Geometric determination of coordinated centers of curvature in network mechanisms through linkage reductionDie geometrische bestimmung der bahnkrümmungen in labyrinthischen gelenkgetrieben mittels zusammenfügungen von jedesmahl zwei einzelgelenke

Coordinated centers of curvature in a network mechanism may be found by way of linkage reduction. This has to be carried out twice, each time in a different way, namely, a first order reduction through joint-joining in order to determine the velocity poles, [1] and a second order reduction, that equally replaces binary bars, but this time preserves instantaneous motion up to the 2nd order.For the reduced linkage, the problem of finding coordinated centers of curvature may be solved by successive application of Bobillier's Theorem in different four-bar loops.In order to show applicability also for linkages not containing four-bars, the method will be demonstrated for an eight-bar linkage that contains only pentagonal loops. The method introduced is a purely geometric one and does not involve velocity or acceleration constructions. Notwithstanding that, the final result may be used also to determine accelerations in linkage mechanisms.     

X-ray absorption spectroscopic evidence for the formation of Pb(II) inner-sphere adsorption complexes and precipitates at the calcite-water interface

Combined batch sorption and in situ X-ray absorption spectroscopy provide direct assessment of the mechanisms for Pb(II) sorption atthe calcite--water interface under low-temperature conditions. At low metal concentration, 1 microM initial Pb, X-ray absorption fine structure data indicate the formation of Pb mononuclear inner-sphere complexes at the surface. A first-shell Pb-O bond length of 2.34 A is consistent with nearest oxygen neighbors in 3- or 4-fold coordination with a distorted trigonal pyramidal or square pyramidal geometry with a stereochemically active electron lone pair. For high initial Pb concentrations, 20 and 60 microM Pb, precipitation of hydrocerussite and cerussite secondary phases dominates Pb partitioning. At 5 and 10 microM initial Pb, the sorption mechanism is dual in nature with persistence of the mononuclear adsorption complex combined with precipitation of a cerussite phase occurring prior to saturation of theoretically available surface sites. The formation of inner-sphere complexes implies strong metal interactions with the surface-the mechanistic reason for the affinity of Pb for calcite as observed in macroscopic studies. The geometry of the adsorbed complex can influence Pb coprecipitation, as a change to octahedral coordination is required for incorporation into calcite. The results provide the basis for predictions of Pb sequestration by calcite in natural systems.     

Molecular weight variations in perylene‐doped poly(methyl methacrylate) for luminescent solar concentrators

Integrating highly efficient luminescent dyes into poly(methyl methacrylate) matrices with well‐defined parameters, such as degree of polymerization and dispersity, is a key step in the development of emerging technologies such as fiber‐based solar collectors, sensors, contactless coupling devices and integrated light sources. In this work, four perylene‐based fluorescent dyes, perylene from Sigma‐Aldrich, Lumogen F Yellow 083 from BASF, Perylene Orange from TCI and Lumogen F Red 300 from BASF, were polymerized in bulk with methyl methacrylate. The molecular weight distribution was controlled by the ratio between the chain transfer agent and initiator and was measured by size exclusion chromatography. A dopant‐dependent increase in the degree of polymerization, in which the dye causes a drop in the concentration of active growing polymer chains, was observed. Spectroscopic online monitoring of the process in transmission mode confirmed this observation and indicated the formation of stable perylene radicals during the polymerization. Comparative experiments with fluorescent (metal) organic dyes did not show a similar effect. Fitting models for the dye‐dependent molecular weights for Lumogen Yellow and Lumogen Red are proposed. © 2018 Society of Chemical Industry     

Application of thermography for thermoplastic waveguide fabrication

The production of short polymer optical fibers from small material batches is valuable for materials research, especially in the investigation of copolymers. A two‐step fiber drawing process is usually used for this purpose. The drawing temperature of the individual materials is an important parameter in the process. Temperature measurements using contactless methods are preferred because they enable online monitoring and do not affect the drawing process. Such measurements can be carried out with a pyrometer, which allows the measurement of a wide range of temperatures but requires a precise adjustment of the spot to the core of the preform. To circumvent this limitation, a thermographic camera with a resolution of 134 µm per pixel in the heating zone is used. The measurement range 0–250 °C is suitable for the usual drawing conditions. The device is installed outside the resistive heating furnace. The absolute temperature is obtained by calibrating the sensor to the beam path and the material emission properties. Different materials, shapes and thicknesses lead to variations in these parameters. In this work, an analysis of the temperature calibration for poly(methyl methacrylate), poly(styrene) and the copolymers poly[styrene‐co‐(isobornyl methacrylate)] and poly[(methyl methacrylate)‐co‐(isobornyl methacrylate)] is presented. These are all thermoplastic polymers and may be used for the fabrication of polymer optical fibers. © 2018 Society of Chemical Industry     

Structure-property relations of segmented block copolymers with liquid-liquid demixed morphologies

Poly(propylene oxide) based polyether(ester-amide)s (PEEA) with non-crystallisable amide segments were synthesized and their structure-property relations studied. These model segmented block copolymers were used to gain insight in the structure-property relations of block copolymers with liquid-liquid demixed morphologies, also present in segmented polyurethanes. The poly(propylene oxide) used had a molecular weight of 2300 g/mol and was end capped with 20 wt% ethylene oxide. The non-crystallisable amide segments are based on an amorphous polyamide: poly(m-xylylene isophthalamide) and the repetitive length (x) of the amide segment was varied from 1 to 10. Phase separation in these PEEA's occurred by liquid-liquid demixing when the length (x) of the non-crystallisable amide segment was higher than 2 (x>2). TEM experiments showed spherical structures at two size scales, 5-10 nm domains (nano-domains) and 30-500 nm domains (sub-micron domains), both dispersed in a polyether matrix. The size and volume fraction of these spherical domains were found to increase with increasing the amide segment length. The modulus of the materials increased moderately with increasing amide segment content (increasing amide segment length x). The compression and tensile sets values of these PEEA's were found to decrease with increasing amide segment length, thus these PEEA's behave also more elastic at longer amide contents (thus also at higher modulus). Giving time these liquid-liquid demixed segmented block copolymers recovered completely.     

Abandoned Mid-Canada Radar Line sites in the Western James region of Northern Ontario, Canada: a source of organochlorines for First Nations people?

The potential exists for human exposure to polychlorinated biphenyls (PCBs) and other contaminants originating from abandoned Mid-Canada Radar Line (MCRL) sites in sub-arctic Canada. We examined patterns of differences with respect to body burden of organochlorines (lipid-adjusted) between residents of the Ontario First Nations of Fort Albany (the site of MCRL Site 050) and Kashechewan (no radar base) and Hamilton (an industrial, southern Ontario community) to assess whether the presence of Site 050 influenced organochlorine body burden with respect to the people of Fort Albany. PCBs (Aroclor 1260 and summation operator14 PCBs congeners [CBs]) and DDE in the plasma of Fort Albany and Kashechewan subjects were elevated relative to Hamilton participants. PCB and DDE-plasma levels in First Nation women were of comparable magnitude to those reported for Inuit women living in the west/central Northwest Territories. Significantly lower DDE/DDT ratios observed for Fort Albany indicates exposure to higher levels of DDT compared to Kashechewan. The probable source of DDT exposure for Fort Albany people is the DDT-contaminated soil surrounding buildings of Site 050. The results of the correspondence analysis (CA) indicated that people from Hamilton had relatively higher pesticides and lower CB body burdens, while people from Fort Albany and Kashechewan exhibited relatively higher CBs and lower pesticide levels (CA-1). The separation of Fort Albany and Kashechewan from Hamilton was also clear using questionnaire data (i.e., plotting dietary principal component [PC]-1 scores against PC-2); PC-1 was correlated with the consumption of a traditional diet. Separation of Kashechewan and Albany residents occurred because the people of Kashechewan ate more traditional meats and consumed shorebirds. Only one significant relationship was found between PC analysis and contaminant loadings; PC-1 versus CA-3 for Kashechewan. The presence of Site 050 on Anderson Island appears to have influenced organochlorine body burden of the people of Fort Albany. ANCOVA results revealed that it was not activity on Anderson Island that was important, but activity on Site 050 was the influential variable. When these results are considered with the DDE/DDT ratio data and the CB 187 results (Fort Albany and Kashechewan residents differed significantly), the findings are suggestive that Site 050 did influence organochlorine body burden of people from Fort Albany.     

RumexWeeds: A grassland dataset for agricultural robotics

Computer vision can lead toward more sustainable agricultural production by enabling robotic precision agriculture. Vision-equipped robots are being deployed in the fields to take care of crops and control weeds. However, publicly available agricultural datasets containing both image data as well as data from navigational robot sensors are scarce. Our real-world dataset RumexWeeds targets the detection of the grassland weeds: Rumex obtusifolius L. and Rumex crispus L. RumexWeeds includes whole image sequences instead of individual static images, which is rare for computer vision image datasets, yet crucial for robotic applications. It allows for more robust object detection, incorporating temporal aspects and considering different viewpoints of the same object. Furthermore, RumexWeeds includes data from additional navigational robot sensors—GNSS, IMU and odometry—which can increase robustness, when additionally fed to detection models. In total the dataset includes 5510 images with 15,519 manual bounding box annotations collected at three different farms and four different days in summer and autumn 2021. Additionally, RumexWeeds includes a subset of 340 ground truth pixels-wise annotations. The dataset is publicly available at https://dtu-pas.github.io/RumexWeeds/ . In this paper we also use RumexWeeds to provide baseline weed detection results considering a state-of-the-art object detector; in this way we are elucidating interesting characteristics of the dataset.     

Constructing effective Government information campaigns for energy conservation and sustainability: Lessons from Sweden

Information provision is the softest instrument in the government's tool kit. In order to suggest some conditions that promote the effectiveness of this policy instrument, cases are drawn from Swedish housing‐related energy conservation programmes between 1977 and 1998. Information has been particularly successful in influencing consumers who have economic incentives to take conservation measures but who do not know exactly how to go about it. Information has been more successful with owner‐occupants who can influence their energy flow directly than with tenants who cannot. Specific information on how‐to‐do skills has been more instrumental than general‐motivation knowledge. Information activities with perpetual evaluation of outputs and outcomes and incessant feedback of the results not only to programme managers but also to the addressees are more successful than information efforts without a proper evaluation function. These and other conclusions are presented as rules of thumb for information provision.     

Sequential robust optimization of a V-bending process using numerical simulations

The coupling of finite element simulations to mathematical optimization techniques has contributed significantly to product improvements and cost reductions in the metal forming industries. The next challenge is to bridge the gap between deterministic optimization techniques and the industrial need for robustness. This paper introduces a generally applicable strategy for modeling and efficiently solving robust optimization problems based on time consuming simulations. Noise variables and their effect on the responses are taken into account explicitly. The robust optimization strategy consists of four main stages: modeling, sensitivity analysis, robust optimization and sequential robust optimization. Use is made of a metamodel-based optimization approach to couple the computationally expensive finite element simulations with the robust optimization procedure. The initial metamodel approximation will only serve to find a first estimate of the robust optimum. Sequential optimization steps are subsequently applied to efficiently increase the accuracy of the response prediction at regions of interest containing the optimal robust design. The applicability of the proposed robust optimization strategy is demonstrated by the sequential robust optimization of an analytical test function and an industrial V-bending process. For the industrial application, several production trial runs have been performed to investigate and validate the robustness of the production process. For both applications, it is shown that the robust optimization strategy accounts for the effect of different sources of uncertainty onto the process responses in a very efficient manner. Moreover, application of the methodology to the industrial V-bending process results in valuable process insights and an improved robust process design.     

Maternal levels of organochlorines in two communities in southern Vietnam

Some pesticides and PCBs continue to be reported as environmental problems in some areas of Vietnam. In 2005, a study among delivering women took place in two communities in south-central Vietnam (Khanh Hoa Province), namely the coastal city of Nha Trang and the rural district of Dien Khanh located about 10 km inland. The main findings in plasma (n = 189) were relatively high mean concentrations of p,p′-DDE (12.2 µg/l in Nha Trang and 11.4 µg/l in Dien Khanh) and p,p′-DDT (1.2 µg/l in Nha Trang and 1.1 µg/l in Dien Khanh) with no significant community differences. The ratio of p,p′-DDE/p,p′-DDT (11.5 in Nha Trang/12.7 in Dien Khanh) suggests, as in other Vietnamese OCs studies, a relatively recent use of this pesticide. Mean concentrations of PCB 153 (0.15 µg/l in Nha Trang and 0.10 µg/l in Dien Khanh) and other congeners were low in both communities. Age and parity (all compounds), as well as community of residence for PCB 153, were the most important predictors of plasma OCs concentrations.