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Jiacheng Yin Na Li Ming Liu Zhigang Li Xuemin Wang Mingren Cheng Ming Zhong Wei Li Yunhua Xu Xian-He Bu 《Advanced functional materials》2023,33(21):2211950
Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g−1 at 300 mA g−1), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g−1), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO4 unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials. 相似文献
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Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions 下载免费PDF全文
Jing Guo Jie Pan Shuai Chang Xuewen Wang Na Kong Wenrong Yang Jin He 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(15)
The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction. 相似文献
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PAN HaiXian L XiaoYing WANG ZhiGong REN TianLing FANG Tao ZHANG Jie ZHOU ChangJian & WANG LiGang State 《中国科学:信息科学(英文版)》2011,(10):2199-2208
Microelectrode arrays (MEAs) for stimulation and signal recording of in vitro cultured neurons are presented.Each MEA is composed of 60 independent electrodes with 59 working ones and one reference one.These electrodes are divided into 30 pairs.Through each pair of electrodes,four independent states can be realized to define the accessing modes of neurons cultured on the surface of the electrodes.A total MEA covers an area of 10 mm×10 mm.MEAs are fabricated in a silicon-based semiconductor process.An implemented MEA is bonded on a specially designed printed-circuit-board (PCB) and surrounded by a culture chamber.An impedance measurement has been made to verify the electrical characteristics of MEAs.The surface was modified to enhance the biocompatibility.A series of PC12 cells culture experiments validates the effectiveness of the modification.An extracellular signal recording experiment with acetylcholine (Ach) as a stimulant has been carried out,and the results show the feasibility of MEAs for extracellular action potential recording.Extracellular electrical stimulation and recording experiments have been carried out too.They indicate that MEAs can be used for extracellular stimulation,recording,simultaneous stimulation and recording,and isolation of PC12 cells network cultured in vitro. 相似文献
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王娜 《数字社区&智能家居》2011,(10)
在当今社会,传统的教学方式和手段使学生对C#.NET这门课程普遍感觉枯燥无味,难以达到良好的教学效果,只有采用良好的教学模式才能够激发学生学习的主动性、能够激发学生学习的热情。该文谈谈怎样使用案例教学培养学生的兴趣,培养学生的动手实践能力和创造能力,掌握C#.NET编程技术。 相似文献
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基于专家系统的回转窑窑头工况识别 总被引:1,自引:1,他引:0
针对新型干法水泥生产线窑头环节非线性、多变量、强耦合、大时滞等特性导致的工况复杂,控制难度大的问题,在深入分析窑头工况特点的基础上,提出了一种基于专家系统的工况智能识别方法.该方法首先对从集散控制系统中采集的现场参数实时值进行数据预处理,运用ART-2神经网络算法对关键参数的变化趋势进行在线辨识,并输出趋势类别,同时对主要参数的实时值进行模糊化处理,输出模糊档位.基于专家规则的工况识别系统根据参数的辨识结果,通过精确推理输出当前工况.工况识别软件采用c++编写,现场实际运行表明了该方案的正确性和实用性. 相似文献