Graft copolymerization of polyacrylonitrile (PAN) onto polyester (PET) and simultaneous homopolymerization: A kinetic study. I

The kinetics of graft copolymerization of polyacrylonitrile (PAN) onto polyester (PET) and the simultaneous homopolymerization initiated by the potassium penoxomonosulfate (PMS)–ascorbic acid (H₂A) redox system were studied separately. Results on the graft copolymerization was adequately explained by a mechanism which also accounts for the reason for simultaneous homopolymerization. The observed homopolymerization results agreed with the proposal. Kinetic chain-length measurements on the graft copolymer and homopolymerization were used to evaluate the kinetic parameters. © 1995 John Wiley & Sons, Inc.     

Performance analysis of torus optical interconnect with data center traffic

Two-dimensional torus network nodes are typically interconnected using XY routing algorithm for transmitting a packet from a source node to a destination node. In XY routing, if all the paths are used efficiently, the throughput and latency can be improved. In this paper, to utilize all the paths efficiently, we propose a novel binary optical routing algorithm (BORA) to improve the throughput and latency. The throughput is calculated according to the injection rate and number of packets received at the destination. The XY routing algorithm and proposed BORA are implemented using objective modular network testbed in C++ simulation software and the results are analyzed and compared. In this paper, the simulation results show that the network latency reduces to 50% while using the proposed algorithm; moreover, the throughput is also improved.     

Where is the teacher? Digital analytics for classroom proxemics

The term Classroom Proxemics refers to how teachers and students use classroom space, and the impact of this and the spatial design on learning and teaching. This study addresses the divide between, on the one hand, substantial work on proxemics based on classroom observations and, on the other hand, emerging work to design automated feedback that helps teachers identify salient patterns in their use of the classroom space. This study documents how digital analytics were designed in service of a senior teacher's practice-based inquiry into classroom proxemics. Indoor positioning data from four teachers were analysed, visualized and used as evidence to compare three distinct learning designs enacted in a physics classroom. This study demonstrates how teachers can make effective use of such visualizations, to gain insight into their classroom practice. This is evidenced by (a) documenting teachers' reflections on visualizations of positioning data, both their own and that of peers and (b) identifying the types of indicator (operationalized as analytical metrics) that foreground the most useful information for teachers to gain insight into their practice.     

Deep‐Blue Phosphorescent Ir(III) Complexes with Light‐Harvesting Functional Moieties for Efficient Blue and White PhOLEDs in Solution‐Process

The photoluminescence (PL) efficiency of emitters is a key parameter to accomplish high electroluminescent performance in phosphorescent organic light‐emitting diodes (PhOLEDs). With the aim of enhancing the PL efficiency, this study designs deep‐blue emitting heteroleptic Ir(III) complexes (tBuCN‐FIrpic, tBuCN‐FIrpic‐OXD, and tBuCN‐FIrpic‐mCP) for solution‐processed PhOLEDs by covalently attaching the light‐harvesting functional moieties (mCP‐Me or OXD‐Me) to the control Ir(III) complex, tBuCN‐FIrpic. These Ir(III) complexes show similar deep‐blue emission peaks around 453, 480 nm (298 K) and 447, 477 nm (77 K) in chloroform. tBuCN‐FIrpic‐mCP demonstrates higher light‐harvesting efficiency (142%) than tBuCN‐FIrpic‐OXD (112%), relative to that of tBuCN‐FIrpic (100%), due to an efficient intramolecular energy transfer from the mCP group to the Ir(III) complex. Accordingly, the monochromatic PhOLEDs of tBuCN‐FIrpic‐mCP show higher external quantum efficiency (EQE) of 18.2% with one of the best blue coordinates (0.14, 0.18) in solution‐processing technology. Additionally, the two‐component (deep‐blue:yellow‐orange), single emitting layer, white PhOLED of tBuCN‐FIrpic‐mCP shows a maximum EQE of 20.6% and superior color quality (color rendering index (CRI) = 78, Commission Internationale de L'Eclairage (CIE) coordinates of (0.353, 0.352)) compared with the control device containing sky‐blue:yellow‐orange emitters (CRI = 60, CIE coordinates of (0.293, 0.395)) due to the good spectral coverage by the deep‐blue emitter.