Biogenic versus abiogenic emissions from agriculture in the Netherlands and options for emission control in tomato cultivation

In this paper, present-day emissions of greenhouse gases and acidifying compounds from agriculture are analysed at the farm level. Quantitative estimates are given for these emissions from three nested systems in the Netherlands: the agricultural sector, greenhouse horticulture, and tomato cultivation under glass. Total emissions are subdivided into emissions from biogenic sources and abiogenic sources. We conclude that, although most of the emissions from the agricultural sector have biogenic sources, those from abiogenic sources should not be neglected. Abiogenic emissions are mainly from greenhouse horticulture. The cost-effectiveness of options to reduce carbon dioxide (CO₂) and nitrogen oxides (NO_x) emissions from on-farm combustion of natural gas in tomato cultivation under glass is analysed. An inventory is given of technical reduction options that are presently available in practice. Based on information about the costs and the reduction potential of each option, cost-efficiency curves are derived for both types of emissions. Relative to a situation where none of the described options were applied (early nineties), CO₂ and NO_x emissions from tomato cultivation can be reduced at most by about 70% and 75%, respectively, by combinations of technical options. This revised version was published online in August 2006 with corrections to the Cover Date.     

Application of a chromium‐free photoresist to CRT screen processing

In 1998, Toyo Gosei Co. published a paper on the development of a new water‐soluble photopolymer of high sensitivity, PVA‐ARBB. In close co‐operation with LG. Philips Displays, the new material was further developed to be applicable in patterning the phosphor layer of a CRT screen. The new material shows about 3 times higher light sensitivity, gives 4–5% higher luminance, has no dark reaction, and is chromium‐free. It is the first chromium‐free photoresist used for phosphor patterning in CRT mass production. A comparison is presented between the conventional resist and the new resist. A survey is given of the most important process conditions.     

Improved magnetic trapped field in thin-wall YBCO single-domain samples by high-pressure oxygen annealing

Oxygen high pressure (up to 16 MPa) has been introduced in the oxygen-annealing step necessary to make the YBa₂Cu₃O_x phase superconducting (change x from 6 to about 7). It enables a displacement in the equilibrium phase diagram towards higher temperatures, which means the possibility to achieve the same final oxygen content as the one at low temperature, but with the benefit of higher diffusion rates. Initial development made on thin bars (1.5–3 mm thick) has confirmed the interest of using a high pressure of oxygen. TEM observations have shown an increase of twin density associated with higher Jc. This is in agreement with other works claiming the possibility of higher Jc by twin engineering, and more precisely by twin refinement while annealing at high temperature. We report the successful application of this process without any adjustment to so-called thin-wall single-domain samples. These samples are obtained by growing a crystal on a pellet already shaped with an array of holes. The advantage is that, as far as diffusion processes are concerned, the typical length is not anymore the diameter of the sample, but the thickness of the walls between holes. The trapped field of 16 mm diameter Y123 thin-wall single-domain samples was doubled (0.6 T vs. 0.3 T at 77 K) in a rather short annealing time (about 3 days). Microstructures as well as magneto-optical observations of plain and thin-wall samples evidenced a reduction of cracks in the thin-wall samples. Improved performances were confirmed by further characterizations performed from 77 down to 20 K using the pulse-field facilities of the LNCMP at Toulouse.     

Estimating the geotechnical properties of heterogeneous rock masses such as flysch

The design of tunnels and slopes in heterogeneous rock masses such as flysch presents a major challenge to geologists and engineers. The complex structure of these materials, resulting from their depositional and tectonic history, means that they cannot easily be classified in terms of widely used rock mass classification systems. A methodology for estimating the Geological Strength Index and the rock mass properties for these geological formations is presented in this paper. Electronic Publication     

Patterning of Epitaxial Perovskites from Micro and Nano Molded Stencil Masks

A process is developed that combines soft lithographic molding with pulsed laser deposition (PLD) to make heteroepitaxial patterns of functional perovskite oxide materials. Micro‐ and nanostructures of sacrificial ZnO are made by micro molding in capillaries (MiMiC) and nano transfer molding, respectively, and used to screen the single crystalline substrates during subsequent PLD. ZnO is used because of its compatibility with the high temperatures reached during PLD and because of the ease of its removal after use by benefiting from its amphoteric nature. Sub‐micrometer sized lines of La_0.67Sr_0.33MnO₃ are made by the transfer molding approach, preserving the anisotropic features expected for a fully oriented thin film and taking account for the magnetostatic contribution from the line shapes. Different patterns of SrRuO₃ are made with lateral dimensions of a few micrometers having individual features for which electrical isolation is illustrated. The bottom‐up soft lithographic methods can be compliantly utilized for making epitaxial structures of various shapes and sizes in the μm down to the nm range, and offer unique opportunities for fundamental studies as well as for realizing technological applications.     

Influence of OH scavenger on the water effect on secondary organic aerosol formation from ozonolysis of limonene, Delta3-carene, and alpha-pinene

The effect of OH scavengers on how water vapor influences the formation of secondary organic aerosol (SOA) in ozonolysis of limonene, Delta3-carene, and alpha-pinene at low concentrations has been investigated by using a laminar flow reactor. Cyclohexane and 2-butanol (3-40 x 10(13) molecules cm(-3)) were used as scavengers and compared to experiments without any scavenger. The reactions were conducted at 298 K and at relative humidities between <10 and 80%. The yield of SOA decreased in the order "no scavenger" > 2-butanol > cyclohexane. The effect of water vapor was similar for 2-butanol and without a scavenger, with an increase in particle number and mass concentration with increasing relative humidity. The water effect for cyclohexane was more complex, depending on the terpene, scavenger concentration, and SOA concentration. The water effect seems to be influenced by the HO2/RO2 ratio. The results are discussed in relation to the currently suggested mechanism for alkene ozonolysis and to atmospheric importance. The results imply that the ozone-initiated oxidation of terpenes needs revision in order to fully account for the role of water in the chemical mechanism.     

Electrolyte effects on recirculating dense bubbly flow: An experimental study using X-ray imaging

In this work, the effect of an electrolyte (up to 2 M of NaCl dissolved in water) on a homogeneous dense bubbly flow, in an airlift bubble column, is studied using nonintrusive techniques. X-ray and high-speed imaging are used to investigate the bubble size distribution, the local and the global gas-fraction profiles. The major effect of the electrolyte is the bubble size distribution at the fine-pore sparger, which is a consequence of the bubble coalescence inhibition promoted by the electrolyte. The bubble plume widening, the increase in overall gas fraction, and the onset of bubble recirculation in the column can all be explained by the bubble size reduction at the fine-pore spargers. As a result of the bubble size reduction, the overall role of the electrolyte is in a reduction of the driving force for the liquid recirculation. Furthermore, an accumulation of the small bubbles causes a layer of foam at the free surface, which is dynamic in nature and induces additional bubble recirculation.     

Automated Acquisition and Processing of 3D GPR Data for Object Detection and Characterization

To improve image resolution of GPR data, proper data acquisition is the first key part of the whole imaging sequence. Obtainable down and cross range resolutions, insofar as they are related to acquisition, are determined by the frequency bandwidth of the GPR equipment, the temporal and spatial sampling rates and the accurate knowledge of the antenna positions. The key parameters for three-dimensional imaging algorithms are wave velocity distribution in the domain of interest, radiation (polarization and amplitude) characteristics of the antenna system and emitted waveform. To this end we have designed and manufactured a measurement frame with high horizontal position accuracy of the antennas, by using a servomotor that automatically moves the antennas over the whole area of the measurement frame for a fixed vertical position of the antennas. When acquisition is completed, the data needs to be processed such that object detection and characterization is most easily accomplished. In most cases, object detection can be carried out on the preprocessed data itself, but in some cases and certainly for characterization purposes improved image resolution is required. This is realized using imaging algorithms, preferably those that take into account the polarization and amplitude characteristics of the antennas.Now with Shell International Exploration and Production B.V.