Untersuchungen an chemischen Konservierungsmitteln II. Mitteilung Verfahren zur Bestimmung der antimikrobiellen Wirksamkeit von chemischen Konservierungsmitteln

Zusammenfassung Untersuchungen über den Einfluß unterschwelliger, d. h. die Zellvermehrung zwar hemmender, jedoch nicht völlig verhindernder Konservierungs-mittelkonzentrationen auf die Vermehrung von Hefe haben gezeigt, daß der Verlauf von Wachs tumskurven in enger Beziehung zur angewandten Konservierungsmitteldosis steht. Ebenso besteht ein enger Zusammenhang zwischen der angewandten Konservierungs-mittelkonzentration und der schließlich erreichten Endzelldichte. Diese Beobachtungen führten zur Entwicklung verhältnismäßig einfacher Verfahren zur Konservierungs-mittelbewertung, die in der vorliegenden Arbeit beschrieben werden. Ebenso werden Beispiele für ihre praktische Anwendung gegeben.Wir danken der Deutschen Forschungsgemeinschaft für ihre Unterstützung der vorliegenden Arbeit. — An dieser Stelle sei auch FrauH. Egger unser herzlicher Dank für ihre fleißige Mitarbeit bei der Durchführung der Versuche, ausgesprochen.     

LL(k)-PARSING OF COUPLED-CONTEXT-FREE GRAMMARS

Coupled-context-free grammars are a natural generalization of context-free grammars obtained by combining nonterminals to corresponding parentheses which can only be substituted simultaneously. Refering to the generative capacity of the grammars we obtain an infinite hierarchy of languages that comprises the context-free languages as the first and all the languages generated by TAGs as the second element. Here, we present a generalization of the context-free LL(k) -notion onto coupled-context-free grammars, which leads to a characterization of subclasses of coupled-context-free grammars–and in this way of TAGs as well–which can be parsed in linear time. The parsing procedure described works incrementally so that it can be used for on-line parsing of natural language. Examples show that important elements of the tree-adjoining languages can be generated by LL(k )-coupled-context-free grammars.     

Poly(L‐lysine)/microcrystalline cellulose biocomposites for porous scaffolds

The need for tissue engineered scaffolds is growing due to a shortage in organ donation, potential immunoreactions to allotransplants, and high cost associated with transplantation. The main focus of this research is concerned with material selection and processing which are key for a successful design of any tissue engineered structure. This work investigates the possibility of reinforcing a weak polypeptide [poly(L ‐lysine)] with a stronger polysaccharide (cellulose) and processing the resulting composite into a porous structure. As the main processing parameters, the effect of pH on the secondary structure of the polypeptide and the effect of the hydrolysis conditions on the properties of commercially available microcrystalline cellulose (MCC) were studied. The significance of the cellulose content as well as the scaffold fabrication conditions on the properties of the composite system was assessed. Overall, PLL/MCC composites showed a lower crystallinity compared to the PLL alone while further hydrolyzed MCC particles (HMCC) showed surface erosion and resulted in a crystallinity increase when incorporated into a composite structure. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers     

Nanoarchitecturing of Activated Carbon: Facile Strategy for Chemical Functionalization of the Surface of Activated Carbon

Nanoarchitecturing of carbon nanospheres onto the surface of activated carbon (AC) gives birth to a new composite carbon material that features a hierarchical structure with macro‐ and nanometer dimensions of the respective carbon components and exhibits a remarkably enhanced adsorption capability for heavy‐metal ions ( and Fe³⁺) from aqueous solution as compared to AC. Thus, we first propose that nanoarchitecturing of AC can be utilized not only as a flexible method for the synthesis of novel, hybrid, nanostructured composite carbon materials but also as a new and “green‐route” strategy for functionalization of the surface of AC in an effective manner. Hence, there is scope for a possible new concept in the functionalization of industrial AC for specific applications.     

In vitro and in vivo inhibition of Hass avocado polyphenol oxidase enzymatic browning by paeonol, β-cyclodextrin,and paeonol:β-cyclodextrin inclusion complex

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CO2 savings of ground source heat pump systems – A regional analysis

In the current study the savings of CO₂ emissions due to the use of ground source heat pump (GSHP) systems was investigated in comparison to conventional heating systems. Based on a subsidy program for GSHP systems in southwest Germany, the regional, average, and total CO₂ savings of 1105 installed GSHP systems were determined on a regional scale. The emitted CO₂ per kWh of heating demand for the studied scenario resulted in 149 g CO₂/kWh for GSHP using the German electricity mix and 65 g CO₂/kWh using the regional electricity mix, which results in CO₂ savings of 35% or 72%, respectively. Similar CO₂ avoidances of GSHP systems were found in American and European studies ranging between 15% and 77% strongly depending on the supplied energy for the heat pumps and the efficiency of installation. The resulting CO₂ savings for one installed GSHP unit in the present study therefore range between 1800 and 4000 kg per year. Nevertheless, the minimum average total annual CO₂ savings of all installed GSHP systems due to the subsidy program amounted to 2000 tons per year. The maximum regional avoided additional CO₂ emissions are primarily associated with the affluent suburbs of the most densely populated area in the region. In 2006 the total contribution of CO₂ savings due to GSHP systems in Germany was only about 3.4% of the total renewable energies. However, continuously rising numbers of installed GSHP units and the increasing use of renewable electricity demonstrate that there is a fine opportunity to substantially avoid additional CO₂ emissions associated with the provision of heating (and cooling) of buildings and other facilities.     

Chemical composition and nutritive value of peach palm (Bactris gasipaes Kunth) in rats

The peach palm (Bactris gasipaes Kunth) is the starchy fruit of a palm tree widely cultivated in Central and South America. The present study aimed at determining its chemical composition and its nutritive value in rats. The average chemical composition of 17 samples was as follows: 410 g kg^?1 water and, in g kg^?1 of dry matter (DM), 54 g crude protein, 114 g oil, 39 g neutral detergent fibre, 716 g starch, 21 g sugars and 18 g ash. The main variability was observed for the oil (60–180 g kg^?1 DM) and starch (590–780 g DM) contents. The proteins contained, on average, in g kg^?1 of proteins, 49 g lysine, 13 g methionine, 19 g cysteine, 39 g threonine and 7 g tryptophan. The mineral fraction contained, per kg DM: 1.0 g Ca, 0.8 g P, 0.6 g Mg, 0.3 g Na, 44 mg Fe, 4 mg Cu and 10 mg Zn. The digestibility of four peach palm genotypes was determined in rats fed a diet composed of 350 g kg^?1 of peach palm and 650 g of a control diet based on maize and soybean meal. The digestibility of DM, energy, starch and protein of peach palm alone reached, on average 91, 87, 96 and 95%, respectively. No difference was observed between varieties, except for starch (p < 0.05). On average, peach palm contained 51 g of truly digestible protein kg^?1 DM and 3.691 kcal digestible energy kg^?1 DM. A growth trial was also carried out for 1 month on rats (initial weight: 78 g) fed a diet containing 0, 200, 400, 600 or 800 g peach palm kg^?1, at the expense of a diet composed of maize starch and casein. The growth rate of the rats decreased (p < 0.05) as the peach palm concentration increased. The growth decrease was due to a decrease (p < 0.05) in DM intake and to the lower quality of the peach palm protein. It is concluded that peach palm is mainly an energy source for humans and animals. It is poor in protein and minerals but can be consumed in large amounts. Copyright © 2005 Society of Chemical Industry     

Physicochemical Characterization of a Heat Treated Calcium Alginate Dry Film Prepared with Chicken Stock

Solid sodium alginate was dissolved into chicken stock in order to give a final alginate concentration of 0.9 percent (w/v). Calcium ions present in chicken stock were enough to induce ionic gelation. After drying, Fourier transform infrared spectroscopy, thickness and mechanical properties of films obtained were determined. Calcium alginate‐chicken stock films were heated at 130 °C for different times between 0 and 15 min. Mechanical and optical studies, differential scanning calorimetry, visual aspect and scanning electron microscopy were carried out to describe physicochemical properties of heat treated films. Heating developed a maroon ochre color and increased the brittleness (crispness) of the films related to the intensity of the treatment. Differential scanning thermometry and study on appearance of the films suggested that Maillard reactions may be responsible for the observed changes. Maillard reactions mainly occurred between reducing sugar monomers and free amino groups of gelatin peptides present in the chicken stock, and between alginate and gelatin peptides to a lesser extent. In addition, the plasticizing effect of fat added with chicken stock was also studied. These studies suggest a potential use of heat treated chicken stock films as a substitute of roasted chicken skin.