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101.
102.
A novel mesoporous TiO2 phosphor doped with Eu was synthesized through a facile hydrothermal synthesis method using cetyltrimethylammonium bromide as structure template reagent. The samples were characterized by X-ray diffraction, N2 adsorption-desorption, scanning electron microscope, high-resolution transmission electron microscopy, ultraviolet visible diffuse reflectance, X-ray photoelectron spectroscopy, and three dimensional Photoluminescence. The X-ray diffraction results demonstrated that the products were anatase type with polycrystalline. N2 adsorption-desorption analysis showed that the samples were of high ordered double mesoporous structures. Eu-doped mesoporous TiO2 indicated the typical fluorescent spectra of Eu3+ ion occurred: the excited-states at 5L6 (394 nm), 5D2 (465 nm) and 5D1 (535 nm); the main emission peaks at 592 and 617 nm, corresponding with the transitions 5D0 --> 7F1 and 5D0 --> 7F2, respectively. Meanwhile, the phenomena of Eu(3+)-doped mesoporous TiO2 phosphor with efficient nonradiative energy transfer from the mesoporous TiO2 host to the activator Eu3+ ions was observed and possible emission mechanism was proposed. High dispersion of Eu in mesoporous TiO2 matrix was responsible for enhanced luminescence. 相似文献
103.
Fei Li Heqiu Zhang Lizhong Hu Yingmin Luo Yu Zhao Yu Qiu Jiuyu Ji Lunlun Yue 《Journal of Materials Science: Materials in Electronics》2013,24(12):4812-4816
One-dimensional (1D) ZnO microwires were successfully synthesized by chemical vapor deposition and their structural and morphological properties were analyzed by X-ray diffraction and scanning electron microscopy, demonstrating that the microwires were single crystalline with perfect hexagonal structure and smooth surface. Using these 1D microstructures, we fabricated a novel ZnO-based ethanol gas sensor. Operating at room temperature, the sensor was found to have good sensing characteristics. The reliability and stability of the sensor could be improved by connecting multiple 1-wire devices (1-WD) in parallel into a multi-wires device. In interior natural lighting environment and under 3 V bias, the response and recovery time of the 1-WD to 200 ppm ethanol gas were <10 s and about 300 s, respectively, and the minimum and maximum detection limit were about 2 and 200 ppm, respectively. A sensing model was proposed for discussing the performance of the sensor. The simplicity in fabrication, low power consumption and low cost make the sensor suitable for practical application in many fields, especially in identifying driving under the influence and chemical industry monitoring. 相似文献
104.
电容器故障监测系统的应用研究 总被引:7,自引:3,他引:4
基于近年并联电容器装置频繁出现故障的现象和特点,研制出一套电容器故障监测系统,分别提取并联电容器装置的电流和电压实时信号,利用Labview虚拟仪器程序进行软件开发实现在线监测,对获取的电流电压信号进行谐波、合闸涌流、暂态过电压等方面进行分析和研究,并应用于现场测量,给出了一起电容器内部击穿故障的监测实例。 相似文献
105.
106.
上海历史文化风貌区的分类比较与保护规划的应对 总被引:1,自引:0,他引:1
2003年,上海市划定了中心城12个历史文化风貌区,它融合了上海城市发展过程中各个时代的鲜明风格,体现了近代上海在社会经济、文化、生活各方面的成就和发展轨迹.由于上海这样的大都市的历史风貌复杂、多样,每个风貌区所面临的问题也不尽相同,因此保护规划在统一的规划框架下,必须有不同的变化和侧重.分类比较的目的就是为了进一步归纳总结,完善保护规划体系,使风貌区保护规划编制方法更加易于推广. 相似文献
107.
Fe2O3由于成本低廉,储量丰富和理论比容量高(1007 mA hg^-1)等特点,在锂离子电池负极材料的应用中极具发展前景.然而一些问题仍然存在,如:充放电过程中比容量的迅速衰减,不可逆的体积膨胀以及较短的循环寿命等.这些问题严重制约了Fe2O3在锂离子电池中的实际应用.为了突破这些局限,本文以金属-有机骨架(MOF... 相似文献
108.
Cong Ge Xuebin Xu Fei Ma Jianmin Zhou Changwen Du 《International journal of molecular sciences》2022,23(13)
Benefitting from the special structure of the leaf cuticle layer, plants have natural hydrophobicity and anti-fouling abilities. Inspired by the leaf surface structure, a biomimetic modification strategy was raised to improve the surface hydrophobicity of polyacrylate coating for controlled release fertilizer. Double-layer (polyacrylate and carnauba wax) coated fertilizer was obtained after biomimetic modification. The quality of controlled release fertilizer modified with the carnauba wax was greatly enhanced, and the coating material was effectively saved. The surface appearance of polyacrylate-coated fertilizer was improved for the surface blemish was repaired by the loaded carnauba wax. The characterizations by Fourier transform infrared spectroscopy indicated that the hydrogen bonds were formed between the water-based polyacrylate membrane and the carnauba wax layers. By optimizing the content of polyacrylate and carnauba wax, the release duration of the fertilizer was effectively prolonged, which was improved from 1 month to more than 2 months after the biomimetic modification. Therefore, biological wax as an environmentally-friendly natural material that has showed a broad potential in the application of coated controlled release fertilizer. 相似文献
109.
Yunhua Yang Adhimoolam Karthikeyan Jinlong Yin Tongtong Jin Rui Ren Fei Fang Han Cai Mengzhuo Liu Dagang Wang Kai Li Haijian Zhi 《International journal of molecular sciences》2022,23(13)
E3-ubiquitin ligases are known to confer abiotic stress responses in plants. In the present study, GmPUB21, a novel U-box E3-ubiquitin ligase-encoding gene, was isolated from soybean and functionally characterized. The expression of GmPUB21, which possesses E3-ubiquitin ligase activity, was found to be significantly up-regulated by drought, salinity, and ABA treatments. The fusion protein GmPUB21-GFP was localized in the cytoplasm, nucleus, and plasma membrane. Transgenic lines of the Nicotiana benthamiana over-expressing GmPUB21 showed more sensitive to osmotic, salinity stress and ABA in seed germination and inhibited mannitol/NaCl-mediated stomatal closure. Moreover, higher reactive oxygen species accumulation was observed in GmPUB21 overexpressing plants after drought and salinity treatment than in wild-type (WT) plants. Contrarily, silencing of GmPUB21 in soybean plants significantly enhanced the tolerance to drought and salinity stresses. Collectively, our results revealed that GmPUB21 negatively regulates the drought and salinity tolerance by increasing the stomatal density and aperture via the ABA signaling pathway. These findings improved our understanding of the role of GmPUB21 under drought and salinity stresses in soybean. 相似文献
110.
Cold plate is an important component for a liquid battery thermal management system.In order to study the transient thermal performance of the cold plate under ... 相似文献