Carbonium Ion and Hydridocobalt Intermediates in the Acidic Phase Transfer Catalyzed Reactions of Olefins and Dienes with Cobalt Carbonyl

The intermediates mentioned in the title are probably involved in the hydrogenation of olefins and dienes; bidentate phosphine and arsine cobalt complexes are useful reagents for these reactions.     

Surface morphology and I-V characteristics of single-crystal,polycrystalline, and amorphous silicon FEA's

This letter reports the surface morphology and current-voltage (I-V) characteristics of single-crystal silicon (c-Si), polycrystalline silicon (poly-Si), and amorphous silicon (a-Si) field emitter arrays (FEAs). As-deposited a-Si film has a smoother surface than poly-Si film. The surface morphology of the a-Si remains smooth even after phosphorus doping and oxidation at 950°C to be improved in emission characteristics, i.e., smaller anode current deviation among arrays smaller gate current, and higher failure voltage than those of poly-Si FEAs. Such improved characteristics can be explained by the smooth surface morphology which is kept during doping and oxidation. The surface roughness and emission characteristics of a-Si FEAs are comparable to those of c-Si FEAs     

A comparison of LII analysis results from numerical model and experiment at elevated surrounding pressures

With environmental concerns over emitted particulate matters(PM) from combustion systems, various researches have been conducted on reduction and measurement techniques of particulate matters. The LII analysis results from numerical models and experiments in an ethylene/air laminar diffusion flame at elevated pressure up to 2.0 MPa with laser fluence 0.07 J/cm², detection wavelength 400 nm were compared to validate a modified LII numerical model. The lifetime of the LII signal decreased as the elevated pressure increased, so that LII decay time also decreased in both results. In the aspect of heat transfer mechanism, it becomes earlier that dominant conduction starts. This shows that the results matched well under the pressure conditions. It is concluded that the LII numerical model could be applied to decide particle size in TIRE-LII at the high-pressure condition.     

Structural Analysis on Organic Thin-Film Transistor With Device Simulation

A 2-D device simulation for organic thin-film transistors (OTFTs) was carried out to reveal the characteristic difference between staggered and planar structures. Assuming the OTFT with Schottky barrier contact, the staggered-structure TFT has more current flow, bigger field-effect mobility, and lower contact resistance than the planar structure. The simulation results indicate that the source electrode of the staggered structure has better ability to supply the current than that of the planar structure.     

Effects of Different Salt Treatments on the Fermentation Metabolites and Bacterial Profiles of Kimchi

The effects of purified salt (PS) and mineral‐rich sea salt (MRS), both with different mineral profiles, on kimchi fermentation were studied using a culture‐dependent 16S rRNA sequencing technique and mass‐based metabolomic analysis. The different mineral profiles in the fermentation medium caused changes in the bacterial profiles of the 2 kimchi products. An increase of Leuconostoc species in MRS‐kimchi decreased the Lactobacillus/Leuconostoc ratio, which led to changes in metabolites (including sugars, amino acids, organic acids, lipids, sulfur compounds, and terpenoids) associated with kimchi quality. Although further studies on the relationship between these salt types and kimchi fermentation are needed, these results suggested that the MRS treatment had positively affected the changes of the kimchi mineral contents, bacterial growth, and metabolite profiles, which are linked to kimchi quality.     

Cycling performance of a lithium-ion polymer cell assembled by in-situ chemical cross-linking with fluorinated phosphorous-based cross-linking agent

Lithium-ion polymer cells composed of a carbon anode and a LiCoO₂ cathode are assembled with a gel polymer electrolyte cured by in-situ chemical cross-linking with novel cross-linking agents. The strong interfacial adhesion between the electrodes and the porous polyethylene membrane by the chemical cross-linking results in the stable capacity retention of the cell. However, a reduction in the ionic mobility in both the electrolyte and the electrodes adversely affects the high rate performance of the cell. These results imply that proper control of the cross-linking density in the cell is imperative for achieving good capacity retention and high rate performance of the cell.     

The novel usage of spectroscopic ellipsometry for the development of amorphous Si solar cells

We present the novel use of spectroscopic ellipsometry (SE) for the development of a-Si:H solar cell. SE is a very fast and useful tool to measure various optical properties of thin film. In the case of a-Si:H thin film analysis, generally, SE is used to estimate the film thickness, roughness, void fraction, optical constants such as (n,k), and so forth. In this study, optical parameters from SE measurements were analyzed with relation to structural and electrical properties of a-Si:H thin film for solar cell. By analyzing IR absorption spectra and conductivity measurements, it was affirmed that <ε₂> and parameter A by Tauc-Lorentz model fitting of SE data are representative parameters qualifying a-Si:H thin film, and that they have close relationships with FF and light induced degradation property of solar cells. Based on the analysis, solar cells that have i-layers with various E_g were optimized. By this research, easier and faster methodology to develop a-Si:H thin film for thin film Si solar cells using SE measurements was established.     

Electrospray‐deposited nickel ferrite thin film electrode for hydrogen production in PV‐assisted water electrolysis system

Nanocrystalline Ni ferrite thin film was prepared by electrospray deposition technique and characterized by different analytical techniques at different annealing temperatures. All these films were studied by photovoltaic‐assisted water electrolysis system for solar to hydrogen production efficiency measurement. Highly dense and uniform surface morphology was observed in as‐deposited film, which changed into agglomerated nanocrystalline grains of irregular size and shape with change in annealing temperature. The X‐ray photoelectron spectroscopy study showed that the as‐deposited film was a mixture of an oxyhydroxide form of iron and an Ni₂O₃ form of nickel, whereas it changed into ferrite phase with change in annealing temperature. The as‐deposited film was observed to be of amorphous phase, which changed to crystalline cubic spinel structure with change in annealing temperature. The solar to hydrogen production efficiency was found to increase in a film with an increase in annealing temperature. The film annealed at 500°C showed a high solar to hydrogen production efficiency (8.29%) with constant performance of up to initial 500 h. Thereafter, the performance slowly declined by 11% when up to 1000 h. Copyright © 2011 John Wiley & Sons, Ltd.     

Isolation of lactic acid bacteria starters from <Emphasis Type="Italic">Jeung</Emphasis>-<Emphasis Type="Italic">pyun</Emphasis> for sourdough fermentation

Lactic acid bacteria (LAB) are key for the fermentation of sourdoughs to improve the quality and nutritive value of bread. The aim of this study was to isolate the LAB starter for sourdough fermentation from Jeung-pyun, a Korean traditional rice cake. Among the twenty two LAB screened, five isolates were selected based on exo-polysaccharide production. Among them, three isolates showed cell growth greater than 8.5 Log CFU/g, maximum increase in the volume of dough, and dextran concentration up to 0.16%. During the sourdough fermentation, pH and total titratable acidity (TTA) were changed, as the three isolates synthesized lactic acid and acetic acid with fermentation quotients less than 2.0. They were identified as Leuconostoc lactis EFEL005, Lactobacillus brevis EFEL004, and Le. citreum EFEL006. They displayed good fermentation properties (growth, dextran production, pH, and TTA) in dough and they are regarded as potential starters to be used in sourdough fermentation.     

Low-frequency noise in ambipolar carbon nanotube transistors

Low-frequency noise measurements on individual single-walled carbon nanotube transistors exhibiting ambipolar characteristics have been carried out. With a polymer electrolyte as gate medium, low-frequency noise can be monitored in both p- and n-channel operation of the same nanotube under the same chemical environment. 1/ f noise in the p-channel of polymer electrolyte gated nanotube transistor is similar to that of back gate operation. However, most devices exhibit significantly larger noise amplitude in the n-channel operation that has a distinct dependence on the threshold voltage. A nonuniform energy distribution of carrier trapping/scattering sites is considered to explain these observations.