Removal of Cadmium from Aqueous Solution by Nano Composites of Bentonite /TiO2 and Bentonite/ZnO Using Photocatalysis Adsorption Process

Silicon - In this study, bentonite/TiO2 and bentonite/ZnO nanoparticles were used for studying the cadmium removal from the aqueous solution. The experiments were done in a batch condition under...     

Characterization of the continuous-flow mixing of non-Newtonian fluids using the ratio of residence time to batch mixing time

Continuous-flow mixing of pseudoplastic fluids possessing yield stress is a complex phenomenon exhibiting non-ideal flows within the stirred vessels. Electrical resistance tomography (ERT), a non-intrusive technique, was employed to measure the mixing time in the batch mode while dynamic tests were performed to study the mixing system in the continuous mode. This study attempts to explore the effects of the operating conditions and design parameters on the ratio of the residence time (τ) to the mixing time (θ) for the continuous-flow mixing of non-Newtonian fluids. To achieve these objectives, the effects of impeller types (four axial-flow impellers: A310, A315, 3AH, and 3AM; and three radial-flow impellers: RSB, RT, and Scaba), impeller speed (290–754 rpm), fluid rheology (0.5–1.5%, w/v), impeller off-bottom clearance (H/2.7–H/2.1, where H is the fluid height in the vessel), locations of inlet and outlet (configurations: top inlet-bottom outlet and bottom inlet-top outlet), pumping directions of an axial-flow impeller (up-pumping and down-pumping), fluid height in the vessel (T/1.06–T/0.83, where T is the tank diameter), residence time (257–328 s), and jet velocity (0.317–1.66 ms⁻¹) on the ratio of τ to θ were investigated. The results showed that the extent of the non-ideal flows (channeling and dead volume) in the continuous-flow mixing approached zero when the value of τ/θ varied from 8.2 to 24.5 depending on the operating conditions and design parameters. Thus, to design an efficient continuous-flow mixing system for non-Newtonian fluids, the ratio of the residence time to the mixing time should be at least 8.2 or higher.     

Fe3O4@MCM-41@NH-SO3H: an Efficient Magnetically Reusable Nano-Catalyst for the Formylation of Amines and Alcohols

Silicon - In this article the preparation of Fe3O4@MCM-41@NH-SO3H, a new sulfonated magnetic mesoporous nanocomposite, is reported. The introduced catalyst is structurally based on MCM-41 as the...     

New moment-rotation equation for welded steel beam-to-column connections

A three-parameter tangent inverse equation is generically proposed for the non-linear moment-rotation (M-θ) relationship of semi-rigid steel beam-to-column connections. The parameters are the initial stiffness, the plastic stiffness, and a reference moment. Two commonly used welded moment connections are picked up for moment-rotation calculation and comparison between the results of the proposed model and those of a detailed nonlinear finite elements modeling. Semi-analytical equations are proposed for calculating the parameters containing basic factors affecting behavior of the connections. The coefficients of the equations are computed based on a data bank developed in this study using the finite element method. A large number of finite elements models covering the whole range of common dimensions of the above connections are analyzed. Accuracy of the finite element model is verified on the basis of the available test results from previous studies. Tensile tests for determination of material properties of weld to be used in the modeling are conducted. Comparison between the results of the semi-analytical equations and the finite element models shows that the proposed model is able to estimate the moment-rotation curves of the welded beam-to-column connections with very good accuracy.     

An Integrated Framework to Evaluate Resilient-Sustainable Urban Drainage Management Plans Using a Combined-adaptive MCDM Technique

Due to the inevitability of urban flood in presence of the rainfalls exceeding design capacity of urban drainage system, resilience approach has been recently considered instead of the conventional urban drainage management. However, acceptance of resilience approach necessitates considering sustainability in the selection of urban drainage projects due to the various aspect of flood impacts. This paper presents a new integrated framework to show how urban drainage plans are resilient and sustainable. The framework consists of several indicators including technical, economic, social, environmental and planning aspects. On the other hand, the selection of suientropy of the probability distribution p _i . In fact, entropy reduces the effect of plan among available suggested plans is complicated in presence of multiplicity of the indicators. A new combined-adaptive multi criteria decision making technique including combination of Adaptive analytical hierarchical process, Entropy and TOPSIS is here introduced to facilitate the decision making process as well as dealing with uncertainties due to the subjective experts’ preferences. Moreover, presented framework are applied on a part of urban drainage system of Tehran, Capital City. Four urban drainage plans are designed and suggested to be evaluated along with existing system in terms of their sustainability and resilience. The results shows the presented framework provide comprehensive information regarding the behavior of the urban drainage plans against urban floods as well as their sustainability for urban managers. In addition, presented framework facilitates and accelerate the complicated process of decision making. Therefore, it can be employed as comprehensive decision support tool for resilient and sustainable urban drainage management.     

A Simulation-Optimization Model for Conjunctive Use of Canal and Pond in Irrigating Paddy Fields

Water Resources Management - In this study, a new methodology is presented for conjunctive use of canal and pond to assess the role of ponds in saving local water and optimizing use of them in...     

Evaluation of Four Tree Algorithms in Predicting and Investigating the Changes in Aquifer Depth

One of the key elements in improved management and better planning for aquifer maintenance is the ability to predict changes in aquifer depth. In order to forecast changes in aquifer depth in Qazvin plain, four methods, including Classification and Regression Tree (CART), Reduced Error Pruning Trees (RepTree), M5-Pruned (M5P), and M5Rule, were used in this work. The absolute mean error (MAE) and coefficient of determination (R2) data show that the CART algorithm performs better than other algorithms at forecasting changes in aquifer depth. The CART algorithm's prediction findings showed that the aquifer's behavior in the two seasons was entirely different. In the first stage, which began in November and continued through April, there was an annual average depth of 0.045 m. The aquifer depth has been greatly influenced by rising precipitation and falling air temperature. The aquifer experiences an average decline of 0.15 m in the second portion, which runs from May to October. Aquifer depth has significantly decreased as a result of declining natural water supplies and rising agricultural water use. It is advised to utilize a crop scheme with reduced water need when rainfall reduces due to the strong effect of changes in aquifer depth from rainfall with a delay of one to three months ago.