Biological and chemical redox transformations of mercury in fresh and salt waters of the high arctic during spring and summer

It is well-established that atmospheric deposition transports Hg to Arctic regions, but the postdepositional dynamics of Hg that can alter its impact on Arctic food chains are less understood. Through a series of in situ experiments, we investigated the redox transformations of Hg in coastal and inland aquatic systems. During spring and summer, Hg reduction in streams and pond waters decreased across a 4-fold increase in salinity. This alteration of Hg reduction due to chloride was counterbalanced by the presence of particles, which favored the conversion of oxidized Hg to its elemental form. In saline waters, biogenic organic materials, produced by algae, were able to promote oxidation of Hg(O) even under dark conditions. Overall these results point to the vulnerability of marine/ coastal Arctic systems to Hg, compared to inland systems, with oxidation processes enhancing Hg residence times and thus increasing its potential to enter the food chain.     

Desulfurization of high sulfur petroleum coke by molten caustic leaching

Desulfurization by molten caustic leaching (MCL) at 400–500 °C has been investigated in order to reduce the sulfur content of petroleum coke. Effective parameters on desulfurization of petroleum coke, other than temperature, include alkali to feed (petroleum coke) mass ratio, time and mesh size in the ranges of 0.5–1.5, 1–3 h and 200–600 µm, respectively. In this work, petroleum coke desulfurization conditions using solid KOH have been studied. Maximum petroleum coke desulfurization by MCL method has been obtained by Taguchi L9 design using alkali to feed mass ratio of 1, temperature of 600 °C, time of 2 h and mesh size of 200 µm. The changes in the main groups on the coke surface have been determined using FTIR spectroscopy. In addition, SEM-EDX, TGA and XRD analyses have been used to investigate the changes in coke physical and chemical properties.     

Manufacture of a mechanical test rig to simulate the movements of forces within the shoulder

The shoulder complex, also known as the glenohumeral joint is the most manoeuvrable and one of the most well used joints of the human body. Over time problems can occur with the glenohumeral joint and surrounding muscles, cartilage, tendons and ligaments caused by ageing or by over stressing the shoulder complex. This work examines the design of a new innovative glenohumeral test rig. The test rig was required to imitate the movement of the humerus in the human body and replicate all the ranges of motion, which it can move in when combined with the relevant bones, muscles, ligaments and tendons in the shoulder complex. A variable force also had to be applied to the glenoid in all ranges of motion. Research had to be undertaken in the ranges of motion of the shoulder complex and the forces acting on the glenoid. Concept designs were initially created to mimic specific ranges of motion; adduction, flexion, internal (medial) and external (lateral) rotation for example. The concepts were evolved and combined to develop a test rig that would replicate any axial movement of the shoulder. Research determined the most appropriate manufacturing processes and materials so that the test rig could be manufactured in the material laboratories.     

Experiments on two-phase flow in hydraulic jump on pebbled rough bed: Part 1–Turbulence properties and particle chord time and length

This study reported and discussed turbulence characteristics, such as turbulence intensity, correlation time scales, and advective length scales. The characteristic air–water time scale, including the particle chord time and length and their probability density functions (PDFs), was investigated. The results demonstrated that turbulence intensity was relatively greater on a rough bed in the roller length, whereas further downstream, the decay rate was higher. In addition, the relationship between turbulence intensity and dimensionless bubble count rate reflected an increase in turbulence intensity associated with the number of entrained particles. Triple decomposition analysis (TDA) was performed to determine the contributions of slow and fast turbulent components. The TDA results indicated that, regardless of bed type and inflow conditions, the sum of the band-pass (T'_u) and high-pass (T″_u) filtered turbulence intensities was equal to the turbulence intensity of the raw signal data (T_u). T″_u highlighted a higher turbulence intensity and larger vorticities on the rough bed for an identical inflow Froude number. Additional TDA results were presented in terms of the interfacial velocity, auto- and cross-correlation time scales, and longitudinal advection length scale, with the effects of low- and high-frequency signal components on each highlighted parameter. The analysis of the air chord time indicated an increase in the proportion of small bubbles moving downstream. The second part of this research focused on the basic properties of particle grouping and clustering.     

Experiments on two-phase flow in hydraulic jump on pebbled rough bed: Part 2–Bubble clustering

A survey on bubble clustering in air–water flow processes may provide significant insights into turbulent two-phase flow. These processes have been studied in plunging jets, dropshafts, and hydraulic jumps on a smooth bed. As a first attempt, this study examined the bubble clustering process in hydraulic jumps on a pebbled rough bed using experimental data for 1.70 < Fr₁ < 2.84 (with Fr₁ denoting the inflow Froude number). The basic properties of particle grouping and clustering, including the number of clusters, the dimensionless number of clusters per second, the percentage of clustered bubbles, and the number of bubbles per cluster, were analyzed based on two criteria. For both criteria, the maximum cluster count rate was greater on the rough bed than on the smooth bed, suggesting greater interactions between turbulence and bubbly flow on the rough bed. The results were consistent with the longitudinal distribution of the interfacial velocity using one of the criteria. In addition, the clustering process was analyzed using a different approach: the interparticle arrival time of bubbles. The comparison showed that the bubbly flow structure had a greater density of bubbles per unit flux on the rough bed than on the smooth bed. Bed roughness was the dominant parameter close to the jump toe. Further downstream, Fr₁ predominated. Thus, the rate of bubble density decreased more rapidly for the hydraulic jump with the lowest Fr₁.     

Fe3O4@MCM-41@NH-SO3H: an Efficient Magnetically Reusable Nano-Catalyst for the Formylation of Amines and Alcohols

Silicon - In this article the preparation of Fe3O4@MCM-41@NH-SO3H, a new sulfonated magnetic mesoporous nanocomposite, is reported. The introduced catalyst is structurally based on MCM-41 as the...     

Numerical simulation of cooling performance in microchannel heat sinks made of AlN ceramics

Microsystem Technologies - The problem of generating a high amount of heat in microelectronic equipment should be minimized properly. Allowing systems to run for long periods of time in high...     

Study the Effect of Surface Parameters Variation on the Corrosion Behavior of Thin Chromium Layer on Modified Titanium

Protection of Metals and Physical Chemistry of Surfaces - In this study, a thin chromium layer was applied on pure titanium substrate in a Sargent bath including 250 g/L chromic acid and 2.5 g/L...     

Studying the Role of Gelation Agents in Gelcasting Non-porous Si3N4 Bodies by Pressureless Sintering

Silicon - The monomer content in the gelcasting process affects the kinetics of cross-linking reactions which determines the quality of the gel network structure and the final properties of the...     

Inclusion complexes of atorvastatin calcium (ATV-Ca) and rosuvastatin calcium (ROV-Ca) drugs with α-CD, β-CD, γ-CD,HP-β-CD,M-β-CD,and maltodextrin along with their characterizations through experimental and computational methods

The aim of this research is a comparison of the efficiency of six commercially available cyclodextrins (CDs) to improve the solubility and oral bioavailability of atorvastatin calcium (ATV-Ca) and rosuvastatin calcium (ROV-Ca) drugs in aqueous media. Inclusion complexes of both drugs with non-toxic α-CD, β-CD, γ-CD, HP-β-CD, M-β-CD, and maltodextrin were prepared in a 1:1 stoichiometry via the kneading method. To reach the best CD, various experimental and computational analyses were performed including phase solubility, dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), atomic force microscopy (AFM), hydrogen-1 nuclear magnetic resonance (¹HNMR), carbon-13 nuclear magnetic resonance (¹³CNMR), and molecular docking calculations. The M-β-CD turned out to be the best substrate for the micro-encapsulation of both drugs. Also, ATV showed a higher tendency than ROV to form inclusion complexes with CDs. Molecular docking studies showed that HP–β–CD and M-β-CD are the most suitable substrates for the formation of inclusion complexes, respectively. Our research showed that the β-CD is not necessarily the most efficient substrate for increasing solubility based on previous reports in the literature; meanwhile, the other employed substrates in this study can show acceptable performances in this regard. According to our results, M-β-CD is the best substrate for the micro-encapsulation of both drugs, which increases their solubility in water.