Crosslinked poly(vinyl alcohol) membrane as separator for domestic wastewater fed dual chambered microbial fuel cells

The use of Nafion as a proton exchange membrane in microbial fuel cells (MFCs) is expensive with operational issues like biofouling and fuel crossover limiting the practical application of the device to harvest energy from wastewaters. In this connection, a facile route is adapted to fabricate a Nafion-alternative membrane using poly(vinyl alcohol) (PVA) crosslinked with glutaraldehyde (GA) as a relatively low-cost, effective membrane for MFCs. The crosslinking of the PVA membrane resulted in a reduction in hydroxyl groups and the formation of the acetal ring and ether linkage demonstrated by controlled water uptake and swelling ratio with enhanced thermo-mechanical stability. The crosslinked membrane displayed higher power density than those typically reported for domestic wastewater fed MFCs, reaching a maximum of 158.28 mW/m² for the fabricated membrane. The PVA-GA membrane with antimicrobial activity, high power performance, and negligible fuel crossover shows its potential as a separator in future MFCs based on its performance and low cost of installation.     

Biohydrogen synthesis from catalytic steam gasification of furniture waste using nickel catalysts supported on modified CeO2

Present study evaluated the catalytic steam gasification of furniture waste to enhance the biohydrogen production. To do this, 10 wt% nickel loaded catalysts on the variety of supports (Al₂O₃, CeO₂, CeO₂-La₂O₃, and CeO₂–ZrO₂) were prepared by the novel solvent deficient method. The hydrogen selectivity (vol%) order of the catalysts was achieved as Ni/CeO₂–ZrO₂>Ni/CeO₂>Ni/Al₂O₃?Ni/CeO₂-La₂O₃. The best catalytic activity of Ni/CeO₂–ZrO₂ catalyst (~82 vol % H₂ at 800 °C) was ascribed to the smaller size of nickel crystals, finely dispersed Ni on the catalyst surface, and Ce_1-xZr_xO_2-δ solid solution. The role of Ce_1-xZr_xO_2-δ solid solution in Ni/CeO₂–ZrO₂ catalyst was observed as bi-functional; acceleration of water-gas-shift and oxidation of carbon reaction. The high resistance of Ni/CeO₂–ZrO₂ towards the coke formation showed its potential to establish a cost-effective commercial-scale biomass steam gasification process. This study is expected to provide a promising solution for the disposal of furniture wastes for production of clean energy (biohydrogen).     

Catalyst design for maximizing C5+ yields during Fischer-Tropsch synthesis

Fischer-Tropsch (FT) process has great potential to accomplish energy security but also for utilizing greenhouse gases to address the energy problem. Different kinds of feedstocks like coal, biomass (via gasification), CO₂, methane (via reforming), and nonconventional energy sources are used to obtain the syn-gas (CO and H₂). The formation of hydrocarbons in the FT process follows ASF distribution over the majority of the catalysts. It can be overcome by the application of a suitable catalyst, controlling the active metal interaction with the support and interaction of formed hydrocarbon with the support. The ratio of syn-gas is important to maintain the desired conversion and to have more selectivity towards C₅+ products. Increase in the H₂: CO ratios in the feed increases C₅+ products and methane decreases. Whereas with the decrease in the ratios increases undesirable reactions and methane formation. In this article, we have discussed the recent literature from the viewpoint of increasing the C₅+ selectivity. Support has a profound influence on product distribution. With the application of suitable support and controlling the interaction of the active sites yields the good CO conversion with fewer lighters and higher C₅+ hydrocarbons.     

Effects of Cattaneo–Christov heat flux analysis on heat and mass transport of Casson nanoliquid past an accelerating penetrable plate with thermal radiation and Soret–Dufour mechanism

In this analysis, the effect of Catteneo–Christov model on heat alongside mass transport magnetohydrodynamics of a Casson nanoliquid with thermal radiation and Soret–Dufour mechanism is considered. The fluid flow is considered through porous media as the thermophysical attributes such as viscosity along with thermal conductivity are considered to be constant. Suitable similarity transformations were employed on the governing coupled flow equation to yield total differential equations (ODE). An accurate and newly developed spectral method called spectral homotopy analysis method (SHAM) was employed to provide solution to the simplified equations. The numerical method of homotopy analysis method (HAM) is SHAM. SHAM portrays the division of nonlinear equations into linear as well as nonlinear parts. The findings in this study show that an increment in the Casson parameter is seen to elevate the velocity plot at the wall and lessen the velocity far away from the plate. An increase in the Brownian motion and thermophoresis term is observed to speed up the local skin friction coefficient.     

Modelling and investigation of clean power wind energy systems by using UPQC

This article presents a new clean power technique for wind energy system based on Unified Power Quality Conditioner (UPQC) with usage of various Artificial Intelligent techniques (AI). Application of AI techniques such as Artificial Neural Networks, Fuzzy Logic is growing fast in the area of power electronics equipment‐based wind energy system, for instance, UPQC. A novel control scheme is developed by using different AI techniques to mitigate the balancing issues and to control the power–quality problems in UPQC and hence to provide clean power to the grid. The proposed system is composed of shunt active power filter, and the inherent proportional integral (PI) control parameters are tuned with application of PI techniques. A detailed Matlab simulation study is carried out with an application of PI techniques under sag, swell, unbalanced, and harmonic conditions. An exhaustive simulation study is carried out to investigate the application of PI technique‐based controllers and compare its performance with the conventional PI controller with its results explored. Copyright © 2016 John Wiley & Sons, Ltd.     

Numerical Investigations on the Advantage of Nanofluids under DDMC in a Lid‐Driven Cavity

Double diffusive mixed convection in a lid‐driven cavity filled with Cu–water nanofluid is studied in detail. Various numerical experiments are conducted under horizontal thermal and concentration gradients. Flow equations were solved in velocity vorticity form using Galerkin's weighted residual finite element method. The Maxwell‐Garnett model and Brinkman models are applied to predict the thermal conductivity and dynamic viscosity of the nanofluid, respectively. The effectiveness of a nanofluid on heat transfer enhancement with respect to change in Richardson number has been studied at different Reynolds numbers for variation in particle volume fraction from 0 to 0.05. Similarly, the effect of buoyancy ratio on heat and mass transfer is presented for buoyancy ratio in the range of ?25 to 25. Detailed contour plots comparing the streamlines, temperature, concentration with and without nanoparticles were presented for all the range of parameters considered. The role of particle concentration and change in type of nanofluid has been reported. The average Nusselt number has increased in all the cases where as the Sherwood number slightly decreased with an increase in particle volume fraction. The Ag–water nanofluid showed better improvement in heat transfer characteristics compared to other nanofluids for all Reynolds numbers and particle volume fractions.     

Thermodynamic evaluations of solar cooling cogeneration cycle using NaSCN–NH<Subscript>3</Subscript> mixture

The commercial refrigeration and air conditioning consumes more electric power for its operation. The solar vapor absorption refrigeration helps to minimize the electric power usage and it is renewable. Large size of solar collector area is required for producing the standalone power as well as cooling cycle. The integration of power and cooling cycle minimizes the number of components such as heat exchanger, separator and collector area. The main objective of the work is to integrate power and cooling for two outputs with single cycle using NaSCN–NH₃ as working fluid. The advantages of NaSCN–NH₃ are having high pressure and pure ammonia vapor at the exit of the generator. The integrated cycle is made by providing the turbine at the exit of the generator along with superheater. It has three pressures of generator, condensing and sink pressure, which is depending on separator and ambient temperature. At the separator temperature of 150°C with weak solution concentration of 0.30, it produces the cogeneration output of 284.80 kW with cycle and plant thermal efficiency of 0.49 and 0.20 respectively.     

Experimental studies on solar flat plate collector with internally grooved tubes using aqueous ethylene glycol

In order to cope up with the increase in energy demand and decline in fossil fuels, it has become imperative to use renewable resources efficiently. Among these renewable resources, solar thermal energy is abundant in nature. Solar water heating systems are one of the most important applications of solar thermal energy. Providing internal fins to absorber tube is the technique to improve heat transfer augmentation. Hence in the present study, experiments were performed on solar flat plate collector with different cross section of absorber tubes (plain tube and internally grooved tubes with different helix angles) and by varying the mass flow rates of the working fluids. This study reports the experimental results of flat plate collector, where the working fluid is water and aqueous ethylene glycol (50 : 50). Temperature profile of grooved absorber tube will be compared with plain tube. Since conversion efficiency of solar devices is low, the present study mainly focuses on improving the efficiency of solar flat plate collector.     

Inverse Design of Cooling Arrays of Micro Pin-Fins Subject to Specified Coolant Inlet Temperature and Hot Spot Temperature

Given a micro pin-fin array cooling scheme with these constraints: (a) given maximum allowable temperature of the material (the hot spot temperature), (b) given inlet cooling fluid temperature, (c) given total pressure loss (pumping power affordable), and (d) given overall thickness of the entire micro pin-fin cooling array, find the maximum possible average heat flux on the hot surface and find the maximum possible heat flux at the hot spot under the condition that the entire amount of the inputted heat is removed by the cooling fluid. The goal was to create an optimum performance map for a cooling micro array having specified inlet coolant temperature and maximum temperature. Fully 3D conjugate heat transfer analysis was performed on each of the randomly created candidate configurations. Response surfaces based on Radial Basis Functions were coupled with a genetic algorithm to arrive at a Pareto set of best trade-off solutions. These Pareto optimized configurations indicate the maximum physically possible heat fluxes for specified material and constraints. Detailed off-design performance maps of such Pareto-optimized cooling arrays of micro pin-fins were calculated that demonstrate superior on-design and off-design performance of pin-fins having symmetric convex cross sections as opposed to the commonly used circular cross sections.     

Multi-Objective Optimization of Micro Pin-Fin Arrays for Cooling of High Heat Flux Electronics with a Hot Spot

ABSTRACT

This article presents fully three-dimensional conjugate heat transfer analysis and a multi-objective, constrained optimization to find sizes of pin-fins, inlet water pressure, and average speed for arrays of micro pin-fins used in the forced convection cooling of an integrated circuit with a uniformly heated 4 × 3 mm footprint and a centrally located 0.5 × 0.5 mm hot spot. Sizes of micro pin-fins having cross sections shaped as circles, symmetric airfoils, and symmetric convex lenses are optimized to completely remove heat due to a steady, uniform heat flux of 500 W cm^?2 imposed over the entire footprint (background heat flux) and a steady, uniform heat flux of 2000 W cm^?2 imposed on the hot spot area only (hot spot heat flux). The two simultaneous objectives are to minimize maximum substrate temperature and minimize pumping power, while keeping the maximum temperature constrained below 85°C and removing all of input thermal energy by convection. The design variables are the inlet average velocity and size of the pin-fins. A response surface is generated for each of the objectives and coupled with a genetic algorithm to arrive at a Pareto frontier of the best trade-off solutions. Numerical results show that, for a specified maximum temperature, optimized arrays with pin-fins having symmetric convex lens shapes create the lowest pressure drop, followed by the symmetric airfoil and circular cross-section pin-fins. An a posteriori three-dimensional stress–deformation analysis incorporating hydrodynamic and thermal loads shows that Von-Mises stress for each pin-fin array is significantly below the yield strength of silicon, thus, confirming structural integrity of such arrays of micro pin-fins.