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81.
Dai‐Ming Tang Cui‐Lan Ren Ling Zhang Ying Tao Peng Zhang Wei Lv Xiang‐Ling Jia Xiaojuan Jiang Guangmin Zhou Takahito Ohmura Ping Huai Feng Li Yoshio Bando Dmitri Golberg Quan‐Hong Yang 《Advanced functional materials》2019,29(19)
It is essential to understand the size scaling effects on the mechanical properties of graphene networks to realize the potential mechanical applications of graphene assemblies. Here, a “highly dense‐yet‐nanoporous graphene monolith (HPGM)” is used as a model material of graphene networks to investigate the dependence of mechanical properties on the intrinsic interplanar interactions and the extrinsic specimen size effects. The interactions between graphene sheets could be enhanced by heat treatment and the plastic HPGM is transformed into a highly elastic network. A strong size effect is revealed by in situ compression of micro‐ and nanopillars inside electron microscopes. Both the modulus and strength are drastically increased as the specimen size reduces to ≈100 nm, because of the reduced weak links in a small volume. Molecular dynamics simulations reveal the deformation mechanism involving slip‐stick sliding, bending, buckling of graphene sheets, collapsing, and densification of graphene cells. In addition, a size‐dependent brittle‐to‐ductile transition of the HPGM nanopillars is discovered and understood by the competition between volumetric deformation energy and critical dilation energy. 相似文献
82.
Two-dimensional(2D) atomic crystals,such as graphene,black phosphorus(BP) and transition metal dichalcogenides(TMDCs) are attractive for use in optoelectronic devices,due to their unique crystal structures and optical absorption properties.In this study,we fabricated BP/ReS2 van der Waals(vdWs) heterojunction devices.The devices realized broadband photoresponse from visible to near infrared(NIR)(400–1800 nm) with stable and repeatable photoswitch characteristics,and the photoresponsivity reached 1.8 mA/W at 1550 nm.In addition,the polarization sensitive detection in the visible to NIR spectrum(532–1750 nm) was demonstrated,and the photodetector showed a highly polarization sensitive photocurrent with an anisotropy ratio as high as 6.44 at 1064 nm.Our study shows that van der Waals heterojunction is an effective way to realize the broadband polarization sensitive photodetection,which is of great significance to the realization and application of multi-functional devices based on 2D vdWs heterostructures. 相似文献
83.
本文通过MPEG-2和MPEG-1在视频方面的比较,简略地介绍了MPEG-2视频标准,并附带介绍了C-CUBE公司的MPEG-2视频编码芯片CLM4400的功能和应用前景。 相似文献
84.
处理传输故障的关键是故障的准确定位。为了达到这个目标,需要在维护时清楚故障定位的原则、排查故障的可能原因,掌握一种高效的手段或方法来迅速处理可能遇到的各种故障。 相似文献
85.
86.
PLC提高性实验的实验教学改革探索 总被引:1,自引:0,他引:1
介绍PLC即可编程序控制器在实验教学中进行的提高性实验,提高性实验之一是PLC对三台鼠笼异步电动机的自动与手动控制,PLC指令的灵活应用及实现。 相似文献
87.
Dopamine‐Modified Cationic Conjugated Polymer as a New Platform for pH Sensing and Autophagy Imaging
Quanshan Wen Libing Liu Qiong Yang Fengting Lv Shu Wang 《Advanced functional materials》2013,23(6):764-769
A dopamine‐modified conjugated polymer PFPDA is synthesized and characterized. At low pH, dopamine exists in its hydroquinone form and lacks the ability to quench fluorescence. At high pH, the proportion of the quinone form of dopamine increases due to its autooxidation, and efficient intramolecular electron transfer from the polymer main chain to quinone occurs, resulting in the quenching of the fluorescence of PFPDA. Thus, PFPDA exhibits a fluorescence “turn‐on” response at low pH. PFPDA possesses excellent photostability and exhibits no cytotoxicity, which makes it a good fluorescent material for pH sensing and cell imaging. A light‐induced hydroxyl anion emitter, MGCB, is also used to change the pH of the solution and thus regulate the fluorescence of PFPDA via remote control under light irradiation. Because the cytoplasm becomes acidic when cell autophagy occurs, PFPDA can also be used for autophagy imaging of HeLa cells with good selectivity. 相似文献
88.
Guanhong Chen Yuanhong Kang Huiya Yang Minghao Zhang Jin Yang Zeheng Lv Qilong Wu Pengxiang Lin Yang Yang Jinbao Zhao 《Advanced functional materials》2023,33(28):2300656
Aqueous zinc-iodine (Zn-I2) batteries are promising candidates for grid-scale energy storage due to their safety and cost-effectiveness. However, the shuttle effect of polyiodides, Zn corrosion, and accumulation of by-products restrict their applications. Herein, a simple vermiculite nanosheets (VS) suspension electrolyte is designed for simultaneous confinement of polyiodides and stabilization of Zn anode. It is found that the generation of I5− as dominant intermediate and the precipitation reaction between I5− and alkaline by-products should cause irreversible iodine species loss. Benefiting from the high binding energy between polyiodides and silica-oxygen bonds of VS, dissolved polyiodides are effectively anchored on the surface of VS suspended in the bulk electrolyte to suppress the shuttle effect, which is confirmed by in situ Raman, Ultraviolet-visible characterizations and theoretical calculations. Furthermore, the self-assembly VS interfacial layer on the surface of Zn anode hinders side reactions induced by polyiodides. Meanwhile, the interlayer and surface excess negative charges of VS tend to be compensated by Zn2+ from diffuse layer, which serves as ion accelerators for transferring Zn2+ at the interface immediately, rendering dendrite-free Zn plating/stripping behavior. Consequently, the Zn-I2 battery with VS electrolyte achieves an ultra-long lifespan of 40000 cycles with a negligible capacity decay at 20 C. 相似文献
89.
Network virtualization of a wireless mesh network (WMN) is an economical way for different subscribers to customize their exclusive access networks through a common network infrastructure. The most critical task of network virtualization is virtual network embedding, which can be divided into two sub-problems: node mapping and link mapping. Although there exist approaches to virtual network embedding in wired networks, the characteristics of WMNs make virtual network embedding become a unique and challenging problem. In this paper, virtual access network embedding is studied for WMNs. To support flexible resource allocation in virtual access network embedding, each access node is designed based on orthogonal frequency division multiple access (OFDMA) dual-radio architecture. Through subcarrier allocation on each link, virtual access networks are gracefully separated from each other. To coordinate channel assignment across different links under the constraint of a limited number of orthogonal channels, a novel channel allocation algorithm is proposed to exploit partially-overlapped channels to improve resource utilization. Since the virtual access network embedding problem is NP-hard, a heuristic algorithm is developed based on an enhanced genetic algorithm to obtain an approximate but effective solution. Simulation results illustrate that the virtual access network embedding framework developed in this paper works effectively in WMNs. 相似文献
90.
本文从全球3G发展趋势、电信企业"做大做强"、国内3G发牌的条件、3G对其它产业的拉动、"数字奥运"等多个方面阐述了推动3G发牌的必要性与促进我国信息产业新发展的重大意义. 相似文献