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101.
102.
Banani Kundu Nicholas E. Kurland Subia Bano Chinmoy Patra Felix B. Engel Vamsi K. Yadavalli Subhas C. Kundu 《Progress in Polymer Science》2014
Biomaterials of either natural or synthetic origin are used to fabricate implantable devices, as carriers for bioactive molecules or as substrates to facilitate tissue regeneration. For the design of medical devices it is fundamental to use materials characterized by non-immunogenicity, biocompatibility, slow and/or controllable biodegradability, non-toxicity, and structural integrity. The success of biomaterial-derived biodevices tends to be based on the biomimetic architecture of the materials. Recently, proteins from natural precursors that are essentially structural and functional polymers, have gained popularity as biomaterials. The silks produced by silkworms or spiders are of particular interest as versatile protein polymers. These form the basis for diverse biomedical applications that exploit their unique biochemical nature, biocompatibility and high mechanical strength. This review discusses and summarizes the latest advances in the engineering of silk-based biomaterials, focusing specifically on the fabrication of diverse bio-mimetic structures such as films, hydrogels, scaffolds, nanofibers and nanoparticles; their functionalization and potential for biomedical applications. 相似文献
103.
Gerhard Heise Andreas Brner Marcel Dickmann Marina Englmaier Andreas Heiss Matthias Kemnitzer Jan Konrad Regina Moser Jrg Palm Helmut Vogt Heinz P. Huber 《Progress in Photovoltaics: Research and Applications》2015,23(10):1291-1304
In this paper, we present the selective structuring of all three patterns (P1, P2 and P3) of a monolithic interconnection of CIS (Cu(In,Ga)(S,Se)2) thin film solar cells by picosecond laser pulses at a wavelength of 1064 nm. We show results for single pulse ablation threshold values and line scribing of molybdenum films on glass (P1), CIS on molybdenum (P2) and zinc oxide on CIS (P3). The purposes of these processes are the p‐type isolation (P1), cell interconnect (P2) and n‐type isolation (P3), which are required for complete cell architecture. The half micron thick molybdenum back electrode can be structured with a process speed of more than 15 m/s at about 15 W average power without detectable residues and damage by direct induced laser ablation from the back side (P1). The CIS layer can be structured selectively down to the molybdenum at process speeds up to 1 m/s at about 15 W average power, due to the precision of direct laser ablation in the ultrashort pulse regime (P2). The ZnO front electrode layer is separated by clean trenches with straight side walls at process speeds of up to 15 m/s at about 10 W average power, as a result of indirect induced laser ablation (P3). A validation of functionality of all processes is demonstrated on CIS solar cell modules (30 × 30 cm2). By replacing one state‐of‐the‐art process by a picosecond laser process at a time, solar efficiencies could be increased for P1 and P2 and stayed on a similar level for P3. After an optimization of the patterning processes in the R&D pilot line of AVANCIS, we achieved a new record efficiency for an all‐laser‐patterned CIS solar module: 14.7% as best value for the aperture area efficiency of a 30 × 30 cm2 sized CIS module was reached. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
104.
Carrascoso Felix Li Hao Frisenda Riccardo Castellanos-Gomez Andres 《Nano Research》2021,14(6):1698-1703
Nano Research - Strain is a powerful tool to modify the optical properties of semiconducting transition metal dichalcogenides like MoS2, MoSe2, WS2 and WSe2. In this work we provide a thorough... 相似文献
105.
106.
Crosslinked poly(ester urethane)s and their acrylate derivatives based on trifunctional polycaprolactone and trifunctional aliphatic isocyanates were synthesized. Biodegradable scaffolds with uniform, controlled micron-scale porosity were fabricated with these materials. Mechanical and swelling properties of monolithic and microporous materials were studied. Cytotoxicity, hydrolytic, and enzymatic degradation and their effects on mechanical properties of the biodegradable scaffolds were investigated. The polymer degradation products were found not to be cytotoxic at moderate concentrations and to permit cell attachment and spreading. Degradation rates and mechanical properties could be tuned to desired performance criteria for a given application by adjusting crosslink density and the ratio of hard segment to soft segment. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48943. 相似文献
107.
Xiao Junbing Yan Hongjie Liu Liu Möller Felix Hu Zhiwen Unger Sebastian 《Metallurgical and Materials Transactions B》2019,50(6):3002-3011
Metallurgical and Materials Transactions B - Spout height is a widely used parameter to quantitatively analyze the performance of the submerged gas injection in industrial applications. However,... 相似文献
108.
Felix Amissah Shalina Taylor Randolph Duverna Lambert T. Ayuk‐Takem Nazarius S. Lamango 《European Journal of Lipid Science and Technology》2011,113(11):1321-1331
Polyisoprenylation is a set of secondary modifications involving proteins whose aberrant activities are implicated in cancers and degenerative disorders. The last step of the pathway involves an ester‐forming polyisoprenylated protein methyl transferase‐ and hydrolytic polyisoprenylated methylated protein methyl esterase (PMPMEase)‐catalyzed reactions. Omega‐3 and omega‐6 PUFAs have been linked with antitumorigeneis and tumorigenesis, respectively. PUFAs are structurally similar to the polyisoprenyl groups and may interfere with polyisoprenylated protein metabolism. It was hypothesized that PUFAs may be more potent inhibitors of PMPMEase than their more polar oxidative metabolites, the prostaglandins. As such, the relative effects of PUFAs and prostaglandins on PMPMEase could explain the association between cyclooxygenase‐2 (COX‐2) expression in tumors, the chemopreventive effects of the non‐steroidal anti‐inflammatory (NSAIDs) COX‐2 inhibitors and PUFAs. PUFAs such as AA, EPA, and DHA inhibited PMPMEase activity with Ki values of 0.12–3.7 µM. The most potent prostaglandin was 63‐fold less potent than AA. The PUFAs were also more effective at inducing neuroblastoma cell death at physiologically equivalent concentrations. The lost PMPMEase activity in AA‐treated degenerating cells was restored by incubating the lysates with COX‐1 or COX‐2. PUFAs may thus be physiological regulators of cell growth and could owe these effects to PMPMEase inhibition. Practical applications: Some PUFAs have been widely reported to have anticancer benefits. However, the molecular mechanisms for these effects are not well understood. The findings in the current paper appear to suggest that inhibition of PMPMEase may underlie their effects. They also imply that the expression of COX‐2 in various tumors may serve to convert the PUFAs into significantly less inhibitory prostaglandins. From these findings, AA and the other PUFAs, rather than being substrates for the synthesis of tumorigenic agents may actually contribute in suppressing cell proliferation. This being congruent with the lower cancer risks associated with long term use of anti‐inflammatory agents, the practical implications will likely include the nutritional and/or therapeutic management of cancer with the goal of maintaining suitable levels of the fatty acids in tissues. 相似文献
109.
v. Schröder Karl Boresch K. Dirr R. Ammon Diemair Griebel Schwaibold G. Mall Felicitas Rolleri Kanitz O. Windhausen K. Felix von Querner W. Ludorff E. Fischbach W. Sutthoff Frey-Wyssling Schormüller A. Pirson J. Großfeld E. Chytrek Koelitz Hans Hawelka W. Schreiber Brüning Estler Pawletta W. Wodsak Jesser H. J. Steinbeck Seuss Schmitz Lars Erlandsen W. Hämmerle Masch A. Bäurle W. Leithe Rudolj Abderhalden Haevecker Fr. Bartschat Garber G. Stamm Gertraude Körner-Hennig G. Steinhoff Johannes Wolf Rob Jungkunz Schönfeld Ed. Rentz Klinc K. Höll 《European Food Research and Technology》1940,79(6):568-608
110.
Schwaibold Schormüller Beckel W. Sutthoff Lars Erlandsen v. Skramlik W. Schreiber Kanitz Bierotte M. Steiner W. Wodsak G. Steinhoff H. J. Steinbeck Frey-Wyssling M. Gordienko K. Dirr Pawletta Stelzer W. Wodsak W. Bartels Hoepke G. Stamm Brüning W. Hämmerle Schnetka K. Felix H. Schülke Kluge Krzywanek W. Brandt Gertraude Körner-Hennig K. J. Demeter Damm J. Ph. Bruno Roßmann W. Karlowa H. Ketterl L. W. Jirak W. Preiß Diemair W. Ludorff Jahr Griebel J. J. van Eck W. Preiß C. Pyriki K. Müller Jesser K. Boresch Fr. Bartschat 《European Food Research and Technology》1939,77(3):290-336