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排序方式: 共有637条查询结果,搜索用时 16 毫秒
61.
Jean-Marc Haudin Aurélien Carin Michel Vincent Nicolas Amouroux Gaëlle Bellet Fabrice Montezin 《International Journal of Material Forming》2010,3(4):225-231
In polyamide 12 (PA12) tube extrusion, calibration is the key step of the process that affects the subsequent mechanical properties. In previous work it has been shown that according to the calibration conditions, a very oriented skin layer may be created, which has been correlated to an important decrease of elongation at break. In this paper, we present new results showing a good correlation between molecular orientation and fracture toughness, as evaluated by the EWF (Essential Work of Fracture) approach. They concern notched specimens and confirm the results obtained in classical tensile testing. The specific essential work of fracture is very sensitive to the orientation generated in the skin region by appropriate processing conditions: it decreases from the external to the inner regions of the tube, and increases with skin orientation. 相似文献
62.
63.
Van Son Nguyen Laurent Badie Emmanuel Lamouroux Brice Vincent Fabrice Domingues Dos Santos Maëlen Aufray Yves Fort Didier Rouxel 《应用聚合物科学杂志》2013,129(1):391-396
Piezoelectric films were prepared by incorporation of lithium niobate (LiNbO3) nanoparticles into copolymer of vinylidene difluoride and trifluoroethylene. Nanoparticles of LiNbO3 with ferroelectric phase were successfully synthesized and dispersed homogenously by ultrasonication in the copolymer matrix without any surfactant or surface functionalization. The nanocomposites were fully characterized by electronic microscopy, X‐ray diffraction, differential scanning calorimetry, dynamical mechanical analysis, and piezometer. Surprisingly, the copolymer matrix crystallinity and morphology were not affected by the incorporation of nanoparticles. Therefore the nanocomposites remained good mechanicals properties and high ferroelectricity coupled to nonlinear optical activity thanks to the noncentro symmetric space group of lithium niobate. This could be a novel approach to develop new multifunctional materials. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
64.
Michael Knorr Fabrice Guyon Abderrahim Khatyr Magali Allain Shawkat M. Aly Antony Lapprand Daniel Fortin Pierre D. Harvey 《Journal of Inorganic and Organometallic Polymers and Materials》2010,20(3):534-543
Abstract
CuI reacts instantaneously with butanedithiol in MeCN solution to form a sparingly soluble and thermally stable colorless polymeric material 1 of composition [(Cu2I2){HS(CH2)4SH}] n . Raman and IR spectroscopy confirm the presence of Cu(I) bound S–H functions. Furthermore, small amounts of the yellow compound [{Cu(μ2-I)2Cu}(C4H8S2)2] n 2 co-crystallize after several days. If the reaction mixture is exposed to air, polymeric 2 is isolated as the main product. An X-ray diffraction study reveals that 1D polymer 2 is assembled by rhomboid Cu(μ2-I)2Cu clusters (d Cu···Cu 2.6843(18) ?), which are linked through the S-atoms of six-membered 1,2-dithian heterocycles, thus generating an infinite ribbon. The low-frequency region in the Raman spectra show a striking similarity suggesting that polymers 1 and 2 bear the same cluster rhomboid Cu(μ2-I)2Cu clusters. The photophysics and luminescence properties of 2 have been studied experimentally and by means of DFT/TDDFT calculations. 相似文献65.
Florent ChauveauJulie Mougin Fabrice MauvyJean-Marc Bassat Jean-Claude Grenier 《International Journal of Hydrogen Energy》2011,36(13):7785-7790
High temperature steam electrolysis (HTSE) is one of the most promising ways for hydrogen mass production. To make this technology suitable from an economical point of view, each component of the system has to be optimized, from the balance of plant to the single solid oxide electrolysis cell. At this level, the optimization of the oxygen electrode is of particular interest since it contributes to a large extent to the cell polarization resistance. The present paper is focused on alternative oxygen electrode materials with improved performances compared to the usual ones mainly based on perovskite structure. Two nickelates, with compositions La2NiO4+δ and Nd2NiO4+δ are investigated and evaluated in HTSE operation at the button cell level. The performances of the Ln2NiO4+δ - containing cells (Ln = La, Nd) is improved compared to a cell containing the classical Sr-doped LaMnO3 (LSM) perovskite oxygen electrode showing that nickelates are promising candidates for HTSE oxygen electrodes, especially for operation below 800 °C. Indeed, current densities determined at 1.3 V are 1.1 times larger for the La2NiO4+δ - containing cell and 1.6 times larger for the Nd2NiO4+δ one compared to the LSM - containing cell at 850 °C, whereas at 750 °C they are 1.8 and 4.4 times larger, respectively. Thanks to the use of a reference electrode, by coupling impedance spectroscopy and polarization measurements, the overpotential of each working electrode is deconvoluted from the complete cell voltage under HTSE operating conditions. 相似文献
66.
Fabrice Burel Hassan Oulyadi Claude Bunel Vladimir Grishchenko Natalya Busko Antonina Barantsova Vitaly Boiko 《Journal of Polymer Research》2011,18(6):2265-2273
Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime
end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular,
the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units
(1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that
the structure of the end groups was governed by the steric hindrance of the initiator. Only 1,4 and 4,1 functionalized end
units were evidenced, with a majority of 4,1 end units. 相似文献
67.
Vincent Noblet Christian Heinrich Fabrice Heitz Jean-Paul Armspach 《IEEE transactions on image processing》2005,14(5):553-566
This paper deals with topology preservation in three-dimensional (3-D) deformable image registration. This work is a nontrivial extension of, which addresses the case of two-dimensional (2-D) topology preserving mappings. In both cases, the deformation map is modeled as a hierarchical displacement field, decomposed on a multiresolution B-spline basis. Topology preservation is enforced by controlling the Jacobian of the transformation. Finding the optimal displacement parameters amounts to solving a constrained optimization problem: The residual energy between the target image and the deformed source image is minimized under constraints on the Jacobian. Unlike the 2-D case, in which simple linear constraints are derived, the 3-D B-spline-based deformable mapping yields a difficult (until now, unsolved) optimization problem. In this paper, we tackle the problem by resorting to interval analysis optimization techniques. Care is taken to keep the computational burden as low as possible. Results on multipatient 3-D MRI registration illustrate the ability of the method to preserve topology on the continuous image domain. 相似文献
68.
69.
Cover Picture: Tetrahydroisoquinolinone‐Based Steroidomimetic and Chimeric Microtubule Disruptors (ChemMedChem 1/2014)
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70.
Pierre Rossi Jean Philippe Charron Maléna Bastien-Masse Jean-Louis Tailhan Fabrice Le Maou Sandrine Ramanich 《Materials and Structures》2014,47(10):1773-1785
The paper presents experimental results concerning the comparison of tensile and compressive basic creep behaviours at early ages of two different concretes: a normal strength concrete (NSC) and a very high strength fibre reinforced concrete (HPFRC). This research project has been done in the context of a bilateral collaboration between Polytechnique Montreal and IFSTTAR. Observations on the HPFRC showed specific compressive creep similar to the specific tensile creep. Moreover, the specific creep curves obtained under compressive and tensile loading had always positive values, i.e. they were in same direction of the applied load on specimens. Measurements made on the NSC revealed specific compressive creep with positive values (in the loading direction). However, specific tensile creep presented negative values (opposite direction of loading) for a long period. A physical explanation based on the existence of two mechanisms with opposite effect is proposed to describe these basic creep results. The first mechanism is a coupling between the microcracking process and the water transfers that lead to additional self-drying shrinkage; the second mechanism is the self-healing of concrete induced by the microcracking. 相似文献