Self-assembling of atomic vacancies at an oxide/intermetallic alloy interface

Oxide layers grown on the surface provide an effective way of protecting metallic materials against corrosion for sustainable use in a broad range of applications. However, the growth of cavities at the metal/oxide interface weakens the adherence of the protective layer and can promote its spallation under service conditions, as observed for alumina layers formed by selective oxidation of aluminide intermetallic alloys used in high-temperature applications. Here we show that direct atomic-scale observations of the interface between an ultrathin protective oxide layer (alumina) grown on an intermetallic titanium aluminide substrate (TiAl) can be performed with techniques sensitive to the topmost atomic layers at the surface. Nanocavities resulting from the self-assembling of atomic vacancies injected at the interface by the growth mechanism of the protective oxide are observed for the first time, bringing new insight into the understanding of the fate of injected cavities in oxidation processes.     

Generalized diffusion model in optical tomography with clear layers

We introduce a generalized diffusion equation that models the propagation of photons in highly scattering domains with thin nonscattering clear layers. Classical diffusion models break down in the presence of clear layers. The model that we propose accurately accounts for the clear-layer effects and has a computational cost comparable to that of classical diffusion. It is based on modeling the propagation in the clear layer as a local tangential diffusion process. It can be justified mathematically in the limit of small mean free paths and is shown numerically to be very accurate in two- and three-dimensional idealized cases. We believe that this model can be used as an accurate forward model in optical tomography.     

The impact of print exposure quality and inference construction on syllogistic reasoning.

This study extended the work of S. Siddiqui, R. F. West, and K. E. Stanovich (1998), who studied the link between general print exposure and syllogistic reasoning. It was hypothesized that exposure to certain text structures that contain well-delineated logical forms, such as popularized scientific texts, would be a better predictor of deductive reasoning skill than general print exposure, which is not sensitive to the quality of an individual's reading activity. Furthermore, it was predicted that the ability to generate explanatory bridging inferences while reading would also be predictive of syllogistic reasoning. Undergraduate students (N = 112) were tested for vocabulary, nonverbal cognitive ability, exposure to general print, exposure to popularized scientific literature, and the ability to comprehend texts distinguished by the number of inferences that must be generated to support comprehension. Hierarchical multiple regression analyses showed that a combined measure of exposure to general and scientific literature was a significant predictor of syllogistic reasoning ability. Additionally, the ability to comprehend high-inference-load texts was related to solving syllogisms that were inconsistent with world knowledge, indicating an overlap in deductive reasoning skill and text comprehension processes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Sintering Behavior and Optical Properties of Yttria

Sintering in air of a pure yttria powder was investigated on green samples shaped by slip casting. The "relative density/grain size" trajectory has been drawn and hypotheses concerning the mechanisms controlling grain growth and densification were formulated. Samples were fully densified by an additional hot isostatic pressing step on pre-sintered samples. After optimal polishing, optical properties were measured in the UV, visible, and infrared ranges.     

Application of neural-fuzzy controller for streaming video over Bluetooth 1.2

This paper is to introduce an application of Computational Intelligence (CI) to Moving Picture Expert Group-4 (MPEG-4) video compression over IEEE.802.15.1 wireless communication, known as Bluetooth 1.2, in order to improve picture quality. The 2.4 GHz Industrial, Scientific and Medical frequency band is used for the IEEE.802.15.1 standard. IEEE.802.15.1 can be affected by noise and interference due to other neighboring wireless devices sharing the same frequency carrier. The noise and interference create difficulties in ascertaining an accurate real-time transmission rate at the receiving end. Furthermore, the MPEG-4 codec is an object-oriented compression system and demands a high bandwidth. It is therefore difficult to avoid excessive delay, image quality degradation and/or data loss during MPEG-4 video transmission over standard systems. A new buffer entitled ‘buffer added’ has been introduced at the input of the Bluetooth 1.2 device. This buffer is controlled by a Rule-Based Fuzzy (RBF) logic controller at the input and a neural-fuzzy controller (NFC) at the output. The two new fuzzy rules manipulate and supervise the flow of video over the Bluetooth 1.2 standard. The computer simulation results illustrate the comparison between a non-CI video transmission over Bluetooth 1.2 and the proposed design, confirming that the applications of RBF and NFC do improve the image quality, reduce data loss and reduce time delay.     

Validation of the performance of a GMO multiplex screening assay based on microarray detection

A new screening method for the detection and identification of GMO, based on the use of multiplex PCR followed by microarray, has been developed and is presented. The technology is based on the identification of quite ubiquitous GMO genetic target elements first amplified by PCR, followed by direct hybridisation of the amplicons on a predefined microarray (DualChip^® GMO, Eppendorf, Germany). The validation was performed within the framework of a European project (Co-Extra, contract no 007158) and in collaboration with 12 laboratories specialised in GMO detection. The present study reports the strategy and the results of an ISO complying validation of the method carried out through an inter-laboratory study. Sets of blind samples were provided consisting of DNA reference materials covering all the elements detectable by specific probes present on the array. The GMO concentrations varied from 1% down to 0.045%. In addition, a mixture of two GMO events (0.1% RRS diluted in 100% TOPAS19/2) was incorporated in the study to test the robustness of the assay in extreme conditions. Data were processed according to ISO 5725 standard. The method was evaluated with predefined performance criteria with respect to the EC CRL method acceptance criteria. The overall method performance met the acceptance criteria; in particular, the results showed that the method is suitable for the detection of the different target elements at 0.1% concentration of GMO with a 95% accuracy rate. This collaborative trial showed that the method can be considered as fit for the purpose of screening with respect to its intra- and inter-laboratory accuracy. The results demonstrated the validity of combining multiplex PCR with array detection as provided by the DualChip^® GMO (Eppendorf, Germany) for the screening of GMO. The results showed that the technology is robust, practical and suitable as a screening tool.     

Sintering of an ultra pure α-alumina powder: I. Densification,grain growth and sintering path

Sintering in air of an ultra pure α-alumina powder has been investigated. Isothermal experiments have been conducted on green samples shaped by slip casting. The grain growth and densification kinetics have been established. The “relative density/grain size” trajectory, called “sintering path”, has been drawn. Hypotheses concerning the mechanisms controlling grain growth and densification have been formulated. For the first time, it is shown that grain growth and densification kinetics exhibit two distinct regimes, where an initial point defect formation step plays a key role. When point defects have been generated, the diffusion of the associated Al³⁺ cations controls grain growth and densification.     

Spark Plasma Sintering of fine alpha-silicon nitride ceramics with LAS for spatial applications

Many space systems such as satellite mirrors and their supporting structures require to be made from very low-thermal expansion materials combining both high hydrostability and relatively high mechanical properties. In this study, we have applied the “composite concept” in order to explore the possibility of fabricating near zero thermal expansion silicon nitride based ceramics. Consequently, a negative thermal expansion material belonged to the lithium aluminosilicate family (LAS powder crystallized under de β-eucryptite structure) was introduced in an alpha-silicon nitride fine powder (5 and 20 vol% of LAS) and the resulting composite system was sintered by Spark Plasma Sintering (SPS) at 1400 and 1500 °C. In the case of 20 vol% LAS compositions, relatively well-densified ceramics (94.4% of the theoretical density) were produced without adding any further sintering additive. The addition of yttria and alumina oxides allowed enhancing the densification level up to 98.2% (20 vol% LAS compositions) or from 62.3% up to 96.7% of the theoretical density in 5 vol% LAS materials. Nevertheless, it was impossible to full consolidate silicon nitride/LAS composite ceramics at temperatures lower than the temperature at which β-eucryptite melts, even by using SPS technology. Moreover, because of the relatively low temperatures involved in SPS, the α to β-Si₃N₄ transformation was avoided, resulting in microstructures composed of fine equiaxed α-Si₃N₄ grains (<200 nm) and of a glassy phase. Even if the effect of having a very large negative thermal expansion material was lost during the sintering step (because of the β-eucryptite melting), ceramics containing only 20 vol% of LAS-based phase exhibited very interesting values as regards of mechanical properties (strength, hardness, toughness, and Young's modulus), thermal conductivity and thermal expansion coefficient. We discuss in this work why we are so interested in developing dense silicon nitride/LAS ceramics sintered without any further additive addition, even though β-eucryptite is melted during the process and the transformation to the β phase is avoided.