Effect of micro-alloying chromium on the corrosion resistance of nanocrystalline nickel aluminide intermetallic produced by mechanical alloying process

In this study, Ni₅₀Al_50 − xCr_x nanocrystalline intermetallic compound was synthesized by using the high energy mechanical milling of pure Ni, Al and Cr elemental powders for 16 h. The morphological investigation was done by using the optical and scanning electron microscope. The corrosion behavior of the samples was studied by using the electrochemical impedance spectroscopy in 3.5% NaCl solution. The results showed that when the micro-alloying Cr content is increased, the particles distribution is modified and the size of particles is decreased. Therefore the passive film which is formed on the surface of samples is less porous, so the corrosion resistance is increased.     

Generating capacity adequacy evaluation of large-scale,grid-connected photovoltaic systems

Large-scale, grid-connected photovoltaic systems have become an essential part of modern electric power distribution systems. In this paper, a novel approach based on the Markov method has been proposed to investigate the effects of large-scale, grid-connected photovoltaic systems on the reliability of bulk power systems. The proposed method serves as an applicable tool to estimate performance (e.g., energy yield and capacity) as well as reliability indices. The Markov method framework has been incorporated with the multi-state models to develop energy states of the photovoltaic systems in order to quantify the effects of the photovoltaic systems on the power system adequacy. Such analysis assists planners to make adequate decisions based on the economical expectations as well as to ensure the recovery of the investment costs over time. The failure states of the components of photovoltaic systems have been considered to evaluate the sensitivity analysis and the adequacy indices including loss of load expectation, and expected energy not supplied. Moreover, the impacts of transitions between failures on the reliability calculations as well as on the long- term operation of the photovoltaic systems have been illustrated. Simulation results on the Roy Billinton test system has been shown to illustrate the procedure of the proposed frame work and evaluate the reliability benefits of using large-scale, grid-connected photovoltaic system on the bulk electric power systems. The proposed method can be easily extended to estimate the operating and maintenance costs for the financial planning of the photovoltaic system projects.     

Ammonia-free chemical bath deposition of nanocrystalline ZnS thin film buffer layer for solar cells

In this work, we prepared zinc sulfide thin films on glass substrates by ammonia-free chemical bath deposition method using thioacetamide as the sulfide source and Ethylene Diamine Tetra Acetic Acid disodium salt as the complexing agent in a solution of pH = 6.0. Thin films of ZnS with different thicknesses of 18–450 nm were prepared. The effect of film thickness and annealing temperature in atmospheric air, on optical properties, band gap energy and grain size of nanocrystals were studied. The X-ray diffraction analysis showed a cubic zinc blend structure and a diameter of about 2–5 nm for ZnS nanocrystals. The Fourier Transform Infrared spectrum of films revealed no peaks due to impurities. The as-deposited ZnS films had more than 70% transmittance in the visible region. The direct band gap of as-deposited films ranged from 3.68 to 3.78 eV and those of annealed films varied from 3.60 to 3.70 eV.     

Bones Morphogenic Protein‐4 and retinoic acid combined treatment comparative analysis for in vitro differentiation potential of murine mesenchymal stem cells derived from bone marrow and adipose tissue into germ cells

Nowadays, infertility is no longer considered as an unsolvable disorder due to progresses in germ cells derived from stem lineage with diverse origins. Technical and ethical challenges push researchers to investigate various tissue sources to approach more efficient gametes. The purpose of the current study is to investigate the efficacy of a combined medium, retinoic acid (RA) together with Bone Morphogenic Protein‐4 (BMP4), on differentiation of Bone Marrow Mesenchymal Stem Cells (BMMSCs) and adipose‐derived mesenchymal stem cells (ADMSCs) into germ cells. Murine MSCs were obtained from both Bone Marrow (BM) and Adipose Tissue (AT) samples and were analyzed for surface markers to get further verification of their nature. BMMSCs and ADMSCs were induced into osteogenic and adipogenic lineage cells respectively, to examine their multipotency. They were finally differentiated into germ cells using media enriched with BMP4 for 4 days followed by addition of RA for 7 days (11 days in total). Analyzing of differentiation potential of BMMSCs‐ and ADMSCs were performed via Immunofluorescence, Flowcytometry and Real time‐PCR techniques for germ cell‐specific markers (Mvh, Dazl, Stra8 and Scp3). Mesenchymal surface markers (CD90 and CD44) were expressed on both BMMSCs and ADMSCs, while endothelial and hematopoietic cell markers (CD31 and CD45) had no expression. Finally, all germ‐specific markers were expressed in both BM and AT. Although germ cells differentiated from ADMSCs showed faster growth and proliferation as well as easy collection, they significantly expressed germ‐specific markers lower than BMMSCs. This suggests stronger differentiation potential of murine BMMSCs than ADMSCs.     

Scattering by a magnetized plasma-coated topological insulator cylinder

In the present paper, the scattering characteristics of a magnetized plasma-coated topological insulator cylinder are formulated and analysed graphically. Field equations at each interface are expanded in terms of cylindrical wave vector functions by imposing extended classical wave-scattering theory. By applying the boundary conditions, scattering matrices are obtained in terms of scattered and transmitted coefficients. The obtained results are also compared with published results to display the accuracy of the present formulation under some special conditions. Changes in the bistatic echo widths of the topological insulator cylinder are also recorded by varying the anisotropic plasma parameters (i.e., the applied magnetic field, plasma density and effective collisional frequency).     

Green waste to biogas: Renewable energy possibilities for Thailand's green markets

Today, the production of energy from waste is not a new process; however, its implementation and application continue to be a challenge in developing countries. Despite the abundance of valuable waste in the urban markets of these countries, practices aiming at renewable energy generation are missing. In Thailand, so-called green markets are replete with renewable energy potential, but the practical implementation of this potential is rare. Therefore, the main purpose of this study is to show that the conversion of green waste into renewable energy is not only environmentally beneficial but also financially rewarding. This is demonstrated by exploring the energy potential of the market and conducting a benefit–cost analysis under two scenarios. The results illustrate that for the selected market, converting organic waste into biogas is advantageous both environmentally as well as financially; further, the benefit–cost ratio is three times higher after conversion, compared to before. Additionally, there is a huge margin of conversion and production of biogas. The policy makers and planners of Talaad Thai (Thailand's largest green market) should invest greater effort in initiating plans, and set an example for other markets in Thailand, in order to make this planet clean and green.     

Aliphatic polyamidoamine hyperbranched polymers/layered silicate nanocomposites

Polyamidoamine hyperbranched polymer (Hyp)/clay nanocomposites were synthesized by using both of montmorillonite and laponite clays. Poly amidoamine hyperbranched polymer (Hyp) was prepared by one‐pot polymerization via couple monomer methodology. Afterward, the amino ends of Hyp were modified with methyl methacrylate (MMA), styrene (St) and butyl methacrylate (n‐BuMA) polymers which were previously prepared via ATRP (atom transfer radical polymerization) to form the corresponding new hyperbranched polymers Hyp₁, Hyp₂ and Hyp₃. Those formed polymers were inserted into the modified clay, such as montmorillonite and laponite to form their nanocomposites. The formed polymer/clay nanocomposites were characterized via XRD, TEM, and thermal analyses. The formed hyperbranched polymers generally showed intercalation behavior more than the exfoliation one mostly because of the bulkiness of the hyperbranched skeleton. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

A study on natural aging behavior and mechanical properties of friction stir-welded AA6061-T6 plates

Mechanical properties, microstructural events, residual stresses, and aging behavior of friction stir-welded AA6061-T6 were investigated in this work. Microstructural and mechanical characterizations of the friction stir-welded joints in as-welded and post-welded conditions were made by means of optical metallography, transmission electron microscopy, X-ray diffraction for determination of residual stresses, tensile testing, and hardness measurements. It was found that weld strength and hardness variations after welding are mainly dependent on the imposed heat input per unit length. Besides, the kinetics of natural aging in the welded samples was found to be noticeable within the first 14 days, and its effect decreases considerably in longer aging durations. The residual stress measurements show that subsequent natural aging leads to considerable relaxation of residual stress of about 22 MPa, while this effect is particularly significant in the stir zone and the thermomechanically affected zone.     

Metal/Polymer Based Stretchable Antenna for Constant Frequency Far‐Field Communication in Wearable Electronics

Body integrated wearable electronics can be used for advanced health monitoring, security, and wellness. Due to the complex, asymmetric surface of human body and atypical motion such as stretching in elbow, finger joints, wrist, knee, ankle, etc. electronics integrated to body need to be physically flexible, conforming, and stretchable. In that context, state‐of‐the‐art electronics are unusable due to their bulky, rigid, and brittle framework. Therefore, it is critical to develop stretchable electronics which can physically stretch to absorb the strain associated with body movements. While research in stretchable electronics has started to gain momentum, a stretchable antenna which can perform far‐field communications and can operate at constant frequency, such that physical shape modulation will not compromise its functionality, is yet to be realized. Here, a stretchable antenna is shown, using a low‐cost metal (copper) on flexible polymeric platform, which functions at constant frequency of 2.45 GHz, for far‐field applications. While mounted on a stretchable fabric worn by a human subject, the fabricated antenna communicated at a distance of 80 m with 1.25 mW transmitted power. This work shows an integration strategy from compact antenna design to its practical experimentation for enhanced data communication capability in future generation wearable electronics.