3Gmap L-systems: an application to the modelling of wood

In this paper an extension of L-systems is proposed, based on three-dimensional (3D) generalized maps that allow an easier control of the internal structure of 3D objects. A first and original application of this extension is also proposed: wood modelling by growth simulation. Numerous other applications of our work are possible, in the area of computer graphics, as well as in botanical science.     

Spark Plasma Sintering of fine alpha-silicon nitride ceramics with LAS for spatial applications

Many space systems such as satellite mirrors and their supporting structures require to be made from very low-thermal expansion materials combining both high hydrostability and relatively high mechanical properties. In this study, we have applied the “composite concept” in order to explore the possibility of fabricating near zero thermal expansion silicon nitride based ceramics. Consequently, a negative thermal expansion material belonged to the lithium aluminosilicate family (LAS powder crystallized under de β-eucryptite structure) was introduced in an alpha-silicon nitride fine powder (5 and 20 vol% of LAS) and the resulting composite system was sintered by Spark Plasma Sintering (SPS) at 1400 and 1500 °C. In the case of 20 vol% LAS compositions, relatively well-densified ceramics (94.4% of the theoretical density) were produced without adding any further sintering additive. The addition of yttria and alumina oxides allowed enhancing the densification level up to 98.2% (20 vol% LAS compositions) or from 62.3% up to 96.7% of the theoretical density in 5 vol% LAS materials. Nevertheless, it was impossible to full consolidate silicon nitride/LAS composite ceramics at temperatures lower than the temperature at which β-eucryptite melts, even by using SPS technology. Moreover, because of the relatively low temperatures involved in SPS, the α to β-Si₃N₄ transformation was avoided, resulting in microstructures composed of fine equiaxed α-Si₃N₄ grains (<200 nm) and of a glassy phase. Even if the effect of having a very large negative thermal expansion material was lost during the sintering step (because of the β-eucryptite melting), ceramics containing only 20 vol% of LAS-based phase exhibited very interesting values as regards of mechanical properties (strength, hardness, toughness, and Young's modulus), thermal conductivity and thermal expansion coefficient. We discuss in this work why we are so interested in developing dense silicon nitride/LAS ceramics sintered without any further additive addition, even though β-eucryptite is melted during the process and the transformation to the β phase is avoided.     

Behavior of Paramagnetic Iron during the Thermal Transformations of Kaolinite

Kaolinites with various degrees of structural order and iron content were heated and subsequently analyzed via electron paramagnetic resonance. Iron was present in two different states in the heated materials, either as dilute structural Fe³⁺ ions or in concentrated Fe³⁺ phases. During metakaolinization, the environment of dilute Fe³⁺ ions changed, following modifications of the Al³⁺ coordination, and the Fe³⁺ concentration increased. With the breakdown of metakaolinite, the diffusion of Fe³⁺ ions induced their exsolution in superparamagnetic iron-rich domains (Fe³⁺ clusters in γ-Al₂O₃ and/or Fe³⁺ oxide nanophases), which produced a decrease in the dilute Fe³⁺ concentration. The subsequent breakdown of γ-Al₂O₃ and the formation of mullite made the dilute Fe³⁺ concentration increase again, because of the incorporation of Fe³⁺ ions in the mullite structure.     

Photoclickable Surfaces for Profluorescent Covalent Polymer Coatings

The nitrile imine‐mediated tetrazole‐ene cycloaddition reaction (NITEC) is introduced as a powerful and versatile conjugation tool to covalently ligate macromolecules onto variable (bio)surfaces. The NITEC approach is initiated by UV irradiation and proceeds rapidly at ambient temperature yielding a highly fluorescent linkage. Initially, the formation of block copolymers by the NITEC methodology is studied to evidence its efficacy as a macromolecular conjugation tool. The grafting of polymers onto inorganic (silicon) and bioorganic (cellulose) surfaces is subsequently carried out employing the optimized reaction conditions obtained from the macromolecular ligation experiments and evidenced by surface characterization techniques, including X‐ray photoelectron spectroscopy and FT‐IR microscopy. In addition, the patterned immobilization of variable polymer chains onto profluorescent cellulose is achieved through a simple masking process during the irradiation.     

Thermo-mechanical characteristics of concrete at elevated temperatures up to 310 °C

Both, the normal strength concretes (NSC) and high strength concretes (HSC) have been used in structures which may be exposed to elevated temperatures. Concretes have also been used in the construction of radiation shielding structures. Data on the behaviour of concrete at high temperature is of prime concern in predicting the constructions and safety of buildings in response to certain accidents or particular service conditions. Prediction of mechanical behaviour, thermo-mechanical deformations and moisture migration in non-uniformly heated concrete is important for safe operation of concrete containment.This paper presents the results of an experimental investigation carried out to predict the behaviour of concrete intended for nuclear applications. For this purpose, normal concrete having compressive strength of 40 MPa was designed using limestone aggregates. Cylindrical specimens (110 mm × 22 mm) were made and subjected to heating-cooling cycles at 110, 210 and 310 °C. Measurements were taken for thermal gradient, mass loss, deformations, residual mechanical properties, thermal conductivity, and porosity. This investigation developed some important data on the properties of concrete exposed to elevated temperatures up to 310 °C. Comparisons and interesting conclusions were drawn about the thermal stability at high temperature and the residual mechanical properties of the tested concrete.     

A new sustainable hydrogen clean energy paradigm

We analyze the feasibility of a novel, hydrogen fuel cell electric generator to provide power with zero noise and emissions for myriad ground based applications. The hydrogen fuel cell electric generator utilizes a novel, scalable apparatus that safely generates hydrogen (H₂) on demand according to a novel method, using a controlled chemical reaction between water (H₂O) and sodium (Na) metal that yields hydrogen gas of sufficient purity for direct use in fuel cells without risk of contaminating sensitive catalysts. The sodium hydroxide (NaOH) byproduct of the hydrogen producing reaction, is collected within the apparatus for later reprocessing by electrolysis, to recover the Na reactant. The detailed analysis shows that the novel, hydrogen fuel cell electric generator will be capable of meeting the clean power requirements for residential and commercial buildings including single family homes and light commercial establishments under a wide range of geographic and climatic conditions.     

Modelling mechanical properties of spruce and Douglas fir timber by means of X-ray and grain angle measurements for strength grading purpose

This study proposes a model using data from a scanner (X-ray and grain angle measurements) to perform strength grading. The research also includes global measurements of modulus of elasticity (obtained by vibrations and ultrasound methods), static bending stiffness and bending strength of 805 boards of Douglas fir and 437 boards of spruce. This model can be used in an industrial context since it requires low computational time. The results of this study show that the developed model gives better results than the global non-destructive measurements of the elastic modulus commonly used in the industry. It also shows that this improvement is particularly higher in the case of Douglas fir than for spruce. The comparison has been made on both the quality of the mechanical properties assessment and on the improvement of the grading process according to the European standards by using different index.     

Physical market determinants of the price of crude oil and the market premium

We analyze the determinants of the real price of crude oil by means of an equilibrium correction model over the last two decades where we focus on the aspects of the physical market that impact on the clearing price. We find that two cointegrating relations affect the changes in prices: one refers to OPEC's behavior, attempting to control prices using its market power and quotas; the other to the coverage rate of OECD expected future demand using inventory behaviors. We derive a forecasting equation for the change in oil prices which we use to assess the speculative elements of the price increases of the period 2000–05. We show that worries alien to the physical markets were the causes of the increase in oil prices and we quantify their overall impact.     

Brockett's stabilization condition under state constraints

A variant of Brockett's necessary condition for feedback stabilization is derived, in the state constrained case.