A Thermoplastic Gel Electrolyte for Stable Quasi‐Solid‐State Dye‐Sensitized Solar Cells

Dye‐sensitized solar cells (DSSCs) are receiving considerable attention as low‐cost alternatives to conventional solar cells. In DSSCs based on liquid electrolytes, a photoelectric efficiency of 11 % has been achieved, but potential problems in sealing the cells and the low long‐term stability of these systems have impeded their practical use. Here, we present a thermoplastic gel electrolyte (TPGE) as an alternative to the liquid electrolytes used in DSSCs. The TPGE exhibits a thermoplastic character, high conductivity, long‐term stability, and can be prepared by a simple and convenient protocol. The viscosity, conductivity, and phase state of the TPGE can be controlled by tuning the composition. Using 40 wt % poly(ethylene glycol) (PEG) as the polymeric host, 60 wt % propylene carbonate (PC) as the solvent, and 0.65 M KI and 0.065 M I₂ as the ionic conductors, a TPGE with a conductivity of 2.61 mS cm^–2 is prepared. Based on this TPGE, a DSSC is fabricated with an overall light‐to‐electrical‐energy conversion efficiency of 7.22 % under 100 mW cm^–2 irradiation. The present findings should accelerate the widespread use of DSSCs.     

DNA Computing Boosted by a Cationic Copolymer

The huge information storage capability of DNA and its ability to self‐assemble can be harnessed to enable massively parallel computing in a small space. DNA‐based logic gates are designed that rely on DNA strand displacement reactions; however, computation is slow due to time‐consuming DNA reassembly processes and prone to failure as DNA is susceptible to degradation by nucleases and under certain solution conditions. Here, it is shown that the presence of a cationic copolymer boosts the speed of DNA logic gate operations that involve multiple and parallel strand displacement reactions. Two kinds of DNA molecular operations, one based on a translator gate and one on a seesaw gate, are successfully enhanced by the copolymer without tuning of computing conditions or DNA sequences. The copolymer markedly reduces operation times from hours to minutes. Moreover, the copolymer enhances nuclease resistance.     

Growth of large-diameter ZnTe single crystals by liquid-encapsulated melt growth methods

The 80-mm-diameter ZnTe single crystals were successfully obtained by the liquid-encapsulated Kyropoulos (LEK) method. Both 〈100〉- and 〈110〉-oriented single crystals were reproducibly grown by using ZnTe seed crystals. Furthermore, 80-mm-diameter, 〈100〉 and 〈110〉 ZnTe single crystals were obtained by the pulling method. The etch pit densities (EPDs) of the grown crystals by the LEK and pulling methods were lower than 10,000 cm⁻². The strain in the grown crystals by the pulling method was lower than that of LEK crystals.     

Dynamic properties of an all solid-state frequency-shifted feedbacklaser

Frequency-shifted feedback (FSF) laser exhibits outstanding features in its oscillation spectrum. We analyze build-up dynamic properties of the FSF laser by means of rate equation and analyze steady-state dynamic properties of the FSF laser by means of Wigner-Ville distribution of intracavity electric field. Furthermore, we analyze instantaneous oscillation frequency at peak spectral intensity and oscillation bandwidth of its spectrum using the formula of instantaneous spectral intensity derived from Wigner-Ville distribution of intracavity electric field. These analytical results are in good agreement with the experimental ones which have been observed by a diode-pumped Nd:YVO₄ FSF laser. It becomes clear that the FSF laser supports many frequency components simultaneously even though the gain medium is homogeneously broadened and has a continuously chirped frequency components of comb in which the creation of chirped frequency components are strongly correlated in phase because of a replica of the preceding components. Also, the instantaneous oscillation frequency is closely related to the detuning frequency which depends on the total net gain in the cavity and the gain bandwidth of atomic transition. The oscillation bandwidth is defined as the product of the saturation-broadened bandwidth and the total resonant modes contributing to FSF operation     

Analysis of course errors on CVOR antennas (including effects ofmutual coupling between elements)

A VHF omnidirectional radio range (VOR) is a navigation aid radio beacon facility, which provides aircraft with azimuth information relative to the VOR station in question as the origin. In Japan, two types of VOR-the conventional type (referred to as a CVOR) and the Doppler type (referred to as a DVOR)-are currently in use. An element known as the Alford loop antenna (ALA), which changes the loading reactance, is used for the VOR because the horizontally polarized wave and nondirectivity in the horizontal plane are preferred. A VOR antenna consists of a carrier antenna and a sideband antenna-an aircraft receives separate signals from these two antennas and compares them to obtain azimuth information. The mutual coupling between the elements forming the carrier and the sideband antenna affects the directivity of the single elements, resulting in errors in azimuth information. With the mutual coupling between the antenna elements being taken into consideration, a quantitative calculation was made by using the moment method-the results of the calculation made it clear that a loading reactance value of -320 Ω is better to make not mutually coupled elements nondirectional while a loading reactance value of -600 Ω is optimum to minimize the azimuth error of a CVOR     

Thickness scaling limitation factors of ONO interpoly dielectricfor nonvolatile memory devices

This paper describes the scaling limitation factors of ONO interpoly dielectric thickness, mainly considering the charge retention capability and threshold voltage stability for nonvolatile memory cell transistors with a stacked-gate structure, based on experimental results. For good intrinsic charge retention capability, either the top- or bottom-oxide thickness should be greater than around 6 nm. On the other hand, a thicker top oxide structure is preferable to minimize degradation due to defects. It has been confirmed that a 3.2 nm bottom-oxide shows detectable threshold voltage instability, but 4 nm does not. Effective oxide thickness scaling down to around 13 nm should be possible for flash memory devices with a quarter-micron design rule     

Group 3 error-free facsimile terminal for analog cellular networks

A Group 3 error-free facsimile terminal for use in an analog cellular network has been developed. This facsimile terminal is provided with the International Telecommunication Union (ITU-T, formerly CCITT) T.30 recommendation protocol and an adaptive error control scheme (AECS) for Group 3 communication and error-free communication. The AECS monitors the channel conditions and selects the optimum error correction code. The ITU-T V.27ter is used as the modulation method and the transmission rate is 4800 bps. This system is compatible with the modified Huffman (MH), modified READ (MR), and modified modified READ (MMR) image data compression codes. The average communication time of this facsimile terminal is 40 s per page while moving through the analog cellular network     

Fabrication of long-period fibre grating by CO/sub 2/ laser-annealing in fibre-drawing process

Long-period fibre grating (LPFG) writing by a CO₂ laser-annealing using a fibre-drawing process is demonstrated. The fibre in the drawing process was irradiated periodically by a CO₂ laser to modify the refractive index. An LPFG with transmission loss of -10 dB and full width at half-maximum of 13 nm has been fabricated. Results show that the refractive index change was induced by stress at the moment of laser annealing     

Novel Conjugated Organic Dyes for Efficient Dye‐Sensitized Solar Cells

Novel conjugated organic dyes that have N,N‐dimethylaniline (DMA) moieties as the electron donor and a cyanoacetic acid (CAA) moiety as the electron acceptor were developed for use in dye‐sensitized nanocrystalline‐TiO₂ solar cells (DSSCs). We attained a maximum solar‐energy‐to‐electricity conversion efficiency (η) of 6.8 % under AM 1.5 irradiation (100 mW cm^–2) with a DSSC based on 2‐cyano‐7,7‐bis(4‐dimethylamino‐phenyl)hepta‐2,4,6‐trienoic acid (NKX‐2569): short‐circuit photocurrent density (J_sc) = 12.9 mA cm^–2, open‐circuit voltage (V_oc) = 0.71 V, and fill factor (ff) = 0.74. The high performance of the solar cells indicated that highly efficient electron injection from the excited dyes to the conduction band of TiO₂ occurred. The experimental and calculated Fourier‐transform infrared (FT‐IR) absorption spectra clearly showed that these dyes were adsorbed on the TiO₂ surface with the carboxylate coordination form. A molecular‐orbital calculation indicated that the electron distribution moved from the DMA moiety to the CAA moiety by photoexcitation of the dye.     

A 99-mm2 0.7-W single-chip MPEG-2 422P@ML video, audio,and system encoder with a 64-Mb embedded DRAM for portable 422P@HLencoder system

A scalable single-chip 422P@ML MPEG-2 video, audio, and system encoder LSI for portable 422P@HL system is described. The encoder LSI is implemented using 0.13-μm embedded DRAM technology. It integrates 3-M logic gates and 64-Mb DRAM in an area of 99-mm². The power consumption is suppressed to 0.7 W by adopting a low-power DRAM core. It performs real-time 422P@ML video encoding, audio encoding, and system encoding with no external DRAM. Furthermore, the encoder LSI realizes a 422P@HL video encoder with multichip configuration, due to its scalable architecture. This results in a PC-card size 422P@HL encoder for portable HDTV codec system