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81.
Elementary fractional transfer functions are studied in this paper. Some basic properties of elementary transfer functions of the first kind are recalled. Then, two main results are presented regarding elementary fractional transfer functions of the second kind, written in a canonical form and characterized by a commensurate order, a pseudo-damping factor, and a natural frequency. First, stability conditions are established in terms of the pseudo-damping factor and the commensurate order, as a corollary to Matignon’s stability theorem. They extend the previous result into conditions that are simpler to check. Then, resonance conditions are established numerically in terms of the commensurate order and the pseudo-damping factor and give interesting information on the frequency behavior of fractional systems. It is shown that elementary transfer functions of the second kind might have up to two resonant frequencies. Moreover, three abaci are given allowing to determine the pseudo-damping factor and the commensurate order for, respectively, a desired normalized gain at each resonance, a desired phase at each resonance, and a desired normalized first or second resonant frequency.  相似文献   
82.
The heat resistance and the structural integrity of syntactic foam materials are vital for their high performance. Syntactic foam made of hollow glass microspheres and Diglycidyl Ether of Bisphenol A (DGEBA) based epoxy resin cured with Isophorone Diamine (IPD) hardener was subjected to oxidative thermal stress cycles. The degraded syntactic foam sample was examined using an X-ray Micro Computed Tomography (XμCT) to evaluate its internal damage between each state in a combined effect of cycling and increased temperature. Glass microsphere fracture, void enlargement and resin microcracks were observed as a result of the thermal stress using 3D XμCT images. The reconstructed slice representation showed the microcracks and microsphere damage distribution inside the sample. The damaged glass spheres percentage is shown to increase sharply with the progress of the thermal cycle. There was no change in the local density of the syntactic foam as a result of the thermal cycle. An XμCT system proves to be a successful non-destructive technique for examining syntactic foam for defects and structural damages in the micron scale.  相似文献   
83.
    
In an effort to select the best possible medical grade of polyether ether ketone (PEEK) for active medical implants application, it was necessary to inspect surface thermodynamic properties of different grades and correlate with self-bonding (autohesion) strength. Autohesion is the process of choice for encapsulating active medical implants made of PEEK. Temperature modulated DSC was used to investigate crystallinity and thermal events of range of medical grade PEEK (semi-crystalline, amorphous, semi-crystalline with amorphous surface, minerals and black masterbatch filled). Lab shear test was used to measure autohesive forces between PEEK samples pressed at moderate temperature (200 °C) and pressure. Samples with higher mobile amorphous region (MAF) and lower degree of crystallinity (Wc) resulted in higher autohesivce bonding strength. However, semi crystalline PEEK with surfaces that showed high MAF and low Wc resulted in higher autohesive bonding strength when compared with crystalline samples. The presence of fillers (minerals and black masterbatch) in the crystalline structure doubled the autohesive bonding strength values of the semi-crystalline sample. The presence of large crystalline region and a larger portion of the rigid amorphous region acted negatively on autohesion strength. Semi-crystalline PEEK with a special manufacturing procedure to produce amorphous surface produced the best choice among the PEEK grades. This grade have the desired thermodynamical properties in the bulk while exhibiting best surface adhesion strength.  相似文献   
84.
    
Time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) was used to investigate correlations between the molecular changes and postcuring reaction on the surface of a diglycidyl ether of bisphenol A and diglycidyl ether of bisphenol F based epoxy resin cured with two different amine‐based hardeners. The aim of this work was to present a proof of concept that ToF‐SIMS has the ability to provide information regarding the reaction steps, path, and mechanism for organic reactions in general and for epoxy resin curing and postcuring reactions in particular. Contact‐angle measurements were taken for the cured and postcured epoxy resins to correlate changes in the surface energy with the molecular structure of the surface. Principal components analysis (PCA) of the ToF‐SIMS positive spectra explained the variance in the molecular information, which was related to the resin curing and postcuring reactions with different hardeners and to the surface energy values. The first principal component captured information related to the chemical phenomena of the curing reaction path, branching, and network density based on changes in the relative ion density of the aliphatic hydrocarbon and the C7H7O+ positive ions. The second principal component captured information related to the difference in the surface energy, which was correlated to the difference in the relative intensity of the CxHyNz+ ions of the samples. PCA of the negative spectra provided insight into the extent of consumption of the hardener molecules in the curing and postcuring reactions of both systems based on the relative ion intensity of the nitrogen‐containing negative ions and showed molecular correlations with the sample surface energy. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009  相似文献   
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The main objective of this paper was to estimate tip‐tilt disturbances in adaptive optics systems. In a bounded‐error context, set inversion methods based on interval analysis are used to guarantee both state and parameter estimation of tip‐tilt disturbances. Consequently, two methods are performed. The first method is based on contraction–bisection, and the second one is based only on contraction. Both methods are thus compared, and results are discussed according to computational time and pessimism introduced on each estimated parameter. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
87.
    
PEEK is the polymer of choice to replace metal encapsulants and other parts in active medical implants fixated into bone. The current challenge is to improve its biocompatibility with bone tissue to ultimately achieve osseointegration. PEEK sheets surfaces coated with plasma deposited nano thin polymer films using CH4, (CH4 + O2) and (CH4 + N2) gases. PEEK samples plasma treated with nonpolymerizing gases (O2) were also used for comparison. The adhesion performance of osteoblast like cells on the plasma‐treated PEEK surfaces and the presence of Vinculin in these cells were evaluated after long culturing period (12 days). X‐ray photoelectron spectroscopy and Auger spectroscopy were used to provide surface molecular information, surface hardness and molecular density. All plasma‐treated surfaces retained functionality after the sterilization process. PEEK surfaces with high number of oxygen functional groups and particularly oxygen rich thin polymer coating (plasma deposition using CH4+O2 gas mixture) resulted in strong cellular adhesion strength and large Vinculin amount. Further, osteoblast‐like cells responded better to surfaces with lower molecular density acting like another signal for cell adhesion. The osteoblast‐like cells response was weaker for surfaces with both thin films with nitrogen functional groups and nonfunctional (nonpolar) films. Furthermore, thin films rich in nitrogen functional groups repelled the cells, showed abnormal cells shape, smaller Vinculin amount and induced thicker cellular clusters with poor spread. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42181.  相似文献   
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