Large strain behaviour of nanostructured polyelectrolyte hydrogels

The mechanical properties of nanostructured polyelectrolyte hydrogels have been investigated targeting specifically the nonlinear deformation regime at large strains and the fracture properties. The hydrogels were synthesized using a thiol-ene cross-linking chemistry of polyacrylic acid precursor chains previously functionalized with double bonds. Some polymers were also grafted with C₁₂ side chains able to form hydrophobic clusters in water. The large strain deformation of these nanostructured gels was tested in uniaxial compression by performing loading/unloading cycles at different strain rates and up to different maximum strains. All hydrogels displayed a pronounced strain hardening before fracture and a strain dependent hysteresis but the magnitude of these effects depended on the details of the composition. The most pronounced strain hardening was observed for the unmodified hydrogels in pure water while the largest hysteresis was found for the gels containing the highest concentration of nanoclusters. These dissipative processes barely influence the mechanical behaviour at small strains where the gel remains very elastic but become important at large strains and improve the resistance to fracture of the gels.     

Contact mechanics at the nanoscale,a 3D multiscale approach

We present a multiscale coupling method to address contact problems. The components of the model are a molecular dynamics engine, a finite element program and a coupling scheme. We validate the approach, first on Hertzian contact and then with a rough surface contacting a rigid body plane. Various measures are provided to highlight limitations and new opportunities in conducting large‐scale simulations of contact brought by the proposed multiscale approach. Copyright © 2009 John Wiley & Sons, Ltd.     

Kinetics of toluene and sulfur compounds removal by means of an integrated process involving the coupling of absorption and biodegradation

BACKGROUND: Scrubbing using an organic solution instead of an aqueous solution could be a useful way to improve the removal of hydrophobic compounds. Absorption of toluene, dimethyldisulfide (DMDS) and dimethylsulfide (DMS) in an organic solution (di‐2‐ethylhexyladipate—DEHA), followed by biodegradation by activated sludge was considered, with particular attention to kinetic aspects. DEHA was selected for its relevance in terms of absorption capacity and absorption velocity of the selected volatile organic compounds (VOCs). After the biodegradation step and owing to its cost, recycling of the VOC‐free solvent should be considered. RESULTS: Enhancement of VOC mass transfer from the organic to the aqueous phase due to bacterial activity was highlighted and the main driving force was found to be biosurfactant production rather than biodegradation reaction. However, the mass transfer rate between the two phases was shown to be lower than VOC biodegradation rate; hence, significant biodegradation of DMDS and toluene was recorded in a few days during batch experiments, 0.10 and 0.09 mmol respectively. Toluene showed higher biodegradation rates (about 0.05 and 0.10 mg h^?1 for DMDS and toluene), leading to higher growth rates. Contrarily, owing to its high volatility, important DMS losses were observed. CONCLUSION: The relevance of the proposed integrated process was shown for hydrophobic VOC removal, at least for toluene and DMDS. Unfortunately, the absorbent phase was also degraded, proved by detection of by‐products during analyses of the aqueous phase headspace. The comparison of DEHA with other solvents or solid polymers available for multiphase bioreactor applications may be a reliable option to continue this work. Copyright © 2010 Society of Chemical Industry     

Advantages of a mobile LSPIV method for measuring flood discharges and improving stage–discharge curves

This paper investigates the potential of fast flood discharge measurements conducted with a mobile LSPIV device. LSPIV discharge measurements were performed during two hydrological events on the Arc River, a gravel-bed river in the French Alps: a flood greater than the 10-year return period flood in May, 2008, and a reservoir flushing release in June, 2009. The mobile LSPIV device consists of a telescopic mast with a remotely controlled platform equipped with a video camera. The digital video camera acquired sequences of images of the surface flow velocities. Ground Reference Points (GRPs) were positioned using a total station, for further geometrical correction of the images. During the flood peak, surface flow velocities up to 7 m/s and large floating objects prevented any kind of intrusive flow measurements. For the computation of discharge, the velocity coefficient was derived from available vertical velocity profiles measured by current meter. The obtained value range (0.72–0.79) is consistent with previous observations at this site and smaller than the usual default value (0.85) or values observed for deeper river sections (0.90 typically). Practical recommendations are drawn. Estimating stream discharge in high flow conditions from LSPIV measurements entails a complex measurement process since many parameters (water level, surface velocities, bathymetry, velocity coefficient, etc.) are affected by uncertainties and can change during the experiment. Sensitivity tests, comparisons and theoretical considerations are reported to assess the dominant sources of error in such measurements. The multiplicative error induced by the velocity coefficient was confirmed to be a major source of error compared with estimated errors due to water level uncertainty, free-surface deformations, number of image pairs, absence or presence of artificial tracers, and cross-section bathymetry profiles. All these errors are estimated to range from 1% to 5% whereas the velocity coefficient variability may be 10%–15% according to the site and the flow characteristics. The analysis of 36 LSPIV sequences during both events allowed the assessment of the flood discharges with an overall uncertainty less than 10%. A simple hydraulic law based on the geometry of the three sills of the Pontamafrey gauging station was proposed instead of the existing curve that is fitted on available gauging data. The high flow LSPIV discharge measurements indicated that this new curve is more accurate for high discharges since they are evenly distributed in a ±10% interval around it. These results demonstrate the interest of the remote stream gauging techniques together with hydraulic analysis for improving stage–discharge relationships and reducing uncertainties associated with fast flood discharges.     

Titanium to steel joining by spark plasma sintering (SPS) technology

The bonding of Ti–6Al–4V to low alloy steel (AISI4330) using SPS technique in the 850–950 °C temperature range was examined. The formation of a thin (～1 μm) titanium carbide interfacial layer was observed with a thickness only slightly dependent on the joining temperature. This layer separates the joined metals and prevents the formation of Fe–Ti intermetallics in the bonding zone. The maximal tensile strength of the joints (of about 250 MPa) was achieved for bonding at 950 °C for 3.6 ks. The formation of the titanium carbide layer and its evolution are discussed based on the isothermal section of the ternary Fe–Ti–C phase diagram.     

An observer looks at the cell temperature in automotive battery packs

The internal temperature of Li-ion batteries for electric or hybrid vehicles is an important factor influencing their ageing. Generally not measured, it can be reconstructed from an external measurement and a model. This paper presents the simplified modelling of heat transfers in a battery module, leading to a Linear Parameter-Varying (LPV) model. Then, a polytopic observer is proposed to estimate the cell temperature and internal resistance, ensuring a tradeoff between the convergence speed and the noise of the estimated states. Experimental results show the good quality of the estimation and the diagnosis potential offered by internal resistance reconstruction.     

Influence of Post-Laser Welding Heat Treatment on Assembling Performance of Aluminum Alloy Structure

The need to reach the mechanical performance of age hardened Al-Mg-Si (6000 series) base alloy of structures, the assemblies of which are processed by laser welding, has required the efficiency evaluation of age hardening heat treatment performed after welding. It has been established that post-laser aging treatments are not efficient enough to give laser welded assemblies the expected performance of hardened Al base alloy in term of micro-hardness, ultimate tensile strength, and failure deformation. This lack of efficiency has been attributed to insufficient cooling kinetic during laser welding rather than to composition deviation of the bead due to the use of Si rich filler. The interposition of solution heat treatment between welding and aging treatment has been proposed and has shown its efficiency to give the laser welded zone a sufficient strength, similar to that of Al base alloy.