On a non-linear formulation for curved Timoshenko beam elements considering large displacement/rotation increments

An incremental Total Lagrangian Formulation for curved beam elements that includes the effect of large rotation increments is developed. A complete and symmetric tangent stiffness matrix is obtained and the numerical results show, in general, an improvement over the standard formulation where the assumption of infinitesimal rotation increments is made in the derivation of the tangent stiffness matrix.     

The treatment of sulfate-rich wastewater using an anaerobic sequencing batch biofilm pilot-scale reactor

This paper presents the results from 92 cycles of an anaerobic sequencing batch biofilm reactor containing biomass immobilized on inert support (mineral coal) applied for the treatment of an industrial wastewater containing high sulfate concentration. The pilot-scale reactor, with a total volume of 1.2 m³, was operated at sulfate loading rates ranging from 0.15 to 1.90 kgSO₄²⁻/cycle (48 h — cycle) corresponding to sulfate concentrations of 0.25 to 3.0 gSO₄²⁻ l^− 1. Domestic sewage and ethanol were utilized as electron donors for sulfate reduction. Influent sulfate concentrations were increased in order to evaluate the minimum COD/sulfate ratio at which high reactor performance could be maintained. The mean sulfate removal efficiency remained between the range of 88 to 92% at several sulfate concentrations. Temporal profiles along the 48 h cycles were carried out under stable operation at sulfate concentrations of 1.0, 2.0 and 3.0 gSO₄²⁻ l^− 1. Sulfate removal reached 99% for cycle times of 15, 25, and 30 h, and the effluents sulfate concentrations were lower than 8 mgSO₄²⁻ l^− 1. The results demonstrate the potential applicability of the anaerobic configuration for the biological treatment of sulfate-rich wastewaters.     

Hybrid photocatalysts for the degradation of trichloroethylene in air

Hybrid photocatalysts based on an adsorbent SiMgOx and a photocatalyst TiO₂ were developed in a plate shape. The ceramic surface was coated with TiO₂ by the slip-casting technique. The effect of the support in the photocatalytic degradation of trichloroethylene (TCE) was analyzed by modifying TiO₂ loading and the layer thickness. Photocatalysts were characterised by N₂ adsorption–desorption, mercury intrusion porosimetry, SEM, UV–vis spectroscopy and XRD. A direct relationship between the TiO₂ content and the photocatalytic activity was observed up to three layers of TiO₂ (0.66 wt.%). Our results indicate that intermediate species generated on the TiO₂ layer can migrate through relatively long distances to react with the OH⁻ surface groups of the support. By increasing the TiO₂ loading of the photocatalyst two effects were observed: trichloroethylene conversion is enhanced, while the efficiency of the oxidation process is decreased at expenses of increasing the selectivity to COCl₂ and dichloroacetylchloride (DCAC). The results are discussed in terms of the layer thickness, TiO₂ amount, TCE conversion and CO₂, and COCl₂ selectivity.     

Operando FTIR study of the photocatalytic oxidation of acetone in air over TiO2–ZrO2 thin films

Operando FTIR spectroscopy has been used to study the photocatalytic oxidation of acetone vapors over semiconductors films containing TiO₂ and ZrO₂. Preparation of these coatings was carried out by dipping a silicon wafer in stable sols containing particles of TiO₂, Ti_1−xZr_xO₂, or a mixture of ZrO₂ and TiO₂. These differences in chemical composition and phase homogeneity were selected in order to determine their effect on the photocatalytic performance. A transmission cell specifically designed for in situ studies of photocatalytic coatings was utilized for the FTIR experiments under reaction conditions. In contrast with investigations with powdered photocatalysts, the use of thin films guarantees that the whole semiconductor is irradiated, and for that reason purely photochemical reactions are monitored. Acetone adsorption takes place molecularly and is higher on the Ti_1−xZr_xO₂ coating. This fact is very likely related to the higher specific surface of the samples containing Zr. However, the maximum photocatalytic rate for acetone degradation corresponds to the films composed by a binary mixture of TiO₂ and ZrO₂. On the other hand, remarkable differences on the type and concentration of intermediates appearing as a result of the photocatalytic oxidation of acetone are found for the coatings studied. A simple kinetic model was applied to analyze the evolution of both gas phase and surface species. The parameters obtained indicate that each specific surface process is affected in a different way by the variation in the composition of the photoactive films.     

The geography of university scientific production in Europe: an exploration in the field of Food Science and Technology

This paper contributes to the literature on the factors explaining the regional university production of science and its quality in the field of Food Science and Technology (FS&T). We hypothesized that the regional quantity of science generated by universities is shaped not only by the amount of research and development (R&D) funds, as the main mainstream literature suggests, but also by the demand for science at the regional level. Furthermore, given the evolutionary nature of knowledge production, we suggest that the number of publications has a significant effect on the quality of scientific research at the regional level. Drawing on a sample of 48,207 scientific papers in FS&T over the period 1998–2010, we first map and examine the regional distribution of science and its quality across Europe-15. Second, we address our hypotheses by specifying several econometric models to identify the factors affecting the quantity and quality of scientific production. Our results show that the regional demand for FS&T—captured by the regional employment in the food and beverage industry—matters for the generation of science. Additionally, our findings support the hypothesis of a positive and significant effect of the production of papers on the scientific quality at the regional level.     

Policies regarding public availability of published research data in pediatrics journals

Scientometrics - Sharing research data is an increasingly necessary requirement for the advancement of science. The goal of this paper is twofold. First, to analyze the policies on openness in...     

Electrical transport mechanisms of Neodymium-doped rare-earth semiconductors

Journal of Materials Science: Materials in Electronics - This study reports the electrical properties of Nd-doped cerium oxide (CeO2) films synthesized by microwave assisted hydrothermal using a...     

Many At Once: Capturing Intentions to Create And Use Many Views At Once In Large Display Environments

This paper describes results from an observational, exploratory study of visual data exploration in a large, multi-view, flexible canvas environment. Participants were provided with a set of data exploration sub-tasks associated with a local crime dataset and were instructed to pose questions to a remote mediator who would respond by generating and organizing visualizations on the large display. We observed that participants frequently posed requests to cast a net around one or several subsets of the data or a set of data attributes. They accomplished this directly and by utilizing existing views in unique ways, including by requesting to copy and pivot a group of views collectively and posing a set of parallel requests on target views expressed in one command. These observed actions depart from multi-view flexible canvas environments that typically provide interfaces in support of generating one view at a time or actions that operate on one view at a time. We describe how participants used these ‘cast-a-net’ requests for tasks that spanned more than one view and describe design considerations for multi-view environments that would support the observed multi-view generation actions.     

Photochemical Mechanism of an Atypical Algal Phytochrome

Phytochromes are bilin‐containing photoreceptors that are typically sensitive to the red/far‐red region of the visible spectrum. Recently, phytochromes from certain eukaryotic algae have become attractive targets for optogenetic applications because of their unique ability to respond to multiple wavelengths of light. Herein, a combination of time‐resolved spectroscopy and structural approaches across picosecond to second timescales have been used to map photochemical mechanisms and structural changes in this atypical group of phytochromes. The photochemistry of an orange/far‐red light‐sensitive algal phytochrome from Dolihomastix tenuilepis has been investigated by using a combination of visible, IR and X‐ray scattering probes. The entire photocycle, correlated with accompanying structural changes in the cofactor/protein, are reported. This study identifies a complex photocycle for this atypical phytochrome. It also highlights a need to combine outcomes from a range of biophysical approaches to unravel complex photochemical and macromolecular processes in multi‐domain photoreceptor proteins that are the basis of biological light‐mediated signalling.