Stability limits and consolute critical conditions for liquid mixtures

This work addresses the determination of stability limits and consolute critical conditions for multicomponent liquid mixtures. Using the NRTL model, thermodynamic stability and criticality criteria are implemented for ternary liquid mixtures to predict stability limit loci and critical composition at its specified temperature and pressure. The method is general and applicable for the prediction of spinodal curves and critical points for liquid–liquid-phase transitions in multicomponent liquid mixture using liquid–liquid equilibrium data even over a limited range of composition. Stability limits’ loci for 18 aqueous and 3 nonaqueous ternary liquid mixtures were used in validating the method. For ternary systems that were studied over the whole composition range including the critical zone, where experimental compositions at the critical point were available, the predicted results agree with the experimental measurements within 0.7?mol%.     

Enrichment,in vitro,and quantification study of antidiabetic compounds from neglected weed Mimosa pudica using supercritical CO2 and CO2-Soxhlet

Supercritical fluid extraction (SFE) using carbon dioxide (CO₂) and liquid CO₂ using Soxhlet (CO₂-Soxhlet) extraction were employed to extract three (3) antidiabetic compounds viz. stigmasterol, quercetin, and avicularin from Mimosa pudica. Various extraction parameters were studied. Extracts were analyzed pharmacologically, qualitatively and quantitatively to ascertain enrichment levels. All three antidiabetic compounds were effectively enriched under optimized conditions of temperature 60°C, pressure 40 MPa, co-solvent ratio 30%, and CO₂ flow rate of 5 ml min^?1. SFE was found to be the better method for enrichment of the antidiabetic compounds than the CO₂-Soxhlet method. Extraction conditions were seen to affect the enrichment of desired compounds.     

Design and Realization of a Novel Header Compression Scheme for Ad Hoc Networks

IP header compression schemes offer a valuable measure for bandwidth preservation. Such schemes have been practically implemented in infrastructure‐based IP networks for point‐to‐point links. However, minimal research and practical implementation efforts have been conducted in the direction of an IP header compression strategy that can meet the peculiar requirements of multi‐hop ad hoc wireless networks. In this paper, we present a practically implemented multi‐hop IP header compression scheme using the Robust Header Compression (ROHC) protocol suite. The scheme runs on a novel identifier (ID) based networking architecture, known as an ID‐based ad hoc network (IDHOCNET). IDHOCNET additionally solves a number of bottlenecks of pure IP‐based ad hoc networks that have emerged owing to IP address auto‐configuration service, distributed naming and name resolution, and the role of an IP address as an identifier at the application layer. The proposed scheme was tested on a multi‐hop test bed. The results show that the implemented scheme has better gain and requires only O (1) ROHC contexts.     

Cellular DNA breakage by soy isoflavone genistein and its methylated structural analogue biochanin A

Epidemiological studies have indicated that populations with high isoflavone intake through soy consumption have lower rates of breast, prostate, and colon cancer. The isoflavone polyphenol genistein in soybean is considered to be a potent chemopreventive agent against cancer. In order to explore the chemical basis of chemopreventive activity of genistein, in this paper we have examined the structure–activity relationship between genistein and its structural analogue biochanin A. We show that both genistein and its methylated derivative biochanin A are able to mobilize nuclear copper in human lymphocyte, leading to degradation of cellular DNA. However, the relative rate of DNA breakage was greater in the case of genistein. Further, the cellular DNA degradation was inhibited by copper chelator (neocuproine/bathocuproine) but not by compounds that specifically bind iron and zinc (desferrioxamine mesylate and histidine, respectively). We also compared the antioxidant activity of the two isoflavones against tert‐butylhydroperoxide‐induced oxidative breakage in lymphocytes. Again genistein was found to be more effective than biochanin A in providing protection against oxidative stress induced by tert‐butylhydroperoxide. It would therefore appear that the structural features of isoflavones that are important for antioxidant properties are also the ones that contribute to their pro‐oxidant action through a mechanism that involves redox cycling of chromatin‐bound nuclear copper.     

Determination of physicochemical properties of multifloral honeys stored in different containers

In comparison with the initial values, acidity and 5‐(hydroxy‐methyl)‐2‐furaldehyde (HMF) values of all honey samples increased during storage. The total phenol contents of honey were decreased from 286.2 to 108.6 mg GAE/kg during 9 months of storage in white colored container. In addition, total phenol contents of honey sample stored in tin container ranged from 294.7 to 258.6 mg GAE/kg (p < .05). While radical scavenging activity values of honey samples stored in amber colored container during storage are measured as 78.6 g/L, IC₅₀, 77.9 g/L, IC50, and 76.1 g/L, IC₅₀, these activity values were determined as 84.9 g/L, IC₅₀, 80.7 g/L, IC_50, and 75.2 g/L, IC₅₀ in tin container (p < .05), respectively. While acidity values of honey samples stored in white bottle range from 23.6 (3th month) to 25.7% (9th month), it varied from 20.6 (3th month) to 21.6% (9th month) in honey sample stored in amber colored container during storage.

Practical applications

Different honeys are produced in different parts of Turkey. The known honeys are pine, citrus, and chestnut honey. Various flower honeys are produced in these and other regions. HMF formation is considered as a bed result of storage and heating.     

Manufacture of dry‐ and brine‐salted soft camel cheeses for the camel dairy industry

Two experiments were conducted in a camel cheese study to (i) compare camel cheese to bovine cheese made from bovine milk standardised to simulate camel milk, and (ii) describe the technology for manufacture of dry (SCC‐D) and brine‐salted soft camel cheese (SCC‐B). Comparable cheese yield (camel: 7.4 ± 0.15, cow: 7.3 ± 0.55 kg/100 kg of milk) and levels of dry matter loss in whey were observed. Clotting time was 234 s for both cheeses which were made using thermophillic starters. Cheese yield was 9.31 ± 0.64 kg/100 kg with 425.6 ± 38.2 g/kg cheese dry matter for SCC‐D and 8.22 ± 0.90 kg/100 kg with 469 ± 73.8 g/kg dry matter for SCC‐B.