Waterpipe smoking: construction and validation of the Lebanon Waterpipe Dependence Scale (LWDS-11).

Waterpipe smoking is becoming fashionable in Lebanon, but no studies have studied nicotine dependence related to waterpipe smoking. A score was constructed from 21 items and subsequently submitted to two factor analyses, which led to the extraction of four factors. Reliability and test-retest reproducibility were measured. Convergent construct validity and discriminant validity also were assessed for different smokers' samples. The Lebanon Waterpipe Dependence Scale-11 (LWDS-11) was composed of four subscales, the first representing nicotine dependence, the second negative reinforcement, the third psychological craving, and the fourth positive reinforcement. Internal consistency and test-retest reproducibility were adequate, and the subscales correlated adequately with measurements of nicotine metabolites, exhaled carbon monoxide levels, and the frequency of waterpipe smoking. The LWDS-11 discriminated between mild, moderate, and heavy waterpipe smokers, based on a threshold score of 10. Results were biologically and psychologically sound. This is the first scale to characterize waterpipe dependence. With further improvement and confirmation, it could become a useful clinical and epidemiological tool.     

Analyzing furnace-lining integrity using nodal wear modeling

The Nodal Wear Model was developed to systematize the analysis of corrosion phenomena on refractory and ceramic materials that come in contact with corrosive fluids in furnace linings. The model is based on the determination of the thermal field in the furnace lining using a finite-element-method grid in which a second grid is defined to represent the surface of the lining that is attacked by the molten phases. Using a control equation for the wear-corrosion thermal-activated phenomena, a modification of the geometry is introduced and a new geometry is defined to restart the calculation. For more information, contact Roberto A. Parra, Universidad de Concepción-Chile Departamento de Ingeniería Metalúrgica, Edmundo Larenas 285, Concepcion, Chile; +56-41-20-46-63; fax +56-41-22-00-45; e-mail rparra@udec.cl.     

Relation between the critical state friction angle of sands and low vertical stresses in the direct shear test

In this study, the critical state friction angle in a direct shear box was tested at vertical effective stresses between 4?kPa and 150?kPa for seven sands of different origins. The results show a stress dependency on the angle of friction at low vertical stresses, and that the critical state friction angle decreases with increase in the vertical effective stress. The largest drop occurs for vertical effective stresses between 4?kPa and 50?kPa and varies between 4° and 10° depending mostly on the shape of the sand particles and the difference in the extreme void ratios.     

Evaluation of uncertainties in sewer condition assessment

Closed Circuit Television Inspection is used since decades as industry standard for sewer system inspection and structural performance evaluation. In current practice, inspection data are helpful to support asset management decisions. However, the quality and uncertainty of sewer condition assessment is rarely questioned. This article presents a methodology to determine the probability to underestimate, overestimate or accurately estimate the real condition of a pipe using visual inspection. The approach is based on the analysis of double inspections of the same sewer pipes and has been tested using the extensive data-set of the city of Braunschweig in Germany. Results indicate that the probability to inspect correctly a pipe in poor condition is close to 80%. The probability to overestimate the condition of a pipe in bad condition (false negative) is 20% whereas the probability to underestimate the condition of a pipe in good condition (false positive) is 15%. Finally, sewer condition evaluation can be used to assess the general condition of the network with an excellent accuracy probably because the respective effects of false positive and false negative are buffered.     

Distribution of T-2 and HT-2 toxins in milling fractions of durum wheat

The effect of processing on mycotoxin content in milling fractions has been investigated in 10 samples of durum wheat contaminated with T-2 and HT-2 toxins at levels ranging from 97 to 5,954 μg/kg (sum of T-2 and HT-2 toxins). Either naturally contaminated samples or samples artificially inoculated with Fusarium sporotrichioides under field conditions were used. A method based on liquid chromatography-tandem mass spectrometry coupled with immunoaffinity column cleanup was validated in-house for the simultaneous analysis of both toxins in a variety of matrices, including uncleaned wheat, cleaned wheat, screenings, bran, red dog, fine middlings, and semolina. Mean recoveries from samples spiked with T-2 and HT-2 toxins at levels of 100 μg/kg ranged from 85 to 107%, with relative standard deviations (RSDs) lower than 14%. The milling process led to an increase of T-2 and HT-2 toxin contents up to 13- and 5-fold in screenings and bran, respectively, compared with occurrence in the uncleaned wheat; however, an overall reduction of T-2 and HT-2 toxins by 54% (RSD, 20%) and 89% (RSD, 3%) was observed in cleaned wheat and in semolina, respectively.     

Electrochemical reduction of hexahydro-1,3,5-trinitro-1,3,5-triazine in aqueous solutions

Electrochemical reduction of RDX, hexahydro-1,3,5-trinitro-1,3,5-triazine, a commercial and military explosive, was examined as a possible remediation technology for treating RDX-contaminated groundwater. A cascade of divided flow-through cells was used, with reticulated vitreous carbon cathodes and IrO2/Ti dimensionally stable anodes, initially using acetonitrile/water solutions to increase the solubility of RDX. The major degradation pathway involved reduction of RDX to the corresponding mononitroso compound, followed by ring cleavage to yield formaldehyde and methylenedinitramine. The reaction intermediates underwent further reduction and/or hydrolysis, the net result being the complete transformation of RDX to small molecules. The rate of degradation increased with current density, but the current efficiency was highest at low current densities. The technique was extended successfully both to 100% aqueous solutions of RDX and to an undivided electrochemical cell.     

Life cycle assessment of a community hydroelectric power system in rural Thailand

Rural electrification and the provision of low cost, low emission technology in developing countries require decision makers to be well informed on the costs, appropriateness and environmental credentials of all available options. While cost and appropriateness are often shaped by observable local considerations, environmental considerations are increasingly influenced by global concerns which are more difficult to identify and convey to all stakeholders.Life cycle assessment is an iterative process used to analyse a product or system. This study iteratively applies life cycle assessment (LCA) to a 3 kW community hydroelectric system located in Huai Kra Thing (HKT) village in rural Thailand. The cradle to grave analysis models the hydropower scheme’s construction, operation and end of life phases over a period of twenty years and includes all relevant equipment, materials and transportation.The study results in the enumeration of the environmental credentials of the HKT hydropower system and highlights the need to place environmental performance, and LCA itself, in a proper context. In the broadest sense, LCA results for the HKT hydropower system are found to reflect a common trend reported in hydropower LCA literature, namely that smaller hydropower systems have a greater environmentally impact per kWh – perform less well environmentally - than larger systems. Placed within a rural electrification context, however, the HKT hydropower system yields better environmental and financial outcomes than diesel generator and grid connection alternatives.