanism in CPCs gas sensors. It was realized that the wrapped biopolymers intensely influenced the sensitivity of the composites. Experiment results specified that the nature of biomacromolecules and their interactions with vapor molecules affects the resistance change in CPCs. The higher interaction of CS with polar vapor molecules caused more plasticization of polymer segments in the MWNTs connections. Such phenomenon enhanced the resistance change in the presence of analytes. Moreover, it was inferred that the semiconductor character of MWNTs has an important effect in the final signals. The more polar structure of CS in comparison with HM‐CS enhanced the adsorption of vapor molecules on the surface of MWNTs, and the electron donor analytes decreased the conductivity of p‐type MWNTs increasing the final responses. The presented results corroborate that the performance of CPCs gas sensors could be finely tuned through manipulation of the nanointerfaces. POLYM. COMPOS., 37:2803–2810, 2016. © 2015 Society of Plastics Engineers  相似文献   
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Electrophoretic deposition (EPD) is a versatile technique that has drawn attention due to its ease of use and performance in depositing high-quality layers at room temperature. This technique principle is based on the deposition of charged particles from a stable colloidal suspension on a conductive substrate using either a direct or alternating current. Using relatively simple and low-cost equipment, the EPD technique enables the deposition of layers with controlled microstructures at nanoscale. The EPD technique has been particularly successful in the fabrication of the electrocatalyst layers for low-temperature fuel cells, which are anchored on the top of the fuel cell electrodes. In comparison with other electrocatalyst layer deposition techniques such as drop-casting, the EPD technique offers clear advantages for the control of the thickness and packing density of the electrocatalyst layers. Owing to the dense packing density, electrocatalyst layers deposited by EPD could achieve enhanced conductivity and efficiency. The present review aims at comprehensively evaluating the recently published results on the electrocatalyst layers fabricated by EPD and applied in oxygen reduction reactions, alcohol electro-oxidation reactions, hydrogen evolution reactions, and oxygen evolution reactions.  相似文献   
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This paper develops and validates the first principle based numerical method for predicting the noise radiated from the rotating Horizontal-Axis Wind Turbine (HAWT) blades. The noise radiated to the far-field was predicted by the code based on Ffowcs Williams–Hawkings (FW–H) equation, using both original non-permeable formulation and permeable formulation. A commercially available CFD solver, ANSYS CFX 11.0, was used to calculate the flow parameters on and around the blade surface that are required for FW–H codes. A capability of the solver for modelling the flow field around the wind turbine blades was validated by comparing with the experimental results of NREL phase VI wind turbine blades. The FW–H codes were validated using acoustic results of UH-1H helicopter rotor in hover and Hartzell aircraft propeller in forward motion, which were measured in anechoic wind tunnel facility. Then the developed FW–H acoustic codes were applied to calculate the noise radiated from NREL Phase VI wind turbine blades.  相似文献   
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用特征曲线法确定油井水侵途径   总被引:1,自引:0,他引:1  
对油井水淹动态进行分析,准确确定油井出水原因,是提高堵水工艺措施效果的关键。常规的油井出水原因分析方法,因本身的局限性,或是费用高而使其应用受到限制。所提出的含水特征曲线方法能够有效地分析机械采油井、自喷井及停产井的含水动态,并能够简捷地确定油井的出水原因。  相似文献   
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