Influence of the edge rounding process on the behaviour of blanked parts: numerical predictions with experimental correlation

Blanking of sheet metal is an important forming process in the automotive industry for the manufacture of mechanical components. The final component shape, obtained at the end of bending or deep-drawing processes, often has sharp edges due to the blanking operation. Concerning passenger safety components, like seat belt anchors, rounding of the edges by punching is necessary to avoid cutting the belt material. In addition to removing the sharp edges, the punching results in work hardening of the material in the rounded zones which results in an increase in the local resistance of the material. In this study, a high-strength low-alloy steel (HSLA S500MC) has been tested with the aim of quantifying the blanking and edge rounding operations. The mechanical behaviour of test specimens is investigated by means of tensile tests and the material is characterised in terms of Vickers micro-hardness. Numerical simulations of the edge rounding process are developed using previously identified material behaviour laws. The residual stress fields are characterised and compared to experimental results. This is done so that numerical simulation can be done in the future to prediction the in-service behaviour of the component. Specimens with rounded edges are compared to specimens that were not submitted to the rounding operation. It is shown that Edge Rounding by Punching improves the component resistance, therefore justifying the use of this process in the manufacture of automotive safety components.     

Rheological and high gelling properties of mango (Mangifera indica) and ambarella (Spondias cytherea) peel pectins

Ambarella and mango peels are good sources of pectins (15–20%), with high degree of methylation (60–78%) and high molar masses. Ambarella and mango ( Améliorée and Mango varieties) peel pectins were extracted using HCl or oxalic acid/ammonium oxalate (OAAO). Purified pectins were analysed for their flow behaviour and phase diagrams were established at pH 3 as sucrose vs. pectin concentration. The gelation kinetics and mechanical spectra of these pectin gels were studied and compared to those of commercial citrus (lime) pectins. At a concentration of 1% (w/v), all pectic solutions had a shear thinning behaviour but at 0.6% (w/v), only OAAO-extracted pectins exhibited such behaviour. Phase diagrams showed that at pH 3, gelation of OAAO mango extracted pectins was possible at low polymer concentration (0.2%; w/w) for a sucrose concentration of 60% (w/w). OAAO-extracted pectins exhibited a higher gelling ability than HCl-extracted ones. Sucrose (45–50%) and pectin (0.2–0.6%) concentration had a deep impact on the gel strength. Our results enable to conclude that the OAAO extraction from mango and ambarella peels allowed the recovery of pectins that exhibit high gelling properties.     

Chemical reactors of special geometry for the precipitation of mineral particles

Precipitation of pseudo‐boehmite particles is experimentally investigated. The experiments have been carried out in three chemical reactors specially designed to achieve an effective control of the properties of mineral particles produced by precipitation. The chemical reactors are the Sliding‐Surface Mixing Device, the Special Rushton Turbine Reactor and the Vortex Effect Reactor. The mixing efficiency of these new mixing devices is experimentally evaluated and the influence of reactor geometries, operating parameters and initial supersaturation on pseudo‐boehmite particle properties is studied. The particle properties evaluated are particle size distribution, crystallite size, BET surface area, porous volume, mean pore radius and particle shape. A comparison of the particle properties obtained with the three reactors is made.     

Biomass effects on oxygen transfer in membrane bioreactors

Ten biomass samples from both municipal and industrial pilot and full scale submerged membrane bioreactors (MBRs) with mixed liquor suspended solids concentrations (MLSS) ranging from 7.2 to 30.2g L(-1) were studied at six air-flow rates (0.7, 1.3, 2.3, 3, 4.4 and 6m(3)m(-3)h(-1)). Statistical analyses were applied to identify the relative impacts of the various bulk biomass characteristics on oxygen transfer. Of the biomass characteristics studied, only solids concentration (correlated with viscosity), the carbohydrate fraction of the EPS (EPS(c)) and the chemical oxygen demand (COD) concentration of the SMP (SMP(COD)) were found to affect the oxygen transfer parameters k(L)a(20) (the oxygen transfer coefficient) and alpha-factor. The relative influence on k(L)a(20) was MLSS>aeration>EPS(c)>SMP(COD) and on alpha-factor was MLSS>SMP(COD)>EPS(c)>aeration. Both k(L)a(20) and alpha-factor increased with increasing aeration and EPS(c) and decreased with increasing MLSS and SMP(COD). MLSS was found to be the main parameter controlling the oxygen transfer.     

Visual Disfunction due to the Selective Effect of Glutamate Agonists on Retinal Cells

One of the causes of nervous system degeneration is an excess of glutamate released upon several diseases. Glutamate analogs, like N-methyl-DL-aspartate (NMDA) and kainic acid (KA), have been shown to induce experimental retinal neurotoxicity. Previous results have shown that NMDA/KA neurotoxicity induces significant changes in the full field electroretinogram response, a thinning on the inner retinal layers, and retinal ganglion cell death. However, not all types of retinal neurons experience the same degree of injury in response to the excitotoxic stimulus. The goal of the present work is to address the effect of intraocular injection of different doses of NMDA/KA on the structure and function of several types of retinal cells and their functionality. To globally analyze the effect of glutamate receptor activation in the retina after the intraocular injection of excitotoxic agents, a combination of histological, electrophysiological, and functional tools has been employed to assess the changes in the retinal structure and function. Retinal excitotoxicity caused by the intraocular injection of a mixture of NMDA/KA causes a harmful effect characterized by a great loss of bipolar, amacrine, and retinal ganglion cells, as well as the degeneration of the inner retina. This process leads to a loss of retinal cell functionality characterized by an impairment of light sensitivity and visual acuity, with a strong effect on the retinal OFF pathway. The structural and functional injury suffered by the retina suggests the importance of the glutamate receptors expressed by different types of retinal cells. The effect of glutamate agonists on the OFF pathway represents one of the main findings of the study, as the evaluation of the retinal lesions caused by excitotoxicity could be specifically explored using tests that evaluate the OFF pathway.     

Numerical study of NOx formation during incineration of cellulosic and plastic materials: The combustion regime

A numerical model has been developed (Chemkin) to study combustion processes in a fixed-bed reactor. The test section is divided into several successive Perfect Stirred Reactor (PSR). At the entry, the thermal degradation species of the solid are used as input and at the exit the exhaust gases are recovered. Comparison of previously experimental results and the current model output has been compared with good agreement. The model has been used to establish the reaction pathways at different locations in the reactor. This has allowed defining what is occurring at each specific location of the reactor. A sensitivity study has been conducted varying the different operating parameters. The reaction pathways and sensitivity study have shown that the production of NO is controlled mostly by local oxygen concentration, thus the location of the NO production region depends mostly on the primary air injection. Temperature can have a significant effect on the global NO output, but only if enough oxygen is available for the reactions to proceed. Reduction reactions appear almost insensitive to temperature.     

Defect Control for 12.5% Efficiency Cu2ZnSnSe4 Kesterite Thin-Film Solar Cells by Engineering of Local Chemical Environment

Kesterite-based Cu₂ZnSn(S,Se)₄ semiconductors are emerging as promising materials for low-cost, environment-benign, and high-efficiency thin-film photovoltaics. However, the current state-of-the-art Cu₂ZnSn(S,Se)₄ devices suffer from cation-disordering defects and defect clusters, which generally result in severe potential fluctuation, low minority carrier lifetime, and ultimately unsatisfactory performance. Herein, critical growth conditions are reported for obtaining high-quality Cu₂ZnSnSe₄ absorber layers with the formation of detrimental intrinsic defects largely suppressed. By controlling the oxidation states of cations and modifying the local chemical composition, the local chemical environment is essentially modified during the synthesis of kesterite phase, thereby effectively suppressing detrimental intrinsic defects and activating desirable shallow acceptor Cu vacancies. Consequently, a confirmed 12.5% efficiency is demonstrated with a high V_OC of 491 mV, which is the new record efficiency of pure-selenide Cu₂ZnSnSe₄ cells with lowest V_OC deficit in the kesterite family by E_g/q-Voc. These encouraging results demonstrate an essential route to overcome the long-standing challenge of defect control in kesterite semiconductors, which may also be generally applicable to other multinary compound semiconductors.