Glycosylation,denaturation, and aggregation of soy proteins in defatted soy flakes flour: Influence of thermal and homogenization treatments

This article provides a systematic study of the impact of different thermal treatments (62 ± 2°C, without and with relative humidity control, 79%) on soy protein in defatted soy flour and their aqueous dispersions. The effect of dispersing treatments (magnetic stirring, high-speed, and high-pressure homogenization) on dispersions also was assessed. Changes in protein solubility (water and 0.2 g/100 g potassium hydroxide solution), apparent-reactive lysine content, urease and trypsin inhibitor activities, protein denaturation, and Fourier transform infrared spectra were studied. Glycosylation, aggregation, and denaturation of storage and biologically active soy proteins were observed in different degrees, being mainly promoted by the control of relative humidity and the dispersibility of the sample.     

Designing biomass supply chains within planetary boundaries

The design of sustainable supply chains, which recently emerged as an active area of research in process systems engineering, is vital to ensure sustainable development. Despite past and ongoing efforts, the available methods often overlook impacts beyond climate change or incorporate them via standard life cycle assessment metrics that are hard to interpret from an absolute sustainability viewpoint. We here address the design of biomass supply chains considering critical ecological limits of the Earth—planetary boundaries—which should never be surpassed by anthropogenic activities. Our method relies on a mixed-integer linear program that incorporates a planetary boundaries-based damage model to quantify absolute sustainability precisely. We apply this approach to the sugarcane-to-ethanol industry in Argentina, identifying the optimal combination of technologies and network layout that minimize the impact on these ecological boundaries. Our framework can find applications in a wide range of supply chain problems related to chemicals and fuels production, energy systems, and agriculture planning.     

Combination of Ag Substrate Decoration with Introduction of?BaZrO3 Nano-Inclusions for?Enhancing Critical Current Density of?YBa2Cu3O7 Films

The combination of two methods: Ag substrate decoration and introduction of BZO nano-inclusions has been used in a pulsed laser deposition (PLD) method to increase the critical density (J _c ) of YBCO films. The films were deposited on single crystal SrTiO₃ (STO) substrates decorated with various architecture of Ag nano-dots. We have studied the diameter and density of Ag nano-dots and their influence on J _c of BZO-added YBCO films. We found that 15 laser pulses on the Ag target gives an optimum result in increasing J _c in comparison with BZO-doped YBCO films of the same thickness in self-field and low applied magnetic fields. A higher number of laser pulses on the Ag target led to increasing critical current density in high applied magnetic fields only (above 2 T). We have studied films of the thickness from 0.4 ??m to 3.8 ??m and found that the highest J _c at all applied fields investigated is achieved for a 1.2 ??m thick film. The transmission electron microscopy clearly shows BZO nano-rods that provide strong c-axis pinning centres in the films.     

Expert system for the integrated management of a power utility'scommunication system

In this paper we present a rule-based expert system applied to the fault diagnosis in the communication system of a power utility. The expert system is part of the system devoted to the management of a power utility's communication system, that we called NOMOS. NOMOS manages the communication systems of Sevillana de Electricidad and Union Electrica Fenosa (two major Spanish power utilities)     

A systems view of temporary housing projects in post‐disaster reconstruction

Natural cataclysms (earthquakes, hurricanes and so forth) become natural disasters when they coincide with vulnerabilities; unfortunately, informal settlements in developing countries are only too often highly vulnerable – a reality amply and unhappily confirmed by available statistics. In this context, reconstruction projects are sandwiched between the short‐term necessity to act promptly and the long‐term requirements of sustainable community development – a situation that is currently reflected in alternative and conflicting paradigms at the policy level.

Adopting a case‐study approach, we explore the use of temporary housing within two post‐disaster environments, where the impact of different organizational designs leads to fundamentally different solutions to the short‐term housing problem.

Our research adopts a dynamic systems approach, associating strategic organizational team design with the development of tactical technical proposals. Two case studies from Turkey and Colombia show that a coherent approach to the sequential stages of providing immediate shelter, temporary housing and permanent reconstruction is not always obtained. The research results emphasize that the performance of reconstruction projects is directly linked to the design and management of the project team.     

Characterisation of glasses in the TeO2–WO3–PbO system

As potential candidates for photonic devices, non-linear materials and coatings, 22 glasses in the TeO₂–WO₃–PbO system have been formulated and prepared by conventional melting at temperatures ranging between 710 and 750 °C. The glass forming area has been determined for a wide region of the corresponding ternary diagram. Structural characterisation of the glasses was conducted through FTIR spectrometry and the variation of density values, which allowed calculation of the glass molar volume and the oxygen molar volume. UV–VIS spectra were recorded to determine optical absorption/transmission and energy gap values. Likewise, such results were correlated with the glasses composition and their ability for optical materials. DTA curves yielded data of transition temperature (T_g), onset crystallisation temperature (T_c) and the thermal stability range of glasses. Crystalline phases formed in devitrified and partially devitrified glasses were detected by X-ray diffraction. The properties and structural features of glasses were discussed in terms of their relative proportion of former/modifier oxides. The main glass former oxide is TeO₂, which arranges [TeO₄] groups with tetrahedral coordination, while PbO plays as glass modifier oxide. Tungsten oxide is incorporated as network former, alternating with TeO₂ and forming mixed linkages Te–O–W and W–O–W. WO₃ is the component that contributes most to increase the glass transition temperature, and to decrease both the oxygen molar volume and the thermal expansion coefficient.     

Identification of the flavonoid fraction in saffron spice by LC/DAD/MS/MS: Comparative study of samples from different geographical origins

The flavonoid fraction in saffron spice has been analysed, for the first time, by LC-DAD-MS/MS ESI and five kaempferol derivatives have been found. Compounds such as kaempferol-3-sophoroside, kaempferol-3-sophoroside-7-glucoside and kaempferol-3,7,4′-triglucoside were tentatively identified, whereas other compounds, such as kaempferol tetrahexoside and kaempferol-3-dihexoside were detected. Saffron samples from different geographical origins were clearly separated by their kaempferol 3-sophoroside contents that were able to explain 100% of the variance when a discriminant test was carried out.