2,4,6 Tri-Chlorophenol Containing Wastewater Treatment Using a Hybrid-Loop Bioreactor System

A hybrid-loop bioreactor system consisting of a packed column biofilm and an aerated tank bioreactor with an effluent recycle was used for biological treatment of 2,4,6 tri-chlorophenol (TCP) containing synthetic wastewater. The effects of sludge age (solids retention time) on chemical oxygen demand (COD), TCP, and toxicity removal performance of the system were investigated for sludge ages between 5 and 30?days, while the feed COD (2600±100?mg?L?1), TCP (370±10?mg?L?1), and the hydraulic residence time (25?h) were constant. Percent TCP, COD, and toxicity removals increased with increasing sludge age resulting in nearly complete COD, TCP, and toxicity removal at sludge ages above 20?days. Biomass concentrations in the packed column and in the aeration tank increased with increasing sludge age resulting in low reactor TCP concentrations, and therefore, high TCP, COD, and toxicity removals. More than 95% of COD, TCP, and toxicity removal took place in the packed column reactor. Volumetric rates of TCP and COD removal increased due to increasing biomass and decreasing effluent TCP and COD concentrations with increasing sludge age. The specific rate of TCP removal was maximum (120?mg?TCP?gX?1?day?1) at a sludge age of 20?days. TCP inhibition was eliminated by operation of the system at sludge age above 20?days to obtain nearly complete COD, TCP, and toxicity removal.     

Shadow detection in colour high‐resolution satellite images

Image shadow segmentation has become a major issue in satellite remote sensing because of the recent commercial availability of high‐resolution images. Detecting shadows is important for successfully carrying out applications such as change detection, land monitoring, object recognition, scene reconstruction, colour correction, etc. This paper presents a simple and effective procedure to segment shadow regions on high‐resolution colour satellite images. The method applies a region growing process on a specific band (namely, the c ₃ component of the c ₁ c ₂ c ₃ colour space). To gain in robustness and precision, the region expansion also imposes a restriction on the saturation and intensity values of the shadow pixels, as well as on their edge gradients. The proposed method has been successfully tested on QuickBird images acquired under different lighting conditions and covering both urban and rural areas.     

Determination of neotectonic features of the Karasu Basin (SE Turkey) and their relationship with Quaternary volcanic activity using Landsat ETM+ imagery

The junction between the East Anatolian and the Dead Sea fault zones lies close to an unstable F: Transform fault (FFF) triple junction where the African, Eurasian and Arabian plates meet in south-eastern Turkey. The Karasu Basin is an ephemeral rifted structure located close to the junction of these plate boundaries and is expressed by a range of tectono-morphological features. This study uses remote sensing to define tectonic structures and discriminate volcanic rocks linked to rifting within the basin using Landsat Enhanced Thematic Mapper Plus (ETM+) imagery. Prior to advanced image processing stages, images were corrected to eliminate atmospheric scattering effects and determine the best band combination for multi-spectral processing techniques based on statistical methods. Following pre-processing stages, edge detection filters were applied to derive tectonic structures defining the basin. The Brovey transformation, a statistical data merging method, was used to combine reflective multi-spectral bands with the Landsat ETM+?panchromatic band. This method fuses higher spatial data with data of lower spatial value. The western margin of the Karasu Basin is defined by the left-lateral Amanos Fault Zone with a contemporary motion (c. –0.4 mm a^?1) probably accommodating most of the left-lateral strike-slip motion between Arabian and African plates on the northern continuation of the Dead Sea Fault Zone. The rift zone has been the site of extensive recent volcanism concentrated within the Brunhes Chron (<0.78 Ma) and linked to fault block rotations between the intracontinental master faults. The boundaries of this activity are defined here using a regolith mapping technique.     

Fermentation of cheese whey powder solution to ethanol in a packed‐column bioreactor: effects of feed sugar concentration

BACKGROUND: Cheese whey powder (CWP) is a concentrated source of lactose and other essential nutrients for ethanol fermentation. CWP solution containing different concentrations of total sugar was fermented to ethanol in an up‐flow packed‐column bioreactor (PCBR) at a constant hydraulic residence time (HRT) of 50 h. Total sugar concentration in the feed was varied between 50 and 200 g L^?1 and a pure culture of Kluyveromyces marxianus was used for ethanol fermentation of lactose. Variations of ethanol and sugar concentrations with the height of the column and with the feed sugar concentration were determined. RESULTS: Ethanol concentration increased and total sugar decreased with the column height for all feed sugar contents. The highest effluent ethanol concentration (22.5 g L^?1) and ethanol formation rate were obtained with feed sugar content of 100 g L^?1. Percentage sugar utilization decreased with increasing feed sugar content above 100 g L^?1 yielding lower ethanol contents in the effluent. The highest ethanol yield coefficient (0.52 gE g^?1S) was obtained with a feed sugar content of 50 g L^?1. Biomass concentration also decreased with column height, yielding low ethanol formation in the upper section of the column. CONCLUSION: The packed column bioreactor was found to be effective for ethanol fermentation from CWP solution. The optimum feed sugar content maximizing the effluent ethanol and the specific rate of ethanol formation was found to be 100 g L^?1. High sugar content above 100 g L^?1 resulted in low ethanol productivities due to high maintenance requirements. Copyright © 2008 Society of Chemical Industry     

Salt Inhibition Effects in Biological Treatment of Saline Wastewater in RBC

Design and operation of saline wastewater treatment systems are difficult because of adverse effects of salt on microbial flora. Quantification and modeling of salt inhibition effects are essential in designing biological treatment processes for saline wastewater. Synthetic wastewater containing 0–10% salt (NaCl) was treated in a rotating biodisc contactor (RBC) unit operating in a continuous mode. Effects of important process variables such as the A∕Q ratio, COD loading rate, and salt concentration on COD removal rate and efficiency were investigated. The system's performance improved with an increasing A∕Q ratio; however, performance decreased with an increasing COD loading rate and salt content. The liquid phase was aerated to keep suspended cells active at high feed COD concentrations such as S0 = 5,000 mg∕L. A mathematical model was developed to describe the system's behavior. Model parameters were determined by using the experimental data. Salt inhibition was found to be significant for salt concentrations larger than 2% NaCl. The experimental results and mathematical model may be used in design of RBC units treating saline wastewater.     

Antibacterial oil‐based polyurethane films for wound dressing applications

As an alternative to petroleum‐based polyol, hydroxyl containing material was prepared from linseed oil for polyurethane synthesis. Hexamethylene di‐isocyanate (HMDI) and/or 4, 4′‐methylene diphenyl di‐isocyanate (MDI) were used as isocyanate source. The polymerization reaction was carried out without catalyst. Polymer films were prepared by casting‐evaporation technique. The MDI/HMDI‐based polyurethane and its films had higher T_g and better thermal property than that of the HMDI‐based one because of the existence of benzene ring in the polymer chain. Static water contact angle was determined to be 74° and 77.5° for HMDI and MDI/HMDI‐based films, respectively. Water adsorption was found to be around 2.6–3.6% for both films. In vitro degradation of polyurethanes in phosphate buffered saline at 37°C was investigated by gravimetric method. Fourier transform infrared spectroscopy and scanning electron microscopy were used for confirmation of degradation on the polymer surface. The degradation rate of the HMDI‐based polyurethane film was found higher than that of the MDI/HMDI‐based film. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films, and the polyurethane films investigated here was not cytotoxic. Silver‐containing films were prepared using Biocera A® as filler and were screened for their antibacterial performance against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and/or Bacillus subtilis. The films prepared with and without Biocera A® exhibited antibacterial activity. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Determination of optimum thickness of double-glazed windows for the climatic regions of Turkey

In this study, the optimum air layer thickness of double-glazed windows is determined using the degree-days method. Calculations are obtained for ?skenderun, Kocaeli, Ankara and Ardahan which are in different climate zones of Turkey. Heating cost of the objective function is calculated for natural gas, coal, fuel-oil, electricity and LPG. The optimum air layer thickness is obtained for three different base temperatures which are 18, 20 and 22 °C. The results show that the optimum air layer thickness varies between about 12 and 15 mm depending on the climate zone, fuel type and base temperature. The effect of the fuel type and the base temperature on the optimum air layer thickness diminishes in cold zones. It is shown that with a well-optimized glazed window, up to 60% energy saving can be achieved.     

Assessment of olive cake as soil amendment for the controlled release of triazine herbicides

Organic matter-rich agricultural by-products are being produced in huge quantities and can be applied to soil as a disposal strategy. The application of two different rates (2 and 8% w/w) of olive cake to a Mediterranean calcareous soil resulted in an increased sorption of four triazine herbicides, which was higher for the more hydrophobic compounds (terbuthylazine and prometryn) and lower for the more polar ones (simazine and cyanazine). However, when the sorption coefficients were normalised to the total soil organic carbon (K(oc)), the results did not significantly differ between simazine and cyanazine which is an indication that the olive cake did not exert different sorption capacity for both compounds. On the contrary, K(oc) values for terbuthylazine and prometryn increased in the amended soils. Our results from experiments using mixtures of several pesticides suggest that competition for sorption sites resulted in a decrease of herbicide sorption. Desorption was hysteretical both for the amended and unamended soils, but the addition of olive cake at the highest dose diminished desorption of most of the herbicides. In conclusion, the addition of olive cake behaves as a promising method for reducing the risk of groundwater pollution by pesticides.