Nanoporous gold bumps for low temperature bonding

Nanoporous gold bumps have been deposited on silicon wafers by electroplating a silver–gold alloy followed by etching the silver. An open-porous cellular structure of gold at meso-scale is left on top of the bumps. For flip chip bonding we found low temperature and low force bonding conditions. The porous interconnects have very promising properties, like compressibility and reduced stiffness, which should result in higher bond yield and extended reliability.     

Double‐Inverse‐Opal Photonic Crystals: The Route to Photonic Bandgap Switching

Photonic crystals with a complete bandgap can stop the propagation of light of a certain frequency in all directions. We introduce double‐inverse‐opal photonic crystals (DIOPCs) as a new kind of optical switch. In the DIOPC, a movable, weakly scattering sphere is embedded within each pore of the inverse‐opal photonic crystal lattice. Switching between a diffusive reflector and a photonic crystal environment is experimentally demonstrated. Theory shows that a complete bandgap can be realized that can be opened or closed by moving the spheres. This functionality opens up new possibilities for the control of light emission and propagation. The close link and interaction between the chemical synthesis and the computational design and analysis underlines the interdisciplinary focus of this report.     

Enhancing impedance imaging through multimodal tomography

Several noninvasive modalities including electrical impedance tomography (EIT), magnetic induction tomography (MIT), and induced-current EIT (ICEIT) have been developed for imaging the electrical conductivity distribution within a human body. Although these modalities differ in how the excitation and detection circuitry (electrodes or coils) are implemented, they share a number of common principles not only within the image reconstruction approaches but also with respect to the basic principle of generating a current density distribution inside a body and recording the resultant electric fields. In this paper, we are interested in comparing differences between these modalities and in theoretically understanding the compromises involved, despite the increased hardware cost and complexity that such a multimodal system brings along. To systematically assess the merits of combining data, we performed 3-D simulations for each modality and for the multimodal system by combining all available data. The normalized sensitivity matrices were computed for each modality based on the finite element method, and singular value decomposition was performed on the resultant matrices. We used both global and regional quality measures to evaluate and compare different modalities. This study has shown that the condition number of the sensitivity matrix obtained from the multimodal tomography with 16-electrode and 16-coil is much lower than the condition number produced in the conventional 16-channel EIT and MIT systems, and thus, produced promising results in terms of image stability. An improvement of about 20% in image resolution can be achieved considering feasible signal-to-noise ratio levels.     

新型隔热和导电防护服综述

介绍了隔热导电防护服的市场状况及发展趋势、新型防护服的标准和需求分布,隔热导电防护服的测试方法。     

Charge transfer in thin films of donor–acceptor complexes studied by infrared spectroscopy

The degree of charge transfer in thin films of organic charge transfer (CT)-complexes, which are deposited via thermal evaporation, is examined via infrared-spectroscopy. We demonstrate a linear relationship between the shift in the excitation energy of the CN-stretching mode of CT-complexes with the acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the charge transfer. The measured correlation corresponds very well with DFT calculations. For Na-TCNQ we observe a splitting in the peak of the CN-stretching mode, which can be explained by the coupling of two modes and was confirmed by the calculations. In CT-complexes with partial charge transfer the appearance of an electronic excitation is demonstrated.     

Merocyanine/C60 Planar Heterojunction Solar Cells: Effect of Dye Orientation on Exciton Dissociation and Solar Cell Performance

In this study the charge dissociation at the donor/acceptor heterointerface of thermally evaporated planar heterojunction merocyanine/C₆₀ organic solar cells is investigated. Deposition of the donor material on a heated substrate as well as post‐annealing of the complete devices at temperatures above the glass transition temperature of the donor material results in a twofold increase of the fill factor. An analytical model employing an electric‐field‐dependent exciton dissociation mechanism reveals that geminate recombination is limiting the performance of as‐deposited cells. Fourier‐transform infrared ellipsometry shows that, at temperatures above the glass transition temperature of the donor material, the orientation of the dye molecules in the donor films undergoes changes upon annealing. Based on this finding, the influence of the dye molecules’ orientations on the charge‐transfer state energies is calculated by quantum mechanical/molecular mechanics methods. The results of these detailed studies provide new insight into the exciton dissociation process in organic photovoltaic devices, and thus valuable guidelines for designing new donor materials.     

The Zn(S,O,OH)/ZnMgO buffer in thin‐film Cu(In,Ga)(Se,S)2‐based solar cells part II: Magnetron sputtering of the ZnMgO buffer layer for in‐line co‐evaporated Cu(In,Ga)Se2 solar cells

A ZnS/Zn_1‐xMg_xO buffer combination was developed to replace the CdS/i‐ZnO layers in in‐line co‐evaporated Cu(In,Ga)Se₂(CIGS)‐based solar cells. The ZnS was deposited by the chemical bath deposition (CBD) technique and the Zn_1‐xMg_xO layer by RF magnetron sputtering from ceramic targets. The [Mg]/([Mg] + [Zn]) ratio in the target was varied between x = 0·0 and 0·4. The composition, the crystal structure, and the optical properties of the resulting layers were analyzed. Small laboratory cells and 10 × 10 cm² modules were realized with high reproducibility and enhanced stability. The transmission is improved in the wavelength region between 330 and 550 nm for the ZnS/Zn_1‐xMg_xO layers. Therefore, a large gain in the short‐circuit current density up to 12% was obtained, which resulted in higher conversion efficiencies up to 9% relative as compared to cells with the CdS/i‐ZnO buffer system. Peak efficiencies of 18% with small laboratory cells and 15·2% with 10 × 10 cm² mini‐modules were demonstrated. Copyright © 2009 John Wiley & Sons, Ltd.     

Fresnel-integral approximation

In diffraction analysis, an approximation to K_-(x)=1/(√π)e^ix(2)+iπ/4∫_x ^∞e^-it(2) dt, (0-(x), suitable for computation with a hand-held computer, such as the HP-288     

Quadrature Amplitude Modulation for Differential Space-Time Block Codes

Differential Space-Time Block Codes (DSTBC) do not require any radio channel measurement and channel state information neither on the transmitter nor at the receiver side. Therefore, they are an attractive alternative to coherent Multiple-Input Multiple-output (MIMO) systems. The classical technical proposal for differential techniques is based on M-ary phase shift keying (M-PSK) modulation schemes for DSTBC (PSK-DSTBC). One advantage of this scheme is the constant envelop of the transmit signal, but it is well known that higher-order PSK is less efficient due to the small distance between adjacent points in the constellation diagram. Therefore, in this paper an alternative modulation technique for DSTBC is discussed, which is based on quadrature amplitude modulation (QAM-DSTBC). The signal envelope of the transmit signal is not any more constant in this case. Therefore, the technical challenge of integrating QAM into the DSTBC system design is to control the transmit power in order to avoid an increase or a decrease in transmit power to some extreme values. The mechanism, which is used in this paper to control the transmit power is based on an extension of the original QAM constellation diagram. The additional points, which are integrated into the constellation diagram are used in this case for the mapping procedure to select one of the modulation symbols with high or alternatively low signal power. This means for each single bit pattern there are almost always two modulation symbols available in the mapping procedure one with low and one with high signal power, which gives the basis for a signal power control algorithm. The resulting bit-error-rate (BER) performance of QAM-DSTBC is compared finally to the performance figures of the original proposal of PSK-DSTBC.