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51.
The different groups and/or classes among phenolic acids and aldehydes identified during the elaboration process of "fino" sherry wine have been studied. The study was carried out using different processes during the elaboration of the wine and we have attempted to establish whether the different treatments of the grape affect these groupings. The study was undertaken by means of cluster and multifactorial analysis on the data obtained by the quantitative determination of phenolic acids and aldehydes during vinification and in experiments carried out on the grape under different mechanical treatments. The analysis of phenolic acids and aldehydes was done with HPLC, using a C-18 mu-Bondapak and a stepwise composite gradient. The samples were previously extracted with ethylic ether.  相似文献   
52.
Revolutionary developments in the patterns of world trade have taken place during the past five years, and Latin America is no exception. This article discusses the effects of the Latin American Free Trade Association, the Central American Common Market, and the Inter-American Development Bank on the economic integration of Latin America.  相似文献   
53.
Glycosaminoglycans (GAGs) and proteoglycans (PGs) are major components of the glycocalyx. The secreted GAG and CD44 ligand hyaluronic acid (HA), and the cell surface PG syndecan-1 (Sdc-1) modulate the expression and activity of cytokines, chemokines, growth factors, and adhesion molecules, acting as critical regulators of tumor cell behavior. Here, we studied the effect of Sdc-1 siRNA depletion and HA treatment on hallmark processes of cancer in breast cancer cell lines of different levels of aggressiveness. We analyzed HA synthesis, and parameters relevant to tumor progression, including the stem cell phenotype, Wnt signaling constituents, cell cycle progression and apoptosis, and angiogenic markers in luminal MCF-7 and triple-negative MDA-MB-231 cells. Sdc-1 knockdown enhanced HAS-2 synthesis and HA binding in MCF-7, but not in MDA-MB-231 cells. Sdc-1-depleted MDA-MB-231 cells showed a reduced CD24-/CD44+ population. Furthermore, Sdc-1 depletion was associated with survival signals in both cell lines, affecting cell cycle progression and apoptosis evasion. These changes were linked to the altered expression of KLF4, MSI2, and miR-10b and differential changes in Erk, Akt, and PTEN signaling. We conclude that Sdc-1 knockdown differentially affects HA metabolism in luminal and triple-negative breast cancer model cell lines and impacts the stem phenotype, cell survival, and angiogenic factors.  相似文献   
54.
Traditional management and control models can benefit from added levels of intelligence to increase their capability to adapt to the continuous changes in global markets. After reviewing the classical definition of intelligence and its levels, this paper provides a new approach to help increase the responsiveness of management and control to changes and disturbances in the manufacturing supply chain. The ancient concept of the “Tertium Quid” has inspired a three-level community of agents (MAS-TRIO) that is proposed to improve the coordination of all actors involved. The proposed model combines Multi-Agent Systems (MAS) with Radio-Frequency Identification (RFID) to make possible a certain level of Autonomous Intelligence in the decision-taking process. This paper analyses how these levels of intelligence can be applied to management and control, and the performance of the proposed model has been tested at low and mid-levels on an experimental platform representing the facilities of a distribution centre controlled by a network of programmable logic controllers (PLCs).  相似文献   
55.
The high computation requirements of global optimization algorithms, when used to solve real optimization problems, have caused the appearance of different parallelization strategies using several parallel computing architectures. In this work, the Universal Evolutionary Global Optimizer is implemented in CUDA to be run on GPU architectures (GPuEGO). This parallelization of the referred evolutionary multimodal optimization algorithm is rather different from other previous parallel implementations designed to be executed into shared or distributed memory processors. In this case, due to the special characteristics of a GPU architecture, the original data structures are not valid and it has been necessary to redefine them and all the functions that operate with them. When this approach is applied the acceleration factors achieved by GPuEGO range from \({\times }\) 6.33 to \({\times }\) 23.20 depending on the test function.  相似文献   
56.
By definition, virgin olive oil is consumed unrefined, although a great proportion of the olive oil produced has to be refined to render it edible. Phenolic compounds are among the substances eliminated during the refining process; in the present work these were characterized by HPLC, and their evolution during the different refining steps was studied. The complete refining process removed most polyphenols from oils, but the behavior of individual compounds at each step also was observed. o-Diphenols (hydroxytyrosol, catechol, and hydroxytyrosol acetate) and flavonoids (luteolin and apigenin) were eliminated first during the alkaline treatment. Tyrosol and 4-ethylphenol remained in the oil until the deodorization step. A large amount of phenolic compounds was discovered in the refining by-products such as soapstocks and deodorization distillates. In the latter streams, the concentrations of tyrosol and 4-ethylphenol reached up to 149 and 3720 mg/kg by-product, respectively. This high level of 4-ethylphenol and its well-known strong off-odor can interfere during further processing of the deodorization distillates, and this must be taken into account when deciding what is to become of them. Similarly, the results of this work open the possibility of recovering phenolic compounds from the “second centrifugation olive oils” by adding a new washing step prior to the refining process. By including this new step, the most polar polyphenols, hydroxytyrosol and tyrosol, will diffuse from oil to water and a concentration of up to 1400 mg/L of hydroxytyrosol may be achieved.  相似文献   
57.
This paper addresses the optimal least-squares linear estimation problem for a class of discrete-time stochastic systems with random parameter matrices and correlated additive noises. The system presents the following main features: (1) one-step correlated and cross-correlated random parameter matrices in the observation equation are assumed; (2) the process and measurement noises are one-step autocorrelated and two-step cross-correlated. Using an innovation approach and these correlation assumptions, a recursive algorithm with a simple computational procedure is derived for the optimal linear filter. As a significant application of the proposed results, the optimal recursive filtering problem in multi-sensor systems with missing measurements and random delays can be addressed. Numerical simulation examples are used to demonstrate the feasibility of the proposed filtering algorithm, which is also compared with other filters that have been proposed.  相似文献   
58.
The effect of alumina and nickel in sulfated ZrO2 as a catalyst for n-butane isomerization was investigated. Samples were synthesized by supporting nickel sulfated zirconia on boehmite and then calcining the material. The crystalline structure of ZrO2 was studied by X-ray powder diffraction and refined by the Rietveld method. Surface areas were determined by N2 adsorption and BET analysis, while the acid properties were studied by NH3 adsorption. The chemical reaction was carried out in a fixed-bed microreactor at 338 K under atmospheric (78 kPa) or 245 kPa total pressure. Results showed that either nickel or alumina improved the catalytic activity, but a synergic effect was observed when both components assisted. The catalytic activity was related to the relative content of tetragonal zirconia and acid site density. Alumina stabilized tetragonal zirconia increased the acid site density and presumably led to a better dispersion of nickel oxide. The catalytic activity could be related to both oxidation and acid sites produced by nickel. A bimolecular reaction mechanism helps explain the observed trends. The increase in the reaction rate would be explained by the increase in the rate of the initial step of dehydrogenation either caused by a better dispersion of nickel or higher operating pressure.  相似文献   
59.
The chiral phosphazene copolymers {[NP(O2C12H8)]0.9[NP(O2C20H12)]0.1} (1) and {[NP(O2C12H8)]0.9[NP(O2C20H10Br2)]0.1} n (2) [(O2C12H8) = 2,2′-dioxy-1,1′-biphenyl; (O2C20H12) = R-2,2′-dioxy-1,1′-binaphthyl and (O2C20H10Br2) = R-6,6′-dibromo-2,2′-dioxy-1,1′-binaphthyl] were prepared by sequential substitution from [NPCl2] n and the corresponding dihydroxy-biphenyl or binaphthyl reagents in the presence of Cs2CO3 and K2CO3. The reaction of (2) with tBuLi in THF, followed by addition of PPh2Cl and a treatment with SiHCl3/PPh3 to eliminate any oxidized OC6H4P(O)Ph2 groups, gave the phosphine containing copolymer {[NP(O2C12H8)]0.9[NP(O2C20H10[PPh2]2)]0.1} n (3), that was used as a chiral ligand to support [Ru(p-cymene)Cl] complexes. The resulting catalyst was active for hydrogen transfer from isopropyl alcohol to acetophenone but the placement of the Ru centers in the 6,6′-positions of the binaphthoxyphosphazene units induced no enantioselectivity. Dedicated to Professor Christopher Allen.  相似文献   
60.
Abstract. Since the seminal paper by Dickey and Fuller in 1979, unit‐root tests have conditioned the standard approaches to analysing time series with strong serial dependence in mean behaviour, the focus being placed on the detection of eventual unit roots in an autoregressive model fitted to the series. In this paper, we propose a completely different method to test for the type of long‐wave patterns observed not only in unit‐root time series but also in series following more complex data‐generating mechanisms. To this end, our testing device analyses the unit‐root persistence exhibited by the data while imposing very few constraints on the generating mechanism. We call our device the range unit‐root (RUR) test since it is constructed from the running ranges of the series from which we derive its limit distribution. These nonparametric statistics endow the test with a number of desirable properties, the invariance to monotonic transformations of the series and the robustness to the presence of important parameter shifts. Moreover, the RUR test outperforms the power of standard unit‐root tests on near‐unit‐root stationary time series; it is invariant with respect to the innovations distribution and asymptotically immune to noise. An extension of the RUR test, called the forward–backward range unit‐root (FB‐RUR) improves the check in the presence of additive outliers. Finally, we illustrate the performances of both range tests and their discrepancies with the Dickey–Fuller unit‐root test on exchange rate series.  相似文献   
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