Tellurium clusters in channels of the porous silica ZSM-11

The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) ?. The clusters Te₄ are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) ?. Original Russian Text ? A.E. Lapshin, Yu.F. Shepelev, Yu.I. Smolin, E.A. Vasil’eva, 2008, published in Fizika i Khimiya Stekla.     

A fragmentary model of vitreous As<Subscript>2</Subscript>S<Subscript>3</Subscript>

The X-ray scattering intensity curves for vitreous As₂S₃ are experimentally measured using soft (copper) and hard (molybdenum) X rays. The inclusion of all the specific features revealed in the experimental scattering intensity curves makes it possible to obtain the experimental atomic radial distribution function (ARDF) in the ordering range up to ～1 nm. The experimental ARDF is interpreted in the framework of the fragmentary model. A comparison of the experimental ARDF with the model ARDF calculated from the crystal structure data obtained for orpiment demonstrates that the corrugated layers inherent in crystalline As₂S₃ are retained in the glass structure but the characteristic interlayer interatomic distances are absent. The layers are joined together through the As₄S₅ molecular clusters. Microcrystals consisting of several unit cells are absent in the glass structure, which involves only the structural fragments of both crystalline analogs. One of the possible variants of their joining is proposed.     

γ-Absorption express analysis of the moisture content of coal concentrate in coke production

Coal concentrate with minimum moisture content is used for coke production in metallurgy. At various enterprises, the moisture content is determined by weighing [1]. However, this method is slow and is undertaken in the laboratory. To reduce the loss of production, accelerated monitoring of the moisture content in industrial conditions is required.     

Study of medium-cement concrete based on mixed Chamotte-periclase chromite filler

The possibility is demonstrated of using an addition of periclase-chromite filler (PCF) prepared from PCF grade broken material articles in medium-cement concrete with chamotte filler. The effect of this addition on cement hardening duration, strength and heat resistance is considered. Translated from Novye Ogneupory, No. 8, pp. 42–46, August 2008.     

Study of the microstructure of ceramics from different producers used for protecting precious metal thermocouples

Results are provided for a study of the microstructure of ceramics from four different producers by means of a scanning electron microscope and x-ray microanalysis. Results show that ceramic specimens often do not correspond to claimed parameters. The main disadvantages are ceramic structural inhomogeneity, presence of phases of a different nature, intergranular pores and cracks, and alkali impurities. The ceramics of only one producer correspond to the main parameters for this class, and this is provided by high production technology and starting material quality. Translated from Novye Ogneupory, No. 7, pp. 31–35, July 2008.     

Optical orientation of holes in strained nanostructures

A theory describing the optical orientation and Hanle effect for holes in quantum wells or quantum dots based on cubic semiconductors is developed. It is demonstrated that the presence of internal or external strain in quantum-confinement heterostructures leads to the dependence of the Hanle effect on the orientation of the magnetic field with respect to the heterostructure growth axis.     

Potential applications of LF-noise spectroscopy to the development of new-generation gas sensors

The solution proposed relates to flicker-noise gas sensors under development, which differ from conventional chemical sensors in offering exceptional selectivity for the analysis of a gaseous environment. The classification and analytical justification are given of low-frequency-noise spectroscopy techniques and measures that are proposed for investigation of disordered semiconductors. The feasibility is shown of patterning processes for flicker-noise gas sensors. Some methods are proposed for these processes and for measurement procedures of gaseous-environment monitoring.     

Robustness of classification rules that incorporate additional information

The discrimination problem for two normal populations with the same covariance matrix when additional information on the population is available is considered. A study of the robustness properties against training sample contamination of classification rules that incorporate this additional information is performed. These rules have received recently attention where their total misclassification probability (TMP) is proved to be lower than Fisher's linear discriminant rule. The results of a simulation study on the TMP which compares the behaviour of the new rules against Fisher's rule and some of its robustified versions under different types of contamination are presented. These results show that the rules that incorporate the additional information not only have lower TMP, but they also prevent against some types of contamination. In order to achieve prevention from all types of contamination a robustifed version of these rules is recommended.     

Elimination of organic matter present in wastewaters from the cork industry by membrane filtration

BACKGROUND: The first stage of the cork industrial process generates great volumes of wastewater with moderate to high organic pollutant content that must be purified using different procedures, such as filtration by membranes. RESULTS: The tangential filtration of these wastewaters was studied using two different laboratory equipments. In the first one, three ultrafiltration (UF) membranes were tested, with molecular weight cut‐off (MWCO) 100 kDa and 30 kDa, and two operating modes were used: total recycling of permeate and retentate streams, and in continuous mode, without recycling both streams. In the total recycling UF experiments, the influence of the operating variables on the permeate flux was first established. The effectiveness of the different membranes was determined by evaluating the rejection coefficients for several parameters that measure the global pollutant content of the effluent. The values found for these rejection coefficients were in the following order: ellagic acid and color > absorbance at 254 nm > tannic content > COD (chemical oxygen demand). In the continuous mode experiments, the fouling mechanism for each membrane was established by fitting the experimental data to various filtration fouling models given in the literature. The operating mode in the second equipment was batch concentration, and additional experiments were carried out with an UF membrane (2 kDa), and with a NF membrane (with MWCO in the range 150–300 Da). CONCLUSIONS: The three operating modes tested provided different rejection levels of organic matter; among them, the most effective procedure tested was batch concentration mode using a NF membrane. Copyright © 2007 Society of Chemical Industry     

Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis

Sibunit-supported Ru-catalysts promoted with cesium or rubidium compounds have been comparatively studied with XPS. The cesium promoter interacts both with support and with active component. The absence of the promoter–support interaction in the case of rubidium provides a stronger interaction between promoter and active component compared to the cesium-based catalysts. These differences in the promoter–support and promoter–metal interactions are exhibited when a sequence of ruthenium and alkali introduction are changed.