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排序方式: 共有2352条查询结果,搜索用时 265 毫秒
31.
Ming Li Zbigniew Twardowski Felix Mok Norbert Tam 《Journal of Applied Electrochemistry》2007,37(4):499-504
Sodium dichromate is commonly used in sodium chlorate production to maintain high current efficiency; however, it is also
a well documented carcinogen. To reduce the environmental impact, identification of a suitable alternative with similar buffering
characteristics to dichromate and without adverse effect on the electrolytic performance of sodium chlorate production is
important; sodium molybdate is a good candidate. Molybdate ion and its conjugated acid work as a buffer pair at pH 5–6, a
lower and slightly narrower pH window than the typical buffer region of dichromate. Nonetheless, the molybdate buffer works
effectively during the electrolytic process by maintaining pH at 5.9. Although the use of molybdate buffer will lower the
overpotential of hydrogen evolution reaction (HER) by 100 mV, the average off-gas oxygen content is noticeably compromised
at 3.6–4.6%, measured using a pilot cell operated at 3 kA m−2and 80 °C during a 3-day trial. The resulting current efficiency of 91 92% is significantly lower than when dichromate is
employed as the process additive (> 96%). Mixtures of different dichromate and molybdate ratio were also investigated in terms
of the resulting cathode surface potential. 相似文献
32.
Felix Schmutzler Christopher Zschiesche Juliane Titus David Poppitz Jens Freiding Rainer Rakoczy Andreas Reitzmann Roger Gläser 《化学,工程师,技术》2021,93(6):981-989
The hydroisomerization of two long-chain n-alkane mixtures was investigated over bifunctional Pt/H-ZSM-5 catalysts before and after dealumination of preshaped zeolite/binder pellets. The hydroisomerization over the dealuminated catalysts leads to more isomers and less cracking products. Consequently, higher ratios of multi- to mono-branched isomerization products are formed as expected for large- rather than medium-pore zeolites. This indicates a higher availability of space in the vicinity of the active sites and provides an attractive route to make medium-pore zeolites suitable for upgrading higher boiling hydrocarbon feeds. 相似文献
33.
Christoph Windmeier Felix Flegiel Alexander Döß Ronald Franz Eckhard Schleicher Michael Wiezorek Markus Schubert Uwe Hampel 《化学,工程师,技术》2021,93(7):1119-1125
An optimized equipment design for natural gas processing and liquefaction plants becomes increasingly difficult with changing process conditions: Particularly low values of surface tension create rising challenges on the design of phase separators and column internals. The TERESA test rig at HZDR was designed to allow the investigation of multiphase thermohydraulics and phase separator performance under critical fluid properties in industrial dimensions. A versatile pipe test section is available in DN200 and equipment internals may be tested in a sectional DN300/DN500 test separator. The applied test fluid shows a high vapor-liquid density difference between 1470 and 940 kg m−3, viscosity as low as 0.12 mm2s−1, and surface tension down to 1.3 mN m−1. Volumetric liquid and vapor flow rates may be varied up to 9 and 530 m3h−1 in the test rig, respectively. 相似文献
34.
Thomas Fehn Felix Kugler Beatrice Tübke Rainer Schweppe Phillip Mebert Wolfgang Krcmar Ulrich Teipel 《化学,工程师,技术》2021,93(5):771-780
Due to the growing energy requirements, the proportion of external thermal insulation composite systems (ETICS) installed has increased significantly during the past 50 years. Due to the longevity of these systems, ETICS waste is currently accumulating. Owing to the complex construction as well as a multitude of differently installed materials and substances of the past generations, there are many uncertainties and problems with the clean and low-pollutant processing of such systems. In the frame of this work, the ETICS were processed and sorted before being screened for ingredients or pollutants as well as for the purity of the recovered material fractions. 相似文献
35.
Đurović Gordana Van Neerbos Francine A. C. Bossaert Sofie Herrera-Malaver Beatriz Steensels Jan Arnó Judit Wäckers Felix Sobhy Islam S. Verstrepen Kevin J. Jacquemyn Hans Lievens Bart 《Journal of chemical ecology》2021,47(8-9):788-798
Journal of Chemical Ecology - There is increasing evidence that microorganisms, particularly fungi and bacteria, emit volatile compounds that mediate the foraging behaviour of insects and therefore... 相似文献
36.
We present an algorithm for combining the elements of subsequences of a sequence with an associative operator. The subsequences are given by a sliding window of varying size. Our algorithm is greedy and computes the result with the minimal number of operator applications. 相似文献
37.
Yarlung Tsangpo (Brahmaputra) is the largest river system draining the northern slopes of the Himalayan ranges on the southern Tibetan Plateau. It remains one of only two large non‐regulated rivers in China. In this paper the chemical composition of Yarlung Tsangpo and its major tributaries (Raga Tsangpo, Nyangchu and Lhasa River) are studied. Water samples (n = 55) were collected and measured for major ions, trace elements and nutrients in order to: (1) define the present chemical quality of this water course; (2) address possible mechanisms governing the water chemical compositions, and (3) identify potential sources for contaminants. Multivariable analysis shows that geology and climate are the major explanatory variables for the spatial variation in water chemistry in this river system. In general, water chemistry is mainly controlled by carbonate weathering, with Ca2+ and HCO being the dominant ions. In addition, runoff from brackish/saline lakes and geothermal waters, enriched in Na+, Cl?, SO, Mg2+ and Li, are major contributors of elevated concentrations of these solutes in the headwater regions resulting in a relatively high loading of total dissolved solids (TDS, 146–397 mg L?1). Levels of most heavy metals and total dissolved nutrients were generally found to be low. However, elevated As concentration (avg. 95 μg L?1) in the headwaters and additions from untreated wastewater were evident at some locations. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
38.
39.
Kirsten Bobzin Erich Lugscheider Felix Ernst Reimo Nickel Nazlim Bagcivan Daniel Parkot Arne Schlegel Stefania Ferrara Tatyana Kashko Noémi Leick 《Microsystem Technologies》2008,14(12):1887-1894
Nowadays, micro components have to fulfill rising optical requirements for different scientific and industrial fields like
astronomy, medicine or multimedia. For this purpose, advanced miniaturized chip-cameras are produced for the microsystems
engineering market. The assembly and joining technologies play a very important role in the production of these micro components.
Several challenges are associated with the joining of chip-cameras. In this study, the application of the soldering technology
has been considered in order to face these challenges. Two joining technologies have been investigated: active soldering and
transient liquid phase (TLP) bonding. Both soldering processes have shown a big potential for hybrid microsystems joining
in previous studies. For both processes, soldering alloys and parameters have been conceived in order to fulfill the joining
requirements of the micro camera components. For instance, the joining temperature represents a major challenge because the
chip-camera consists of a plastic material, polymethyl methacrylate (PMMA). Therefore, particular attention has been directed
to the soldering as well as to the coating temperature. The experimental investigations concerning the solders application
through physical vapor deposition (PVD) have been supported by finite element method (FEM) simulations. The analysis of the
temperature distribution in the micro components during the coating process was the focus of the calculations. Possible undesirable
local overheated areas of the chip-camera components can be detected through simulation.
相似文献
Tatyana KashkoEmail: |
40.
O Lortholary M Danis P Casassus H Felix F Gay A Datry M Gentilini 《Canadian Metallurgical Quarterly》1994,145(3):155-158
PURPOSE: To identify clinical and biological features of subacute falciparum malaria, risk factors, and to evaluate the efficacy of curative treatment. PATIENTS AND METHODS: Diagnostic criteria were the association of apyrexia, anemia, little or no parasitemia and a high titer of anti-Plasmodium antibodies. Forty-three cases were observed in subjects returning from chloroquine-resistant areas in Africa. They were matched with controls for age, country of residence and duration of stay. Controls were missionaries who attended our unit for a routine medical check-up during the study period. RESULTS: The clinical presentation and biological features were similar to "malarial cachexia", a condition mainly described in non-immune children in endemic areas. Splenomegaly was present in 58% of the patients. Biological features included little or no parasitemia, an overall decrease in the blood cell count, an increased erythrocyte sedimentation rate and a high titer of anti-Plasmodium antibodies. This syndrome was not correlated with the frequency of chloroquine resistance, the area of stay (urban or rural) or to the kind of chemoprophylaxis. CONCLUSIONS: This study describes subacute resistant falciparum malaria in patients who had prolonged stay in chloroquine-resistant areas of Africa associating splenomegaly, cytopenia and a low or absent parasitemia. Subacute chloroquine-resistant malaria could be due to host factors which remained to be determined by prospective immunological studies. Curative treatment with mefloquine is effective. 相似文献