Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.     

Influence diagnostics in multiple discriminant analysis

Various influence diagnostics in Multiple Discriminant Analysis can be found in the literature. Almost all of them are based on the overall probability of misclassification. Two case-deletion diagnostics which evaluate the effect of the omission on the linear functions which determine Fisher’s Linear Discriminant Rule are proposed in this paper. Both measures are based on the L ₂-norm: The first diagnostic is calculated from the data set and the second diagnostic is calculated in the minimum hypercube which covers it.     

Multiple perspectives of rejected, neglected, and accepted children: Relation between sociometric status and behavioral characteristics.

Hypothesized, on the basis of findings from several studies, that rejected children are more disruptive, aggressive, and socially inappropriate than are their classmates. Three groups of 39 rejected, 29 neglected, and 39 accepted children were randomly selected from 282 boys and 210 girls who were identified separately on the basis of sociometric scores for 492 children in Grades 3–6. The 3 groups were compared using multiple analysis of variance (MANOVA) on measures from 4 domains: peer behavioral attributions, teacher ratings, analog assertiveness task, and self-evaluation. Rejected Ss were clearly distinguished from their same-sex neglected and accepted classmates and were described by teachers and peers as aggressive, disruptive and inattentive. Neglected Ss were only marginally discriminable from same-sex accepted children. Neither neglected nor rejected Ss were differentiated from accepted Ss with respect to observed assertiveness and self-ratings of shyness, unhappiness, and feeling unaccepted. The results replicate previous findings for rejected children. Currently, there is not sufficient justification to consider the group of socially neglected children as a clinical category. (21 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An iterative ADI-FDTD with reduced splitting error

We present a new iterative alternating-direction-implicit finite-difference time-domain (ADI-FDTD) method. By recognizing the ADI-FDTD method as a special case of a more general iterative approach to solve the Crank-Nicolson (CN) FDTD scheme, the splitting error in ADI-FDTD can be reduced systematically. Numerical examples are used to illustrate the improved accuracy of this method.     

MetaModel: a program for modelling and control analysis of metabolic pathways on the IBM PC and compatibles

MetaModel is a user-friendly program for calculating steady-state fluxes and metabolite concentrations of metabolic systems on the IBM PC and compatible computers. For any steady state that is obtained, one can then calculate a matrix of elasticity coefficients at that steady state, or a matrix of control and response coefficients. It thus offers a simple way to calculate the control structure of a pathway: it provides not only an educational tool that allows the student to verify empirically the classic summation relationships of metabolic control analysis but also a research tool for addressing 'what if?' questions about the behaviour of metabolic systems. Results can not only be printed or stored in a file, but can also be written to a special file that can be read by popular spreadsheet programs, thereby giving access to rapid, flexible and powerful methods for subsequent analysis and plotting of these results.     

Attention, the intersection of cost and quality in health care

A method for assessing health care technology that models the demand on the clinician's attention exerted by patients' data (diagnostic and therapeutic) can provide a means for simultaneously reducing the cost and improving the quality of health care. The attentional demand exerted by patients' data can be measured by the amount of uncertainty in the data. Uncertainty can be expressed mathematically by the concept of entropy in information theory.     

Surface tension as a controlled variable in mechanical dishwashing

Using a continuous, in-line, nondestructive technique based on the maximum bubble pressure method, the surface tension of the wash water in a mechanical dishwashing machine has been monitored. This technique has enabled surface tension to be used as a controlled variable, providing feedback to regulate the amount of surfactant added. Assuming the mechanical force of the water spray is adequate to remove bound soil from the dish surface, the food soil may be titrated against surfactant, providing an indirect indication as to when the dishes are clean. This technique also could be applied to a recirculated wash solution for in-place cleaning.     

FATIGUE DAMAGE IN 1045 STEEL UNDER VARIABLE AMPLITUDE BIAXIAL LOADING

Abstract— During constant amplitude loading, two different types of crack systems have been reported In the high cycle fatigue (HCF) region, cracks nucleate on a small number of maxium shear strain amplitude planes One of these cracks becomes a dominant crack and leads to failure of the specimen In the low cycle fatigue (LCF) region, equally developed microcracks are observed over the entire gage section and grow during the majority of the life. The failure is due to a linking in which the microcracks join up during the last few cycles of the fatigue life.
To investigate the interaction of these two types of crack systems in biaxial fatigue, experiments were performed on thin-wall tubular specimens in tension, torsion and combined tension-torsion loading The test program included step loading and block loading in which two equivalent strain amplitudes were employed. One of the equivalent strain amplitudes is in the HCF region and the other was in the LCF region
Fatigue lives were predicted from constant amplitude damage curves when a single crack system dominated the fatigue process Two competitive crack systems were sometimes developed on the maximum shear strain amplitude planes in a single specimen under block loading This resulted in a conservative prediction of the fatigue life.