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排序方式: 共有338条查询结果,搜索用时 31 毫秒
331.
332.
Koresawa M Kikuchi K Mizukami S Kojima H Urano Y Higuchi T Nagano T 《Analytical chemistry》2000,72(20):4904-4907
A novel detection system using both emission energy transfer and time-resolved fluorometry (TRF) was developed, with a europium chelate as the energy donor and a novel fluorophore SNR1, excitable with long-wavelength light corresponding to europium emission, as the energy acceptor. When the donor and acceptor molecules were mixed in solution, energy transfer was observed without direct attachment of the donor and the acceptor, via a diffusion-enhanced energy-transfer mechanism. Thus, the acceptor emission can be detected as a long-lifetime fluorescence in TRF. When the fluorescence properties of the acceptor molecule are changed by interaction with an enzyme or other bioactive molecule, the change can be detected as a long-lived sensitized emission. If we develop or select suitable acceptor molecules, this simple and convenient system should be applicable to a wide variety of bioactive molecules. Since it is based on TRF, it can be used for high-resolution assay. 相似文献
333.
Hom Nath Luitel Takanori Watari Rumi Chand Toshio Torikai Mitsunori Yada Hiroshi Mizukami 《Materials Science and Engineering: B》2013,178(12):834-842
Color point tuning is an important challenge for improving the practical applications of various displays, especially there are very limited white color single hosts that emits in the white spectrum. In this paper, the possibility of color tuning by substituting part of host lattice cation (Sr2+ ions) by Ca2+ or Ba2+ ions in an efficient strontium aluminate phosphor, Sr4Al14O25:Eu2+,Dy3+, is reported and found to be very promising for displays. A detail study by replacing part of Sr2+ with Ca2+ or Ba2+ has been investigated. X-ray diffraction study showed that crystal structure of Sr4Al14O25 is preserved up to 20 mol of Ca2+ ion exchange while it is limited to 10 mol of Ba2+ ions exchange. Substantial shift in the emission band and color were observed by substitution of Sr2+ by Ca2+ or Ba2+ ions. A bluish-white emission and afterglow was observed at higher Ca2+ ions substitution. Further, partial Ca2+ substitutions (up to 0.8 mol) resulted in enhanced afterglow of Sr4Al14O25:Eu2+,Dy3+ phosphor. However, Ba2+ substitution decreased the fluorescence as well afterglow of the Sr4Al14O25:Eu2+,Dy3+ phosphor significantly. The enhanced phosphorescence by partial Ca2+ substitution is explained on the basis of increased density of shallow traps associated with higher solubility of Dy3+ ions in to the host lattice due to equivalent size of Ca2+ and Dy3+ ions. Thus, Ca2+ substitution in the Sr4Al14O25:Eu2+,Dy3+ phosphor is a promising method for tuning the emission color and improving the afterglow intensity of the phosphor. 相似文献
334.
Urabe Y Shiomi T Itoh T Kawai A Tsunoda T Mizukami F Sakaguchi K 《Chembiochem : a European journal of chemical biology》2007,8(6):668-674
Hemoblogin (Hb), which is a typical oligomeric protein, was introduced into the pores of mesoporous silica (FSM: folded-sheet mesoporous material) that had a diameter of 7.5 nm. Soret CD spectra of Hb-FSM-7.5 conjugates showed a peak that was identical to that of free Hb. This suggests that Hb retained its highly ordered structure in the mesoporous silica. In addition, the UV-visible absorption spectrum showed that Hb had an increased resistance to heat denaturation in the silica. Even after heat treatment at 85 degrees C, Hb-FSM-7.5 retained its ligand-binding activity. The stability of Hb-FSM-7.5 was examined further by measuring its peroxidase-like activity. Encapsulation of Hb resulted in the retention of activity in the presence of high NaCl or Gdn-HCl levels. This suggests that encapsulation prevented dissociation and denaturing. Thus, it seems that the mesopores created a favorable environment for the oligomeric protein to perform its function, even under harsh conditions. 相似文献
335.
336.
Satoshi Abo Naoyuki Masuda Fujio Wakaya Shinobu Onoda Toshio Hirao Takeshi Ohshima Toshiaki Iwamatsu Mikio Takai 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2010,268(11-12):2074-2077
The difference of soft error rates (SERs) in conventional bulk Si and silicon-on-insulator (SOI) static random access memories (SRAMs) with a technology node of 90 nm has been investigated by helium ion probes with energies ranging from 0.8 to 6.0 MeV and a dose of 75 ions/μm2. The SERs in the SOI SRAM were also investigated by oxygen ion probes with energies ranging from 9.0 to 18.0 MeV and doses of 0.14–0.76 ions/μm2. The soft error in the bulk and SOI SRAMs occurred by helium ion irradiation with energies at and above 1.95 and 2.10 MeV, respectively. The SER in the bulk SRAM saturated with ion energies at and above 2.5 MeV. The SER in the SOI SRAM became the highest by helium ion irradiation at 2.5 MeV and drastically decreased with increasing the ion energies above 2.5 MeV, in which helium ions at this energy range generated the maximum amount of excess charge carriers in a SOI body. The soft errors occurred by helium ions were induced by a floating body effect due to generated excess charge carriers in the channel regions. The soft error occurred by oxygen ion irradiation with energies at and above 10.5 MeV in the SOI SRAM. The SER in the SOI SRAM gradually increased with energies from 10.5 to 13.5 MeV and saturated at 18 MeV, in which the amount of charge carriers induced by oxygen ions in this energy range gradually increased. The computer calculation indicated that the oxygen ions with energies above 13.0 MeV generated more excess charge carriers than the critical charge of the 90 nm node SOI SRAM with the designed over-layer thickness. The soft errors, occurred by oxygen ions with energies at and below 12.5 MeV, were induced by a floating body effect due to the generated excess charge carriers in the channel regions and those with energies at and above 13.0 MeV were induced by both the floating body effect and generated excess carriers. The difference of the threshold energy of the oxygen ions between the experiment and the computer calculation might be due to the difference between the designed and real structures. 相似文献
337.
The effects of time‐temperature and strain history on potato starch melts at 150 °C were investigated by use of a capillary tube viscometer. Reciprocating and single extrusions were performed in this study. Shear stress at single extrusion decreased gently as initial heating time increased, while shear stress at reciprocating extrusion decreased rapidly as the number of extrusion strokes increased. A high degree of cold water solubility was obtained by reciprocal extrusion at lower moisture content. From the results of gel filtration it could be concluded that starch molecules were depolymerized by high and reciprocal shear stress. According to these results time‐temperature history was more effective on the depolymerization of starch molecules and degradation of starch granules at higher moisture content, while strain history was more effective at lower moisture content. 相似文献
338.
Challenges Based on Antiplasmodial and Antiviral Activities of 7-Chloro-4-aminoquinoline Derivatives
Dr. Satoshi Mizuta Dr. Farhana Mosaddeque Dr. Mya Myat Ngwe Tun Dr. Awet Alem Teklemichael Mayumi Taniguchi Masashi Hosokawa Tomoko Yamaguchi Dr. Juliann Makau Dr. Nguyen Tien Huy Dr. Shusaku Mizukami Prof. Noriyuki Nishida Prof. Kouichi Morita Prof. Kenji Hirayama 《ChemMedChem》2023,18(7):e202200586
We report the structural functionalization of the terminal amino group of N1-(7-chloroquinolin-4-yl) butane-1,4-diamine, leading to a series of 7-chloro-4-aminoquinoline derivatives, and their evaluation as potent anti-malarial and anti-viral agents. Some compounds exhibited promising anti-malarial effects against the Plasmodium falciparum 3D7 (chloroquine-sensitive) and Dd2 (chloroquine-resistant) strains. In addition, these compounds were assayed in vitro against influenza A virus (IAV) and severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). Compound 5 h , bearing an N-mesityl thiourea group, displayed pronounced anti-infectious effects against malaria, IAV, and SARS-CoV-2. These results provide new insights into drug discovery for the prevention or treatment of malaria and virus co-infection. 相似文献