Solution‐Processed Nanoporous Organic Semiconductor Thin Films: Toward Health and Environmental Monitoring of Volatile Markers

Porous materials are ubiquitous in nature and have found a wide range of applications because of their unique absorption, optical, mechanical, and catalytic properties. Large surface‐area‐to‐volume ratio is deemed a key factor contributing to their catalytic properties. Here, it is shown that introducing tunable nanopores (50–700 nm) to organic semiconductor thin films enhances their reactivity with volatile organic compounds by up to an order of magnitude, while the surface‐area‐to‐volume ratio is almost unchanged. Mechanistic investigations show that nanopores grant direct access to the highly reactive sites otherwise buried in the conductive channel of the transistor. The high reactivity of nanoporous organic field‐effect transistors leads to unprecedented ultrasensitive, ultrafast, selective chemical sensing below the 1 ppb level on a hundred millisecond time scale, enabling a wide range of health and environmental applications. Flexible sensor chip for monitoring breath ammonia is further demonstrated; this is a potential biomarker for chronic kidney disease.     

Thermodynamic Equilibrium Analysis of Propane Dehydrogenation with Carbon Dioxide and Side Reactions

A thermodynamic analysis of propane dehydrogenation with carbon dioxide was performed using constrained Gibbs free energy minimization method. Different reaction networks corresponding to different catalytic systems, including non-redox and redox oxide catalysts, were simulated. The influences of CO₂/C₃H₈ molar ratio (1–10), temperature (700–1000 K), and pressure (0.5–5 bar) on equilibrium conversion and product composition were studied. In the presence of CO₂ with a molar ratio of CO₂/C₃H₈ = 1, the temperature of dehydrogenation can be 30 K lower than that of dehydrogenation in the presence of steam (H₂O/C₃H₈ = 1) and about 50 K lower than that of simple dehydrogenation without dilution to achieve 60% propane conversion. It was found that the occurrence of dry reforming of propane and coke-forming side reactions could strongly impact the equilibrium product composition of the multireaction system and, therefore, these reactions should be kinetically controlled. Comparison of the simulated reactant conversions with those reported in the literatures revealed that the experimental conversion levels of propane are far below the corresponding equilibrium values due to rapid catalyst deactivation by coke, implying that research efforts should be directed toward formulation of more active and selective catalysts.     

Plasticity modeling of FRP-confined circular reinforced concrete columns subjected to eccentric axial loading

This paper presents a numerical study on FRP-wrap strengthened reinforced concrete columns subjected to eccentric axial loads using ABAQUS®. For modeling of concrete dilation under non-uniform confinement pressure, a smooth cap plasticity model was combined with concrete damaged plasticity model. This model includes different concrete compaction–dilation behaviors which is pressure-dependent. Proposed model has been calibrated and verified for concrete in number of unconfined and full-wrapped columns under combination of axial force and bending moment. Presented numerical predictions are shown to be in close agreement with existing experimental results. The effect of laminate stacking sequences and column slenderness on strength and ductility of members was examined thoroughly. The results of this study recommend taking fiber angles between zero (circumferential) and 30° can improve ultimate strength and ductility of confined short concrete columns. However, for slender concrete columns the optimum fiber orientation can be set between 15° and 30°.     

Role of Heat Transfer in Early Stage Decarburization of DRI in Slag

The gas generation from reactions between direct reduced iron (DRI) pellets and steelmaking slags is known to take place in two stages; (1) the reaction of FeO and carbon within DRI, i.e., pellet internal reaction, followed by (2) the reduction of slag FeO with DRI carbon at the pellet?Cslag interface, if any carbon remains from the first step. To understand the controlling mechanism of the reaction between FeO and C inside DRI, the rate of the gas release and the temperature of pellets suspended in a slag-free atmosphere were quantified. The results were used to determine the apparent thermal conductivity of DRI that showed values of approximately 0.5 to 2 W.m^?1.K^?1 for a temperature range of 573?K to 1273?K (300?°C to 1000?°C). Furthermore, it was found that the experimental gas evolution rates are consistent with the values predicted by a heat?Ctransfer based model, confirming that the FeO-C reaction within pellet is controlled by the rate of heat transfer from the slag to the DRI pellet.     

Facial expression recognition by using differential geometric features

ABSTRACT

In recent years, a growing interest has been created for improvement of human interaction with computers. Hence, automatic recognition of facial expressions has become one of the active research topics. The purpose of this paper is to identify facial expressions, by using differential geometric features. In the proposed method, only the first and last images are used and differential features are extracted from these two images. Differential geometric features are extracted from changes in the important points of the face in the two images. In this method, the distance between the important points of the face and the reference point was calculated in both directions x and y, for two images, and with the difference between the distance, the differential geometric features between the two images were obtained. Based on the results, with this method, recognition accuracy of six facial expressions in the database was 96.44%, CK +.     

Triple-layer proton exchange membranes based on chitosan biopolymer with reduced methanol crossover for high-performance direct methanol fuel cells application

A novel triple-layer proton exchange membrane comprising two thin layers of structurally modified chitosan, as methanol barrier layers, both sides coated with Nafion^®105 is prepared and tested for high-performance direct methanol fuel cell applications. A tight adherence is detected between layers from SEM and EDX data for the cross-sectional area of the newly designed membrane, which are attributed to high affinity of opposite charged polyelectrolyte layers. Proton conductivity and methanol permeability measurements show improved transport properties for the multi-layer membrane compared to Nafion^®117 with approximately the same thickness. Moreover, direct methanol fuel cell tests reveal higher open circuit voltage, power density output, and overall fuel cell efficiency for the triple-layer membrane than Nafion^®117, especially at concentrated methanol solutions. A power output of 68.10 mW cm^?2 at 5 M methanol feed is supplied using multi-layer membrane, which is found to be about 72% more than that of for Nafion^®117. In addition, fuel cell efficiency for multi-layer membrane is measured about 19.55% and 18.45% at 1 and 5 M methanol concentrations, respectively. Owing to the ability to provide high power output, significantly reduced methanol crossover, ease of preparation and low cost, the triple-layer membrane under study could be considered as a promising polyelectrolyte for high-performance direct methanol fuel cell applications.     

Expanding a performance improvement initiative in critical care from hospital to system

BACKGROUND: Concern about the expense and effects of intensive care prompted the development and implementation of a hospital-based performance improvement initiative in critical care at North Shore University Hospital, Manhasset, New York, a 730-bed acute care teaching hospital. THE HOSPITAL-BASED PERFORMANCE IMPROVEMENT INITIATIVE IN CRITICAL CARE: The initiative was intended to use a uniform set of measurements and guidelines to improve patient care and resource utilization in the intensive care units (ICUs), to establish and implement best practices (regarding admission and discharge criteria, nursing competency, unplanned extubations, and end-of-life care), and to improve performance in the other hospitals in the North Shore-Long Island Jewish Health System. In the medical ICU, the percentage of low-risk (low-acuity) patients was reduced from 42% to 22%. ICU length of stay was reduced from 4.6 days to 4.1 days. IMPLEMENTING THE CRITICAL CARE PROJECT SYSTEMWIDE: A system-level critical care committee was convened in 1996 and charged with replicating the initiative. By and large, system efforts to integrate and implement policies have been successful. The critical care initiative has provided important comparative data and information from which to gauge individual hospital performance. DISCUSSION: Changing the critical care delivered on multiple units at multiple hospitals required sensitivity to existing organizational cultures and leadership styles. Merging organizational cultures is most successful when senior leadership set clear expectations that support the need for change. The process of collecting, trending, and communicating quality data has been instrumental in improving care practices and fostering a culture of safety throughout the health care system.     

The effect of sintering time on the densification and mechanical properties of a mechanically alloyed Cr–Mn–N stainless steel

Sintering is an essential stage in powder metallurgy, which affects the final microstructure and performance of the part. This study is concerned with the sintering and mechanical behaviors of Fe–18Cr–8Mn–0.9N stainless steel prepared from mechanically alloyed amorphous/nanocrystalline powders. The contribution of sintering time to the densification at 1100 °C is considered and a sluggish densification is found for the alloy. Furthermore, the correlation between the microstructure and mechanical properties of the fabricated porous parts is studied. It is found that the yield stress is affected by both porosity and the material’s intrinsic yield strength. Nonetheless, the effect of porosity on the overall hardness typically prevails over the effect of matrix hardness. Interestingly, even after sintering at 1100 °C for up to 20 h, the nanometric structure of the material is retained.     

Uncertainty based distributed generation expansion planning in electricity markets

Decision making under uncertainty is a difficult task in most areas. The distributed generation expansion planning is certainly one of the problems where it is difficult to find an optimal solution for, due to the existence of various uncertain parameters that affect the optimal solution. This paper presents a distributed generation planning strategy based on the multi-objective decision making (MODM) approach under uncertainties. The proposed strategy achieves a Pareto set of locations, sizes, and typical types, for new DG installations in a case-study power network (as the result of a multi-objective optimization). The technical constraints of DG units are also considered in the MODM process. The effects of the uncertain parameters on choosing the best plan(s) are considered using robustness, flexibility, and risk exposure attributes. This aim is performed based on a composite index which is weighted sum of the three mentioned attributes. This paper considers four categories of uncertain parameters including the peak loading factor, electricity market price, and investment and operating costs for the DG long-term planning.     

Retracted papers by Iranian authors: causes,journals, time lags,affiliations, collaborations

Scientometrics - This study aims to analyze 343 retraction notices indexed in the Scopus database, published in 2001–2019, related to scientific articles (co-)written by at least one author...