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61.
Synthesis and characterization of the polyols by air oxidation of soybean oil and its effect on the morphology and dynamic mechanical properties of poly(vinyl chloride) blends
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Pedro A. Ourique Jérôme M. L. Gril Gaëlle W. Guillaume Cesar H. Wanke Sergio G. Echeverrigaray Otávio Bianchi 《应用聚合物科学杂志》2015,132(24)
The use of natural additives, with low toxicity and good compatibility, for PVC is becoming increasingly attractive. In this study, soybean oil additives were prepared by air oxidation reactions and blending with PVC. The oxidation reaction produced a significant increase in the number of hydroxyl groups in soybean oil; however, this kind of reaction results in the formation of a heterogeneous structure due to free radical reactions in the medium. The oxidized soybean oil improved the compatibility with PVC due to an increase in the number of polar groups, such as hydroxyls, and thus a reduction in the amount of atactic polymer was observed. Furthermore, an increase in the molecular weight of the oxidized oil, as well as large amounts of polar groups contributes to reducing the migration of oil in the PVC. Regarding the crystallinity of PVC, the use of pure and oxidized soybean oil causes small changes in the crystalline phase of the polymer. Oxidized soybean oil has great potential for usage as a secondary plasticizer for PVC. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42102. 相似文献
62.
63.
Operational transfer path analysis 总被引:2,自引:0,他引:2
Gert De Sitter Christof Devriendt Patrick Guillaume Erik Pruyt 《Mechanical Systems and Signal Processing》2010,24(2):416-431
One of the tools used to study the NVH behaviour of a system is the transfer path analysis. It aims to identify the operational forces and the propagation paths of the vibrations and is especially interesting in the case when the system is composed of different subsystems. The classical techniques identify the transfer paths when the system is disassembled. This way one eliminates flanking transfer paths. Yet it is very time-consuming and the boundary conditions are not correct anymore. The presented method makes it possible to identify the transfer paths without disassembling the system. The advantages are that the overall testing time is reduced and that the real boundary conditions are present. In this article the theory will be reviewed and it will be validated using data generated by finite element simulations. 相似文献
64.
Carole Guillaume Jeremy Pinte Nathalie Gontard Emmanuelle Gastaldi 《Food research international (Ottawa, Ont.)》2010,43(5):1395-1401
The objective of the present work was to understand how the structural, surface, water vapour and gas barrier properties of wheat gluten (WG) coated paper could be influenced by the features of paper. For this purpose, a surface treated paper (TP) and an untreated paper (UTP) were compared. Penetration of WG-coating into the bulk of paper was more pronounced in UTP than TP. This led to the formation of a significant junction zone resulting in an interpenetrated structure for WG–UTP, suggesting a composite-like structure, while a bi-layer one was obtained for WG–TP. Differences in WG penetration were related to the hydrophilicity, roughness and porosity of the paper used. Even though the extent of penetration did not greatly affect the surface properties (water and oil resistance), the transfer properties (water vapour, O2 and CO2) of WG-coated papers were significantly improved when WG-coating highly penetrated: while the WG–TP behaved as a micro-perforated material, the WG–UTP behaved as WG-film. 相似文献
65.
Nielsen Guillaume Janin Amelie Coudert Lucie Blais Jean Francois Mercier Guy 《Mine Water and the Environment》2018,37(1):42-55
Mine Water and the Environment - Passive treatment is a promising, green technology that is increasingly being used for mine drainage treatment. However, several challenges remain concerning its... 相似文献
66.
The increase in computational capabilities has made time-domain methods applicable for long-range sound propagation modelling. However, such approaches remain very demanding in terms of computational resources. Most current computers are supplied with a powerful device which is still little exploited: the graphics processing unit (GPU). The paper describes an implementation of a transmission line matrix model which allows parallel calculations on heterogeneous systems. A voxelization algorithm used to generate the computational domain is presented. A splitting process is also expounded which makes feasible performing huge domains simulations by accurately dividing the computational domain into subdomains. Each subdomain is enlarged by introducing extra cells containing neighbours subdomains data in order to run several computational iterations on a graphic device without data exchange with the system memory. The influence of the ghost layer depth and the speeding up of computation time with GPU are then illustrated in a realistic built-up area. 相似文献
67.
Xianqin Meng Guillaume Gomard Ounsi El Daif Emmanuel Drouard Regis Orobtchouk Anne Kaminski Alain Fave Mustapha Lemiti Alexei Abramov Pere Roca i Cabarrocas Christian Seassal 《Solar Energy Materials & Solar Cells》2011
In this paper, we present the integration of an absorbing photonic crystal within a thin-film photovoltaic solar cell. Optical simulations performed on a complete solar cell revealed that patterning the hydrogenated amorphous silicon active layer as a 2D photonic crystal membrane enabled to increase its integrated absorption by 28 % between 300 and 720 nm, comparing to a similar but unpatterned stack. In order to fabricate such promising cells, we developed a high throughput process based on holographic lithography and reactive ion etching. The influences of the parameters taking part in those processes on the obtained patterns are discussed. Optical measurements performed on the resulting “photonized” solar cell structures underline the regularity of the 2D pattern and a significant absorption increase above 550 nm, similarly to what is observed on the simulated absorption spectra. Moreover, our patterned cells are found to be robust with regards to the angle of incidence of the light. 相似文献
68.
Guillaume Pichavant Daniel Beysens Denis Chatain Daniel Communal Clément Lorin Alain Mailfert 《Microgravity science and technology》2011,23(2):129-133
A ground based facility (OLGA), providing magnetic compensation of gravity in oxygen, has been developed. A 2-T superconducting
magnetic solenoid is used to create the required magnetic field. A novel electrical supply permits to quickly vary the magnetic
field, leading to rapid variation of the acceleration forces applied to oxygen. These variations can be made from overcompensation
of gravity (−0.5g) to zero gravity or from zero gravity to reduced gravity (0.4g) with a time constant of 340 ms. This time is typical of the cutoff or reignition of spacecraft engines. Preliminary results
on the transient flows induced by these acceleration variations in a reservoir filled with liquid and gaseous oxygen are presented. 相似文献
69.
Olivier Terraz Guillaume Guimberteau Stéphane Mérillou Dimitri Plemenos Djamchid Ghazanfarpour 《The Visual computer》2009,25(2):165-180
In this paper an extension of L-systems is proposed, based on three-dimensional (3D) generalized maps that allow an easier
control of the internal structure of 3D objects. A first and original application of this extension is also proposed: wood
modelling by growth simulation. Numerous other applications of our work are possible, in the area of computer graphics, as
well as in botanical science. 相似文献
70.
Helen Reveron Laurent Blanchard Yann Vitupier Emmanuelle Rivière Guillaume Bonnefont Gilbert Fantozzi 《Journal of the European Ceramic Society》2011,31(4):645-652
Many space systems such as satellite mirrors and their supporting structures require to be made from very low-thermal expansion materials combining both high hydrostability and relatively high mechanical properties. In this study, we have applied the “composite concept” in order to explore the possibility of fabricating near zero thermal expansion silicon nitride based ceramics. Consequently, a negative thermal expansion material belonged to the lithium aluminosilicate family (LAS powder crystallized under de β-eucryptite structure) was introduced in an alpha-silicon nitride fine powder (5 and 20 vol% of LAS) and the resulting composite system was sintered by Spark Plasma Sintering (SPS) at 1400 and 1500 °C. In the case of 20 vol% LAS compositions, relatively well-densified ceramics (94.4% of the theoretical density) were produced without adding any further sintering additive. The addition of yttria and alumina oxides allowed enhancing the densification level up to 98.2% (20 vol% LAS compositions) or from 62.3% up to 96.7% of the theoretical density in 5 vol% LAS materials. Nevertheless, it was impossible to full consolidate silicon nitride/LAS composite ceramics at temperatures lower than the temperature at which β-eucryptite melts, even by using SPS technology. Moreover, because of the relatively low temperatures involved in SPS, the α to β-Si3N4 transformation was avoided, resulting in microstructures composed of fine equiaxed α-Si3N4 grains (<200 nm) and of a glassy phase. Even if the effect of having a very large negative thermal expansion material was lost during the sintering step (because of the β-eucryptite melting), ceramics containing only 20 vol% of LAS-based phase exhibited very interesting values as regards of mechanical properties (strength, hardness, toughness, and Young's modulus), thermal conductivity and thermal expansion coefficient. We discuss in this work why we are so interested in developing dense silicon nitride/LAS ceramics sintered without any further additive addition, even though β-eucryptite is melted during the process and the transformation to the β phase is avoided. 相似文献