Chloroaromatic formation in incineration processes

The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.     

Procedure for predicting settlements of thawing bases for engineering calculations

It was shown that in order to compute the settlement of thawing cohesive soil under a load in time it is necessary to experimentally determine the consolidation coefficient. A procedure is suggested for determining this coefficient, as well as use of the classical solution of a differential equation for seepage consolidation to describe the settlement of soil, thawing of which can occur according to any law.State All-Union Scientific Research Institute of Roads. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 5–7, July–August, 1993.     

A steady-state model for the rotating biological disc reactor

A steady-state model for substrate removal in a rotating biological disc reactor is presented. The model considers the consumption of substrate by micro-organisms in the biofilm attached to the rotating disc, and mass transfer from the attached liquid film to the biofilm. A mass balance on substrate over the liquid in the trough provides an expression for effluent substrate in terms of the microbial kinetic constants, the geometry of the system and the operating conditions. In order to simplify the solution of the equations in the model, first order kinetics are assumed for the rate of microbial growth and substrate utilization. This simplified model can be solved, for example, by using a programmable calculator. The model predicts that the fractional removal of substrate per stage is strongly dependent on the hydraulic loading rate per unit disc area but independent of feed substrate concentration. It predicts constant removal independent of disc size provided the hydraulic loading per unit area is kept constant. The rotational speed has only a slight predicted effect on the rate of substrate removal. The predictions of the model are compared with published data from the literature for both domestic wastewater and some industrial wastes. Trends observed in the field are predicted qualitatively by the model.     

Betons a hautes performances,a granulats artificiels actifs

High strength concretes, in particular at early ages (more than 40 MPa at 3 days and up to 80 MPa at 7 days), are obtained by replacement of certain granular size ranges of sand or gravel by cement-active artificial aggregates in a given concrete composition elaborated with a local supply of aggregates and cement. The strengthening of the paste-aggregate bond by chemical reactions between the artificial aggregates and the cement also involves an improvement of other concrete performances and not only of mechanical strengths. The cracking ability is decreased, the wear strength is higher, and water permeability is low or even nil for certain compositions. The laboratory results are confirmed by tests on the site and show the possibility of achieving high strength concretes without any particular selection of cement and natural aggregates.     

Indirect check of aggregate pore effects on concrete

It is very difficult to quantify aggregate pores directly in a way that allows pore/water interaction to be accurately related to hardened concrete properties. This work examines, a number of aggregates through water absorption checks and gives results of tests on some concretes made with them. Three especially relevant concrete properties are examined, initial surface absorption, freeze/thaw behaviour and drying shrinkage; it is shown that aggregate absorption is reflected in these properties.     

Tunnelling projects in Southern Africa

Until some thirty years ago tunnelling in southern Africa for civil engineering purposes had been on a relatively small scale and of a sporadic nature. The first major tunnel to be built in the region was the 82 km long Orange-Fish Tunnel. Since 1970 more than 175 tunnels with an aggregate length of just over 400 km have been built. Much of the first phase of the Lesotho Highlands Water Project, which will have more than 100 km of tunnels, is about to be completed. The last thirty years represent the busiest period of tunnelling by civil engineers that southern Africa has ever known. The paper starts by summarising the early history of tunnelling in the region, and goes onto describe recent and current tunnelling projects. It also gives an indication of the possible demand for tunnels in the future.     

Effect of chlorination practice on soluble organics

As the practice of chlorination for the disinfection of waste effluents is apparently to be extended, this study was initiated to examine the possibility that chlorinated organics could be formed in the disinfection process. A group of pure compounds that had been demonstrated to be susceptible to chlorination were examined under conditions likely to apply under normal disinfection practice.From the results obtained, it appears only organics with ring structures and electron activating substituents, or amino groupings are capable of chlorination. The frequent presence of ammonia or amino groups means that chloramine formation with its asociated toxicity is likely. However, the presence of ammonia or amino groups will retard the reaction with other compounds making chlorination of these unlikely.     

Conceptual aspects of water re-use

A simplified model of a municipal water recycle system is presented and gives a clear picture of the relationship between process variables such as the intensity of the treatment, the accumulation of pollutants and the number of times the water is re-used. The model can be used to determine the necessary requirements for the treatment process in order to reach a certain desired drinking water quality. This model is extended to cover a variety of practical conditions. It is also shown that accumulation under practical conditions is limited, even if there is no treatment. The model predicts that the recycle system can utilise a low quality supplementary supply, e.g. brackish water. Although the model is derived for a recycle system for domestic water supply it can be used for any closed loop water system.     

Lead in glasgow street dirt and soul

The levels of lead in city street dirt and in soil from various locations in Glasgow were investigated during spring 1976. Lead concentrations in street dirt ranged from 150–2300 ppm, mean 960 ppm, and were significantly elevated with respect to the observed “natural” level of 78 ppm. Lead derived from anti-knock compounds in petrol and introduced to the environment via automobile exhausts was clearly implicated as the main source of lead pollution in a series of soil lead measurements at the centre and periphery of eight Glasgow parks.Various chemical leaching techniques were employed and compared. Less than 5% of street dirt and soil lead was found to be associated with the organic phase.     

Toxicity, accumulation and elimination studies of α-hexachlorocyclohexane (α-HCH) with freshwater organisms of different trophic levels

A short- and long-term toxicity study with α-hexachlorocyclohexane (α-HCH) was carried out with freshwater organisms of different trophic levels (algae, crustaceae and fishes). In this study mortality, immobilization, growth, reproduction, histopathologic changes and enzyme activities were chosen as criteria.Furthermore accumulation and elimination processes were investigated in separate organisms as well as the uptake of α-HCH by one organism and through a food-chain.Finally a tentative method for deriving an “ecological limit” for χ-HCH in surface water is described.