SQUID NMR Studies of the Second Layer of 3He at High Density

Nuclear magnetism in the second layer of ³He films on graphite has been studied as a function of density in the zero-field limit at temperatures down to 300 µK. Total surface coverages in this study ranged from 20 atoms/nm² (the lowest coverage at which the effective exchange parameter turns ferromagnetic) through the two-phase region (ending at about 24 atoms/nm²) and into the single-phase imcommensurate solid region up to 31.2 atoms/nm². The surface layers were studied using both pulsed and cw NMR measured with our SQUID NMR system in magnetic fields of 500 µT and lower. As the surface density continues to increase in the single-phase region, the exchange constant decreases consistently with a picture of steric hindrance impeding ferromagnetic exchange. Several different observational features scale with this inferred exchange: low-field magnetization, NMR frequency shift, and the temperature of onset of significant magnetization.     

The reaction of ceria coatings on mica with H2S: An in-situ X-ray diffraction study

Thin layers of ceria were deposited on the surface of mica platelets in solution. The reaction of such particles with hydrogen sulfide yields a red colored special effect pigment. The ceria layer reacts with H₂S to produce a variety of sulfide and oxysulfide phases. The reaction path discovered in situ by time and temperature resolved X-ray diffraction is CeO₂→CeS₂→C-Ce₂S₃→Ce₁₀S₁₄O. The reaction itself is extremely variable depending on gas flow, heating rates and decomposition atmospheres. Effects on the thin film are recorded by scanning electron microscopy (SEM) and revealed a destruction of the layer once red Ce₁₀S₁₄O was formed. The product layer then reveals the typical nonwetting behaviour of a liquid on a surface.     

Synthesis of LiFePO4 with fine particle by co-precipitation method

LiFePO₄ is a potential candidate for the cathode material of the lithium secondary batteries. A co-precipitation method was adopted to prepare LiFePO₄ because it is simple and cheap. Nitrogen gas was needed to prevent oxidation of Fe²⁺ in the aqueous solution. The co-precipitated precursor shows the high reactivity with the reductive gas, and the single phase of LiFePO₄ is successfully synthesized with the aid of carbon under less reductive conditions. LiFePO₄ fine powder prepared by co-precipitation method shows high rate capability, impressive specific capacity and cycle property.     

On the role of high-energy electrons in the formation of a plasma-beam discharge structure in a diode with a slit cathode

The spatial structure of visible emission from plasma of a transverse nanosecond pulsed electric discharge in a gas-filled diode with a hollow (slit) cathode has been experimentally studied. A relation is established between the regime of electron energy relaxation and the plasma-beam discharge structure formation. High values of the electron emission coefficient are observed in the experiment, which cannot be explained using the notion of electron emission from a cathode bombarded by fast heavy particles.     

High-strain-rate superplasticity of nanocrystalline aluminum alloy 1570

The structure and mechanical properties of nanocrystalline aluminum alloy 1570 obtained by means of severe plastic deformation have been studied. Being tested in a temperature range from 300 to 400°C, the alloy exhibits high-strain-rate superplasticity. At 400°C, the superplasticity is manifested in a very broad range of strain rates, extending from 5 × 10^?3 to 1 s^?1.     

Studying chaotic microwave oscillations in a TWO with depressed collector

Broadband chaotic oscillations were monitored in a depressed potential collector of a traveling-wave oscillator (TWO). This signal appears due to the oscillations of a virtual cathode, which is formed in the spent electron beam under the action of retarding fields existing in the multistage depressed collector.     

Optical properties of strain-compensated InAs/InGaAsN/GaAsN superlattices

The optical properties of heterostructures comprising InAs/InGaAsN quantum wells in strain-compensated GaAsN/InGaAsN superlattices have been studied. It is demonstrated that, using such superlattices of various design and thickness and with additional InAs monolayer spacers, it is possible to control the wavelength of room-temperature emission from InGaAsN quantum wells within 1.3–1.6 μm without deteriorating the output radiation characteristics, which opens additional prospects for the development of lasers on GaAs substrates for telecommunication applications.     

Increasing the efficiency of metal-air current sources operating in a pulse-train mode

A considerable (～1.4-fold) increase in the average output power of a chemical current source has been achieved by means of a periodic pulsed manipulation of the load. A scheme used for the pulse-train loading is presented and mechanisms ensuring an increase in the average output power of the current source are considered.     

Piezoresistive Behavior Study on Finger‐Sensing Silicone Rubber/Graphite Nanosheet Nanocomposites

A novel finger‐sensing nanocomposite with remarkable and reversible piezoresistivity is successfully fabricated by dispersing homogeneously conductive graphite nanosheets (GNs) in a silicone rubber (SR) matrix. Because of the high aspect ratio of the graphite nanosheets, the nanocomposite displays a very low percolation threshold. The SR/GN nanocomposite with a volume fraction of conductive nanosheets closest to that for the percolation threshold presents a sharp positive‐pressure coefficient effect of the resistivity under very low pressure, namely, in the finger‐pressure range (0.3–0.7 MPa), whereby the abrupt transition could be attributed to compressive‐stress‐induced deformation of the conducting network. The super‐sensitive piezoresistive behavior of the nanocomposite is accounted for by an extension of the tunneling conduction theory which provides a good approximation to the piezoresistive effect.     

Properties of gasars-metallic materials with pores formed by released hydrogen

We developed a new type of porous materials with anisotropic structure based on a large number of metals. It is shown that these material, called gasars, have properties different from the properties of the other porous materials. Thus, the strength of gasars is much higher than the strength of powder materials with the same porosity and their impact toughness is readily regulated by the sizes of the pores. The internal structures of gasars and possible versions of the types of pores in these materials are strongly diversified, which makes the spectrum of their possible applications very wide. We discuss some specific directions of the potential applications of gasars. The results of measurements of the thermal conductivity of gasars and monolithic specimens are presented. It is shown that, for a certain level of porosity, the specific thermal conductivity of gasars is higher than for monolithic materials. We also make some basic conclusions concerning the characteristics of new porous materials. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 5, pp. 125–127, September–October, 2007.