Rapid pyrolysis of brown coal and oil shale

A brown coal, peat and oil shale were subjected to a rapid pyrolysis process and medium-heat-value gases together with tar were collected. The char residue was of high activity and suitable for gasification to create a two-stage gasification system. The coal-tar is used for manufacturing liquid fuels and chemicals.     

Integrated UV-based photo microreactor-distillation technology toward process intensification of continuous ultra-high-purity electronic-grade silicon tetrachloride manufacture

Ultra-high-purity silicon tetrachloride (SiCl₄) is demanded as an electronic-grade chemical to meet the stringent requirements of the rapidly developing semiconductor industry. The high requirement for ultra-high-purity SiCl₄ has created the need for a high-efficient process for reducing energy consumption as well as satisfying product quality. In this paper, a mass of production technology of ultra-high-purity SiCl₄ was successfully developed through chlorination reaction in the ultraviolet (UV)-based photo microreactor coupled with the distillation process. The influences of key operational parameters, including temperature, pressure, UV wavelength and light intensity on the product quality, especially for hydrogen-containing impurities, were quantified by the infrared transmittance of Fourier transform infrared spectroscopy (FT-IR) at 2185 cm^-1 and 2160 cm^-1 indicating that characteristic vibrational modes of Si—H bonds, as well as the operating conditions of distillation were also investigated as key factors for metal impurities removing. The advanced intensification of SiCl₄ manufactured by the integration of photo microreactor and distillation achieves the products with superior specifications higher than the standard commercial products.     

CAE软件操作小百科（23）

正1 RecurDyn如何在仿真之前检查模型的各种设置是否正确?在动力学分析之前,若要检验样机,可以先进行运动学分析,且在施加作用力之前确定各种约束是否正确.在RecurDyn中,还提供模型预分析功能,在simulation type中有预分析功能(pre analysis),检查模型自由度、是否有冗余约束及其相关信息.2 RecurDyn怎样解决有冗余约束的问题?当模型存在冗余约束时,软件在求解过程中会     

Preparation and catalytic performance of Co3O4 catalysts for low-temperature CO oxidation

Without use of any surfactant or oxidant, a series of Co₃O₄ catalysts have been prepared from cobalt nitrate aqueous solution via a very simple liquid-precipitation method with ammonium acid carbonate followed by calcination at various temperatures. The catalytic performance of the Co₃O₄ for CO oxidation has been studied with a continuous flowing laboratory microreactor system. The results show that the CO conversion of all the samples can reach 100% at ambient temperature. The catalyst calcined at 300 °C is able to maintain its activity for CO complete oxidation more than 500 min at 25 °C and about 240 min even at −78 °C. High reaction temperature results in a high catalytic stability, while the catalytic stability decreases with further increasing the reaction temperature. Characterizations with X-ray powder diffraction and transmission electron microscopy suggest that all the samples exist as a pure Co₃O₄ phase with the spinel structure, the samples are apt to aggregate and the specific surface area gradually decreases with increasing the calcination temperature, which directly leads to the decrease of catalytic stability. Furthermore, the amount of active oxygen species measured by CO titration experiments appears to be critical for catalytic performance.     

Integrated UV-based photo microreactor-distillation technology toward process intensification of continuous ultra-high-purity electronic-grade silicon tetrachloride manufacture

Ultra-high-purity silicon tetrachloride (SiCl₄) is demanded as an electronic-grade chemical to meet the stringent requirements of the rapidly developing semiconductor industry. The high requirement for ultra-high-purity SiCl₄ has created the need for a high-efficient process for reducing energy consumption as well as satisfying product quality. In this paper, a mass of production technology of ultra-high-purity SiCl₄ was successfully developed through chlorination reaction in the ultraviolet (UV)-based photo microreactor coupled with the distillation process. The influences of key operational parameters, including temperature, pressure, UV wavelength and light intensity on the product quality, especially for hydrogen-containing impurities, were quantified by the infrared transmittance of Fourier transform infrared spectroscopy (FT-IR) at 2185 cm⁻¹ and 2160 cm⁻¹ indicating that characteristic vibrational modes of SiH bonds, as well as the operating conditions of distillation were also investigated as key factors for metal impurities removing. The advanced intensification of SiCl₄ manufactured by the integration of photo microreactor and distillation achieves the products with superior specifications higher than the standard commercial products.     

轻质油品氧化脱硫技术进展

介绍了国内外轻质油品氧化脱硫技术的研究进展情况，分析了选择性氧化脱硫、超声波氧化脱硫、光催化氧化脱硫、等离子体液相氧化脱硫等技术的优缺点，展望了氧化脱硫技术应用前景。     

INNOVATIVE APPLICATIONS OF IONIC LIQUIDS AS “GREEN” ENGINEERING LIQUIDS

Over the past decade, ionic liquids (ILs) have become one of the fastest growing “green” media for chemists and engineers due to their superb physicochemical properties. The applications of these remarkable salts in reactions and extraction processes have been extensively investigated and reviewed. This review, however, highlights recent advances of ILs as versatile “green” engineering liquids in a variety of industrial applications including heat transfer fluids, azeotrope-breaking liquids, lubricants, electrolytes, liquid crystals, supported IL membranes, plasticizers, and more. This review is not intended to be comprehensive, but rather to discuss the potentials of ILs for diverse industrial applications.     

软胶囊亮发素的制备

本文介绍了用明胶软胶囊包装的亮发素的配方和制备方法。在亮发素中含有低粘度液体石蜡油、精制橄榄油、精制茶籽油、精制沙棘籽油、棕榈酸异丙酯、肉豆蔻酸异丙酯、油酸乙酯、二甲基聚硅氧烷、维生素Ｅ和油溶性香料等成份。     

单填料函滑动管板式换热器密封结构的设计

自行设计了一台单填料函滑动管板式换热器代替进口设备，运转良好。本文着重介绍该设备密封结构的设计。     

熔体直纺129dtex/144f涤纶细旦POY的生产工艺

介绍了在直接纺丝设备上,通过工艺调整与设备改进,成功开发129dtex/144f涤纶细旦POY的经验。