Ultrathin polypyrrole films on self-assembled monolayers as an efficient ultramicroelectrode assay

In this work, we investigated the effect of electrodeposition of polypyrrole (PPy) films on two different self-assembled monolayers (SAMs) modified gold electrode for the electrochemical construction of ultramicroelectrode (UME). In order to obtain SAM modified surfaces, 4-mercapto-1-butanol and 11-mercaptoundecanoic acid were used. The effect of these two chains on pyrrole electropolymerization was compared. Electropolymerization of pyrrole on SAM modified Au electrode was carried out by using cyclic voltammetry (CV) and constant potential electrolysis. To investigate the UME formation, the obtained surfaces were tested in Fe(CN)₆^3−/4− redox system. UMEs were characterized using scanning electron microscopy energy-dispersive X-ray spectroscopy, attenuated total reflectance fourier transform infrared spectroscopy and electrochemical impedance spectroscopy. The designed UME was applied as an immobilization matrix to entrap a redox protein, Hemoglobin (Hb), as a model. Direct electron transfer between this protein and the fabricated thiol modified PPy based UME was achieved, which is very challenging on bare electrode surfaces. With this study, a simple, low-cost and reproducible UME production way has been successfully accomplished and Hb modified UME is promising for different bioanalytical applications, for instance; cellular hydrogen peroxide or nitrite sensing.     

Nonlinear finite element analysis of masonry wall strengthened with CFRP strips

In many experimental studies, it has been proved that unreinforced masonry (URM) brick walls have high strength against lateral forces acting in plane. However, out-of-plane strength of URM brick walls against lateral forces has found to be quite low. According to the experiences that were obtained from the major earthquakes, the low out-of-plane performance of URM brick walls resulted in excessive loss of human lives during an earthquake, hence the strengthening of URM brick walls with CFRP strips has been appeared to be a very important subject. However, very limited literature has been found. Especially, the data obtained from experimental studies must be increased for the true understanding of the behavior of strengthened brick walls under out-of-plane lateral forces. However, in most cases, this procedure required large number of expensive experiments. At this stage, numerical analysis can be an appropriate choice, thus in this paper a finite element model is presented for modeling URM brick walls that are strengthened with CFRP strips. The numerical results are compared with the experimental ones and consistent results are obtained from the finite element model. General purpose finite element analysis software ANSYS is used throughout this study. Contact elements are used along the masonry wall–CFRP strip interfaces for the investigation of the stress distribution and load – strain behavior.     

Locally adaptive <Emphasis Type="Italic">k</Emphasis> parameter selection for nearest neighbor classifier: one nearest cluster

The k nearest neighbors (k-NN) classification technique has a worldly wide fame due to its simplicity, effectiveness, and robustness. As a lazy learner, k-NN is a versatile algorithm and is used in many fields. In this classifier, the k parameter is generally chosen by the user, and the optimal k value is found by experiments. The chosen constant k value is used during the whole classification phase. The same k value used for each test sample can decrease the overall prediction performance. The optimal k value for each test sample should vary from others in order to have more accurate predictions. In this study, a dynamic k value selection method for each instance is proposed. This improved classification method employs a simple clustering procedure. In the experiments, more accurate results are found. The reasons of success have also been understood and presented.     

Compressive moduli and network parameters of N‐isopropylacrylamide hydrogels copolymerized by monoesters of itaconic acid and crosslinked with tetraallylammonium bromide

The present study focuses on the mechanical properties of hydrophilically or hydrophobically modified poly(N‐isopropylacrylamide) (PNIPAAm) hydrogels, and all discussions on their improved mechanical strengths are based on the conformational effects of hydrophobic side chains attached to the comonomers and the structural differences between the crosslinkers. Three different types of monoalkyl itaconates, bearing octyl (Oc), cetyl (Ce), and cyclohexyl (CH) groups as comonomers, were used to prepare the copolymeric PNIPAAm hydrogels crosslinked with N,N′‐methylenebisacrylamide (BIS) and tetraallylammonium bromide (TAB) as neutral tetrafunctional and ionic octafunctional crosslinkers, respectively. The most striking result is the compressive E modulus of TAB‐crosslinked PNIPAAm hydrogel containing 10 mol % of mOcI. It reaches nearly 1.0 MPa and is independent of the temperature and pH of the swelling/shrinking medium. The result was discussed in terms of the inter/intramolecular interactions between hydrophobic octyl groups adopting a rod‐like conformation in the case of 25 °C/distilled deionized water (DDW) and 37 °C/DDW combinations. Further, it was observed that the electrostatic repulsive forces between the carboxylate groups on mOcI units could be suppressed even at 37 °C and pH 9 due to the rod‐like conformations of C₈H₁₇ groups. Its micrographs under bright‐field and polarized light supported the presence of an ordered anisotropic phase and multiple associations of extended, hydrophobic side chains. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45039.     

Fabrication of a novel polyhedral oligomeric silsesquioxanes/polyether‐block‐amide nano‐hybrid membrane for pervaporative separation of model fuel butanol

The present study reports the pervaporative separation capability of the pristine and polyhedral oligomeric silsesquioxanes (POSS) loaded hybrid polyether‐block ‐amide (PEBA) membranes for n ‐butanol recovery from the dilute n ‐butanol–water mixtures. It is the first study to produce POSS‐loaded PEBA membranes for n ‐butanol recovery. The morphology and crosslinking structure of the pristine and hybrid membrane were characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The thermal stability and crystallization behaviors of the pristine and hybrid membranes were investigated using thermogravimetric analysis and differential scanning calorimetry methods. Swelling experiments were also done to determine the affinity of the membranes to the n ‐butanol–water mixture. The effect of increasing amount of POSS on pervaporation performance was investigated in terms of flux and the n ‐butanol separation factor at 40 °C and a given n ‐butanol. All the hybrid membranes exhibited high flux and n ‐butanol separation factor than that of the pristine PEBA membrane. The best n ‐butanol separation factor of 27.2 was obtained accompanied with 1.33 Kg m^?2 h^?1 of flux, when the POSS amount was 4 wt %. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45211.     

Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite

The adsorption of Congo Red onto bentonite in a batch adsorber has been studied. Four kinetic models, the pseudo first- and second-order equations, the Elovich equation and the intraparticle diffusion equation, were selected to follow the adsorption process. Kinetic parameters; rate constants, equilibrium adsorption capacities and correlation coefficients, for each kinetic equation were calculated and discussed. It was shown that the adsorption of Congo Red onto bentonite could be described by the pseudo second-order equation. The experimental isotherm data were analyzed using the Langmuir, Freundlich and Temkin equations. Adsorption of Congo Red onto bentonite followed the Langmuir isotherm. A single stage batch adsorber was designed for different adsorbent mass/treated effluent volume ratios using the Langmuir isotherm.     

Strain measurement under the minimal controller synthesis algorithm and an extensometer design

In this paper, minimal controller synthesis (MCS) algorithm is used in the case of strain measurement for the first time. The MCS control is an adaptive control method and it can be recommended as a robust controller for the servohydraulic materials testing machine. The algorithm coped with various specimens, which have different materials and diameters. The control accuracy is important in materials testing due to the fact that even smaller overshoots or undershoots can cause undesirable results in cyclic loading. For this reason, the controller parameters needs to adjusted according to the changes in the plant parameters for acceptable plant output responses.In order to measure strain signal a simple LVDT extensometer was designed. In this set tests, two different specimens were used: aluminium alloy specimens of diameter 10 mm and EN24T steel specimens of diameter 7 mm. The MCS control was implemented in two degrees of freedom form and produced very satisfactory plant output responses owing to the fact that the results produced by the control are in the range of actual values. This indicates that the MCS control can be used in strain measurement very effectively. It may also indicate the possibility of using the MCS control other materials testing applications like strain control and temperature cycle tests.     

Experimental investigation of thermal performance of a double-flow solar air heater having aluminium cans

This study experimentally investigates a device for inserting an absorbing plate made of aluminium cans into the double-pass channel in a flat-plate solar air heater (SAH). This method substantially improves the collector efficiency by increasing the fluid velocity and enhancing the heat-transfer coefficient between the absorber plate and air. These types of collectors had been designed as a proposal to use aluminium materials to build absorber plates of SAHs at a suitable cost. The collector had been covered with a 4-mm single glass plate, in order to reduce convective loses to the atmosphere. Three different absorber plates had been designed and tested for experimental study. In the first type (Type I), cans had been staggered as zigzag on absorber plate, while in Type II they were arranged in order. Type III is a flat plate (without cans). Experiments had been performed for air mass flow rates of 0.03 kg/s and 0.05 kg/s. The highest efficiency had been obtained for Type I at 0.05 kg/s. Also, comparison between the thermal efficiency of the SAH tested in this study with the ones reported in the literature had been presented, and a good agreement had been found.     

Deformation and orientation behavior of polystyrene-b-polybutadiene-b-poly(methyl methacrylate) triblock terpolymers: Influence of polybutadiene microstructures and the molar masses

Morphological changes caused by deformation and orientation of different domains of polystyrene-b-polybutadiene-b-poly(methyl methacrylate), SBM, triblock terpolymers were investigated using in-situ small angle X-ray scattering (SAXS), tensile testing, and transmission electron microscopy (TEM). Two sets of SBM triblock terpolymers with similar weight fractions of the three blocks were studied. The two sets differ in terms of their molecular weights. Each set contained two SBM differing in their polybutadiene isomers (1,2- and 1,4-B). Results showed that for 1,2-B based SBMs the polybutadiene block forms cylindrical domains which coalesce in the glassy lamellar matrix of the two glassy outer blocks whereas the lower molar mass 1,4-B based SBM forms mixed S/M and the higher one forms well segregated long range ordered lamellae. These morphological differences indicate that the deformation and the orientation behavior of the polymers' domains differ. In 1,2-B based SBMs yielding at high stresses was followed by a stress drop after the yield point. The other polymer type showed homogeneous deformation of the lamellar domains at their yield point. 2D-SAXS during deformation of the triblock terpolymers showed an anisotropic deformation pattern in the 1,2-B SBMs, whereas four point SAXS patterns were found for the 1,4-B SBMs. Further studies showed that the fragmented lamellar planes of the lower molar mass 1,2-SBM oriented randomly whereas the orientation of the lamellar planes of the higher molar mass 1,2-B SBM was parallel to the strain direction. The alignment of the lamellar planes of 1,4-B SBMs were randomly distributed in the unstretched state.